Ozone Vertical Profile Characteristics over Qinghai Plateau Measured by Electrochemical Concentration Cell Ozonesondes

ＯｚｏｎｅＶｅｒｔｉｃａｌＰｒｏｆｉｌｅＣｈａｒａｃｔｅｒｉｓｔｉｃｓｏｖｅｒＱｉｎｇｈａｉＰｌａｔｅａｕＭｅａｓｕｒｅｄｂｙＥｌｅｃｔｒｏｃｈｅｍｉｃａｌＣｏｎｃｅｎｔｒａｔｉｏｎＣｅｌＯｚｏｎｅｓｏｎｄｅｓ①ＬｉｕＱｉｊｕｎ（刘奇俊），Ｚｈｅｎｇ...     

Tropospheric ozone profiles near equator and meteorological parameters

This is a study of ozone profile shapes in the 800 to 100 millibar range obtained with balloonsonde data over Trivandrum (8.5° N) during 1975–76 and possible associations of these shapes to some meteorological parameters.Whereas monotonic ozone profiles were noted with clear weather conditions, those associated with cloud cover show three basic anomalous features. Some bulges of increased values are observed in the range of 800 to 500 mb. In the 500–100 mb range, short range or localized cloud cover or passing weather disturbances are associated with fluctuation patterns in the ozone profile and an average depleted value of ozone. The fluctuations are also associated with changing wind speed and direction at these heights.Possible causative mechanisms are discussed. Lightning associated with thundestorm, producing additional CO and NO are sought to interpret the bulges at lower heights. The decrease in values as well as the fluctuation patterns are suggested as due to possible incursion of water vapour from troposphere to stratosphere in the tropical region and dynamical effects associated with it.     

O3浓度增加对油菜影响的诊断试验研究

利用OTC-1型农田开顶式气室对油菜进行了不同臭氧浓度200×10-9、100×10-9、50×10-9、未过滤（25×10-9～40×10-9）和过滤掉自然大气的O₃后（约为10×10-9）5个处理的长期接触试验，结果表明:目前大气本底（25×10-9～40×10-9）和50×10-9的低浓度臭氧对油菜有慢性伤害作用。臭氧浓度增加到100×10-9、200×10-9时油菜出现退绿、失水等急性伤害症状。臭氧浓度增加可导致植株矮化，株型缩小，叶片数和叶面积减少，光合速率、生物产量和经济产量下降。试验还表明，正常生长的油菜移入浓度为100×10-9、200×10-9的臭氧环境下，首先受影响的是叶肉和表皮，而此环境下的新生叶片其叶脉将首先扭曲变形。     

西宁夏季对流层臭氧垂直分布变化与气象要素的关系

根据臭氧、气象探空观测数据,分析了1996年7月5日至8月3日西宁（36°44’N,101°45＇E,海拔高度2296m）上空对流层臭氧垂直分布变化与气象要素之间的关系。对流层臭氧浓度的增加（减少）总伴随着干、冷（暖、湿）气流的输送变化,而这又与大气垂直方向的运动是紧密联系在一起的。分析表明天气动力输送过程对对流层臭氧垂直分布变化有重要作用。     

全球平流层-对流层之间臭氧通量的时空演变研究

利用1958~2001年的臭氧混合比和ECMWF(European Centre for Medium_range Weather Forecast)资料,采用Wei诊断模型定量计算了穿越全球对流层顶的臭氧质量通量.结果表明:(1)臭氧通量场存在纬向型和经向型的空间波列结构,这些空间波列均未能跨越对流层顶断裂带到达热带对流层顶控制区,其中南北两极的极区、地中海-伊朗高原-青藏高原-日本南部-北太平洋和南半球对流层顶断裂带中沿纬圈完整的空间波列最为显著.海洋上空臭氧通量的性质较为均匀一致,大陆上空的空间结构多变.北半球向下与向上的局地平均最大臭氧通量分别是-4μg.m-2.s-1和2.5μg.m-2.s-1,南半球的对应值为-2.5μg.m-2.s-1和1.5μg.m-2.s-1.(2)纬向平均的臭氧净通量依赖于纬度变化,北半球与南半球具有显著的非对称特性,总效应是平流层臭氧向对流层输运注入.臭氧通量有着显著的季节变化,可随不同季节在地理分布上发生空间转移现象,而且其控制机制不仅受对流层顶的季节运动影响,也随大气环境的季节调整而发生改变.(3)南北半球臭氧净通量的变化趋势相反,南半球为双峰结构,表现为非对称振幅的季节波动结构.全球臭氧通量振幅的年际变化表现出明显的QBO(Quasi_Biennial Oscillation)特性,年代际演变的结构形态(向下的臭氧净通量)可划分为4个阶段:1960年代是平稳变化期,1970年代为增强期,1980年代是又一个相对平稳期,1990年代为剧烈变化期.向下的臭氧净通量主极大值出现在1977、1990年和1998年,极小值在1993年和1996年.     

Effect of Preozonation on the Formation of Chlorinated Disinfection By‐products for River Ruhr

The purpose of the study is to gain a better understanding about the formation of THM (trihalomethanes), HAA (haloacetic acids), and AOX (adsorbable organic halogen) in river water (river Ruhr, Essen) through a chlorination kinetics approach. The effect of chlorination time and preozonation on the formation of THM, HAA, and AOX substances was studied. Preozonation can reduce the chlorine demand and the precursors for AOX and THM. THM generation was reduced further, when the ozone dosage consumed increased from 3.5 to 12.5 mg in the 1.4 L reaction vessel. AOX and TCAA (trichloroacetic acid) concentrations also decreased dramatically when 3.5 mg of ozone had reacted with the river water, but a higher dose of ozone did not further reduce AOX and TCAA formations. Besides, the characteristics of organic matter in raw water, ozonated water, and preozonated/chlorinated water was investigated. The results suggest the formation of low‐molecular‐weight acids with low UV absorbance when high‐molecular refractive matter is oxidized.     

辽宁地区O3污染状况及相关气象要素分析

利用2015—2019年辽宁城市逐小时地面O₃浓度观测数据,结合各城市逐小时气象要素观测数据,分析了辽宁地区近5 a的O₃污染状况及影响O₃的相关气象条件。结果表明：除环辽东湾部分城市O₃浓度呈下降趋势外,辽宁地区其他城市的O₃浓度均呈明显的上升趋势,O₃正取代PM_2.5成为影响辽宁地区的首要大气污染物。O₃浓度具有夏季高、冬季低,下午高、早晨低的时间分布特征。除受污染排放源直接影响外,高温、高湿、强辐射、小风和地面低气压都有利于O₃的局地生成;在亚洲夏季风的影响下,上游地区（如京津冀地区）的污染气团会随大气环流向东北地区输送,对辽宁地区夏季O₃污染产生重要影响。     

北半球大气臭氧与太平洋海温时空相关分析

本文利用北半球臭氧网格点资料和太平洋海温网格点资料,通过自然正交函数展开(EOF)和谱分析,讨论了臭氧变化与太平洋海温异常的时空结构对应关系及相互联系,得到了一些有意义的结果。     

Generic precursors to coastal earthquakes: Inferences from Denali fault earthquake

Recent research has shown evidence of strong coupling between the atmosphere and lithosphere in coastal regions, associating abnormal atmospheric phenomena to the occurrence of strong earthquakes. Surface latent heat flux (SLHF), total column water vapor (CWV), relative humidity (RH) and total ozone column (TOC), analyzed over the epicentral region of the Denali fault earthquake of November 3, 2002, exhibit anomalous behavior that could be related to the earthquake preparatory process and its occurrence. The complementary nature of the parameters provides strong support that the anomalous values were driven by lithospheric processes, rather than other atmospheric phenomena. Due to the wide availability of remote sensing observations of atmospheric parameters, the detection of anomalies can be used to mitigate the earthquake risks.     

Temporal variations in surface ozone and its precursors and meteorological effects at an urban site in China

Continuous measurements of ozone and its precursors including NO, NO₂, and CO at an urban site (32°03′N, 118°44′E) in Nanjing, China during the period from January 2000 to February 2003 are presented. The effects of local meteorological conditions and distant transports associated with seasonal changed Asian monsoons on the temporal variations of O₃ and its precursors are studied by statistical, backward trajectory, and episode analyses. The diurnal variation in O₃ shows high concentrations during daytime and low concentrations during late night and early morning, while the precursors show high concentrations during night and early morning and low concentrations during daytime. The diurnal variations in air pollutants are closely related to those in local meteorological conditions. Both temperature and wind speed have significant positive correlations with O₃ and significant negative correlations with the precursors. Relative humidity has a significant negative correlation with O₃ and significant positive correlations with the precursors. The seasonal variation in O₃ shows low concentrations in late autumn and winter and high concentrations in late spring and early summer, while the precursors show high concentrations in late autumn and winter and low concentrations in summer. Local mobile and stationary sources make a great contribution to the precursors, but distant transports also play a very important role in the seasonal variations of the air pollutants. The distant transport associated with the southeastern maritime monsoon contributes substantially to the O₃ because the originally clean maritime air mass is polluted when passing over the highly industrialized and urbanized areas in the Yangtze River Delta. The high frequency of this type of air mass in summer causes the fact that a common seasonal characteristic of surface O₃ in East Asia, summer minimum, is not observed at this site. The distant transports associated with the northern continental monsoons that dominate in autumn and winter are related to the high concentrations of the precursors in these two seasons. This study can contribute to a better understanding of the O₃ pollution in vast inland of China affected by meteorological conditions and the rapid urbanization and industrialization.