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71.
The purpose of the study is to gain a better understanding about the formation of THM (trihalomethanes), HAA (haloacetic acids), and AOX (adsorbable organic halogen) in river water (river Ruhr, Essen) through a chlorination kinetics approach. The effect of chlorination time and preozonation on the formation of THM, HAA, and AOX substances was studied. Preozonation can reduce the chlorine demand and the precursors for AOX and THM. THM generation was reduced further, when the ozone dosage consumed increased from 3.5 to 12.5 mg in the 1.4 L reaction vessel. AOX and TCAA (trichloroacetic acid) concentrations also decreased dramatically when 3.5 mg of ozone had reacted with the river water, but a higher dose of ozone did not further reduce AOX and TCAA formations. Besides, the characteristics of organic matter in raw water, ozonated water, and preozonated/chlorinated water was investigated. The results suggest the formation of low‐molecular‐weight acids with low UV absorbance when high‐molecular refractive matter is oxidized. 相似文献
72.
利用2015—2019年辽宁城市逐小时地面O3浓度观测数据,结合各城市逐小时气象要素观测数据,分析了辽宁地区近5 a的O3污染状况及影响O3的相关气象条件。结果表明:除环辽东湾部分城市O3浓度呈下降趋势外,辽宁地区其他城市的O3浓度均呈明显的上升趋势,O3正取代PM2.5成为影响辽宁地区的首要大气污染物。O3浓度具有夏季高、冬季低,下午高、早晨低的时间分布特征。除受污染排放源直接影响外,高温、高湿、强辐射、小风和地面低气压都有利于O3的局地生成;在亚洲夏季风的影响下,上游地区(如京津冀地区)的污染气团会随大气环流向东北地区输送,对辽宁地区夏季O3污染产生重要影响。 相似文献
73.
唐佑民 《成都信息工程学院学报》1993,(4)
本文利用北半球臭氧网格点资料和太平洋海温网格点资料,通过自然正交函数展开(EOF)和谱分析,讨论了臭氧变化与太平洋海温异常的时空结构对应关系及相互联系,得到了一些有意义的结果。 相似文献
74.
Recent research has shown evidence of strong coupling between the atmosphere and lithosphere in coastal regions, associating abnormal atmospheric phenomena to the occurrence of strong earthquakes. Surface latent heat flux (SLHF), total column water vapor (CWV), relative humidity (RH) and total ozone column (TOC), analyzed over the epicentral region of the Denali fault earthquake of November 3, 2002, exhibit anomalous behavior that could be related to the earthquake preparatory process and its occurrence. The complementary nature of the parameters provides strong support that the anomalous values were driven by lithospheric processes, rather than other atmospheric phenomena. Due to the wide availability of remote sensing observations of atmospheric parameters, the detection of anomalies can be used to mitigate the earthquake risks. 相似文献
75.
Interaction between local and regional pollution during Escompte 2001: impact on surface ozone concentrations (IOP2a and 2b) 总被引:2,自引:0,他引:2
Escompte, a European programme which took place in the Marseille region in June–July 2001, has been designed as an exhaustive database to be used for the development and validation of air pollution models. The air quality Mesoscale NonHydrostatic Chemistry model (Meso-NH-C) is used to simulate 2 days of an Intensive Observation Period (IOP) documented during the Escompte campaign, June 23 and 24, 2001. We first study the synoptic and local meteorological situation on June 23 and 24, using surface and aircraft measurements. Then, we focus on the pollution episode of June 24. This study emphasizes the deep impact of synoptic and local dynamics on observed ozone concentrations. It is shown that ozone levels are due both to regional and local factors, with highlights of the importance of ozone layering. More generally this confirms, even in an otherwise predominant local sea-breeze regime, the need to consider larger scale regional pollutant transport. 相似文献
76.
The new MOdèle de Chimie Atmosphérique à Grande Echelle (MOCAGE) three-dimensional multiscale chemistry and transport model (CTM) has been applied to study heavy pollution episodes observed during the ESCOMPTE experiment. The model considers the troposphere and lower stratosphere, and allows the possibility of zooming from the planetary scale down to the regional scale over limited area subdomains. Like this, it generates its own time-dependent chemical boundary conditions in the vertical and in the horizontal. This paper focuses on the evaluation and quantification of uncertainties related to chemical and transport modelling during two intensive observing periods, IOP2 and IOP4 (June 20–26 and July 10–14, 2001, respectively). Simulations are compared to the database of four-dimensional observations, which includes ground-based sites and aircraft measurements, radiosoundings, and quasi-continuous measurements of ozone by LIDARs. Thereby, the observed and modelled day-to-day variabilities in air composition both at the surface and in the vertical have been assessed. Then, three sensitivity studies are conducted concerning boundary conditions, accuracy of the emission dataset, and representation of chemistry. Firstly, to go further in the analysis of chemical boundary conditions, results from the standard grid nesting set-up and altered configurations, relying on climatologies, are compared. Along with other recent studies, this work advocates the systematic coupling of limited-area models with global CTMs, even for regional air quality studies or forecasts. Next, we evaluate the benefits of using the detailed high-resolution emissions inventory of ESCOMPTE: improvements are noticeable both on ozone reactivity and on the concentrations of various species of the ozone photochemical cycle especially primary ones. Finally, we provide some insights on the comparison of two simulations differing only by the parameterisation of chemistry and using two state-of-the-art chemical schemes for regional photochemical modelling. Regional air quality modelling is found to be highly sensitive to the emission inventory dataset and also to the vertical and horizontal boundary conditions and detailed representation of chemistry. Interestingly enough, they infer the same range of errors compared to total model errors. 相似文献
77.
《Comptes Rendus Geoscience》2018,350(7):354-367
In the 1980s, ground-based monitoring of the ozone layer played a key role in the discovery of the Antarctic Ozone Hole as well as in the first documentation of significant winter and spring long-term downward trends in the populated mid-latitude regions. The article summarizes the close-to-hundred-year-long history of ground-based measurements of stratospheric ozone, and more recent observations of constituents that influence its equilibrium. Ozone observations began long before the recognition of the impact of increasing emissions of manmade ozone-depleting substances on ozone and therefore on UV levels, human health, ecosystems and the Earth climate. The historical ozone observations prior to 1980s are used as a reference for the assessments of the state of the ozone layer linked to the enforcement of the Montreal Protocol. In this paper, we describe the worldwide monitoring networks and their ozone observations used to determine long-term trends with an accuracy of a few percent per decade. Since 1989, the ground-based monitoring activities have provided support for the amendments of the Montreal Protocol (MP). They include monitoring of (a) the ozone total column and the vertical distribution at global scale, (b) the ozone-depleting substances (ODS) related to the MP such as chlorofluorocarbons (CFCs), and their decomposition products in the stratosphere, and (c) the atmospheric species playing a role in ozone depletion, e.g., nitrogen oxides, water vapor, aerosols, polar stratospheric clouds. We highlight important accomplishments in the atmospheric monitoring performed by the Global Atmosphere Watch program (GAW) run under the auspices of the World Meteorological Organization (WMO) and by the Network for the Detection of Atmospheric Composition Change (NDACC). We also address the complementary roles of ground-based networks and satellite instruments. High-quality ground-based measurements have been used to evaluate ozone variabilities and long-term trends, assess chemistry climate models, and check the long-term stability of satellite data, including more recently the merged satellite time-series developed for the detection of ozone recovery at global scale, which might be further modified by climate change. 相似文献
78.
《Comptes Rendus Geoscience》2018,350(7):376-383
Although catalytic chemistry involving ozone-depleting substances (ODSs) is currently a primary driver impacting the abundance of stratospheric ozone, water vapor and aerosols are constituents that also affect stratospheric ozone. Variability in both water vapor and aerosols can induce variability in ozone, and although small relative to that due to trends in ODSs, in the future may become a much more important source of ozone variability. 相似文献
79.
《Atmósfera》2014,27(3):261-271
Air pollution is the main environmental issue in Mexico City, where ozone is one of the most damaging pollutants for human health. In this work we present a retrospective health impact assessment (HIA) study split up by age groups for evaluating the benefits of ozone regulatory strategies from 1991 to 2011 in Mexico City. Since people move from one place to another during the day, which may affect their potential exposure to pollutants, we consider time-dependant spatial population distributions during the day. Ozone data is made up of observations taken with hourly frequency from January 1, 1991 to December 31, 2011, at approximately 22 stations of the monitoring network of Mexico City. Interpolated values for unknown locations are also taken into account in the HIA. The Cressman objective analysis method is applied for interpolating the observed ozone concentrations from monitoring stations to grids of convenient resolution. We demonstrate that different age groups present different spatial patterns of exposure, being the working-age people (between 18 and 64 years) the most benefited. We also confirm the hypothesis that, in general, people move to less polluted regions during the day. 相似文献
80.
The oxidation of organophosphorus pesticides (OPPs), such as malathion and parathion, in aqueous solution was studied using conventional ozonation (O3), photolytic ozonation (O3/UV, O3/UV/H2O2), and heterogeneous catalytic ozonation (O3/TiO2/UV) processes. Experiments were performed in batch mode at laboratory scale and processes were compared in terms of disappearance kinetics. The best results of pesticide mineralization were obtained when TiO2 particles in combination with ozone (O3) and UV photolysis (λ = 254 nm) were applied. Decomposition of 99% of parent compounds were achieved in 10 min and oxon derivatives were completely removed in 30 min. The initial reaction rate increases linearly with increasing catalyst amount. Toxicity measurements of the treated solutions were carried out in order to evaluate the efficiency of the treatment methods. No detoxification was achieved for O3 and O3/UV applications. Heterogeneous photocatalytic ozonation was shown to be feasible for achieving complete decomposition of OPPs and their oxon intermediates. 相似文献