土壤圈在全球变化中的意义与研究内容

土壤圈是地圈系统的重要组成部分，它处于地圈系统，即气圈、水圈、生物圈与岩石圈的交界面，是最活跃、最富生命力的圈层。土壤圈的物质循环是全球变化中物质循环的重要内容，因此，研究土壤圈及其物质循环的结构与功能，对全球变化，特别对全球土壤变化有密切关系。土壤圈在全球土壤变化中的研究内容包括：土壤圈与地圈各圈层的物质循环；水土资源的时空变化；土壤肥力变化与农业持续发展，区域治理与环境建设等，这些都是全球土壤变化，特别是中国全球变化的主题，应引起高度重视。     

Reconstructing the iron cycle from the horizontal distribution of metals in the sediment of Baldeggersee

In Baldeggersee, the distributions of solid phase Fe, Mn, V, Cr, As and Mo were determined in different sediment strata, deposited under various deep-water oxygen conditions. Iron concentrations are correlated with water depth when an anoxic sediment is in contact with an oxic water column. Benthic redox gradients trigger iron transport towards the deepest site (geochemical focusing) and loss of iron from the shallower parts through the outflow. Fe cycling in the lake is inhibited by oxygen penetration into the sediment. Vanadium and arsenic can be used as tracers for the internal Fe cycle. Their distribution patterns are highly correlated with iron. In case of a stable oxycline in the deep water, Mo is enriched in the sediment and correlates with Mn. The horizontal distribution patterns of Fe, V, As and the correlation of Fe and Mn with trace metals are promising proxy indicators for the reconstruction of deep-water oxygen conditions during deposition.     

植物营养元素的含量和δ~(13)C值随海拔而变化的特征及营养元素相互作用对碳同位素分馏作用的影响

为了研究植物营养元素的含量和δ~(13)C值随海拔而变化的相关关系,沿着海拔450 m的贵州茂兰至海拔1330 m的贵州安顺一线,采集和分析研究了C_3植物——小果蔷薇(R.cymosa Tratt)的叶片。分析结果表明,植物叶片中营养元素含量随着海拔的上升而产生的变化是:氮、磷和钾的含量会在增高,而钙和镁的含量却会降低。植物叶片的δ~(13)C值会增大,其变幅为 2.4‰/1000m。     

山西离柳地区生态地球化学环境中氟与人群健康关系的研究

为了研究不同生态地球化学区内元素对人体健康的影响 ,在山西离柳地区西部 ,以氟为例 ,运用地下水化学热力学、化学动力学及统计分析 ,得出 :(1)地氟病患病率及病情轻重程度 ,与水 (土 )中F-总量 (F总)及活度 (aF- )、络合物活度 (aMF)及其饱和指数 (βMF)呈正相关关系 ,符合一般规律 ;(2 )氟的不同存在形态的致病作用是aF- >F总 ,aNaF0 >aCaF+>aMgF+,βNaF0 >βCaF+>βMgF+;(3)水循环交替条件及有关组分含量与病情轻重密切相关。研究结果为防治地氟病和地方性病症提供了定性、定量依据 ,也为同类研究提出了新的途径     

Exchange flux of total gaseous mercury between air and natural water surfaces in summer season

The exchanges of mercury between surface and air are of significance in the biogeochemical cycling of Hg in the environment, but there are still few reliable data on air/surface exchange in aquatic systems. Field measurement campaigns over seawater surface at Kristineberg Marine Research Station (KMRS) and over Hovg?rds?n River surface at Knobesholm in southwestern Sweden were conducted to measure mercury flux using a dynamic flux chamber technique coupled with automatic mercury vapor-phase analyzers. Both sites show net emissions during summer time. Mercury fluxes measured over both river and seawater surfaces exhibit a consistently diurnal pattern with maximum fluxes during the daytime period and minimum fluxes during the nighttime period. At freshwater site, mercury flux is strongly correlated with the intensity of net solar radiation, and negatively correlated with relative humidity. A typical exponential relationship between mercury flux and water temperature was observed at freshwater measurement site. At seawater site, a strong correlation between mercury flux and intensity of solar radiation was obtained. The driving force of mercury emission from water surface to air is the super-saturation of dissolved gaseous mercury in aqueous phase.     

华南亚热带山地土壤有机质更新特征定量研究

选择鼎湖山自然保护区森林植被带（SL）、灌丛一草甸过渡带土壤剖面（GC）进行薄层取样，根据土壤有机质^14C放射性水平，运用模型计算土壤有机质更新速率（m）。结果表明上部0－10cm土层有机质更新速率（m）最高；向下,m锐减；剖面下部m值极低，这说明土壤有机质由不同更新周期（T）组分构成。表层快循环组分占绝对优势，向下，慢循环组分为主，剖面下部为稳定组分。根据m、有机碳含量、有机碳含量、土壤容重、土层厚度计算有机质更新CO2产量，表层0－10cm层段CO2产量约为整个剖面的98％。SL剖面m值及有机质更新CO2产量均明显大于GC剖面相应值。分析表明在同一气候植被是制约土壤有机质更新及CO2产量的第一要素，这为通过绿化加强土壤碳汇功能提供重要依据。     

三江平原湿地植物群落P、K的积累、动态及其生物循环

在三江平原湿地植物生长季节里,选择该区分布最广、面积最大且最具有代表性的毛果苔草(Carexlasioncarpa)-狭叶甜茅(Glyceria spiculosa)群落和小叶章(Deyeuxia angustifo-lia)群落为研究对象,逐月测定两类湿地群落生物量,并对植物样品分别用钼锑抗比色法和原子吸收法测定其P、K含量。在此基础上,探讨了两类湿地群落的P、K积累量及其生物循环特征。结果表明,三江平原不同的植物群落以及同一群落的不同器官,其P、K元素积累量不同,而且都有明显的季节变化。根是群落中P、K元素的最大贮存器官,其P、K积累量占总量的80%左右。湿地群落中K的吸收量、归还量、存留量、现存量和表土贮量都大于P的对应值,同时K的利用系数和循环系数均大于P,毛果苔草-狭叶甜茅群落K的吸收系数大于P,而小叶章群落K的吸收系数小于P。     

淡水中对紫外光敏感的磷化合物研究简述

湖泊、沼泽与河流等淡水生态系统中在的一些对紫外光敏感的磷化合物,它们在紫外光（或太阳光）的作用下释放正磷酸根。本文对其形成释放机制、生态学意义以及铁和腐殖质的调节作用等作了扼要的综述。     

Origin and chemical and isotopic evolution of dissolved inorganic carbon (DIC) in groundwater of the Okavango Delta,Botswana

The origin and the chemical and isotopic evolution of dissolved inorganic carbon (DIC) in groundwater of the Okavango Delta in semi-arid Botswana were investigated using DIC and major ion concentrations and stable oxygen, hydrogen and carbon isotopes (δD, δ¹⁸O and δ¹³C_DIC). The δD and δ¹⁸O indicated that groundwater was recharged by evaporated river water and unevaporated rain. The river water and shallow (<10 m) groundwater are Ca–Na–HCO₃ type and the deep (≥10 m) groundwater is Na–K–HCO₃ to HCO₃–Cl–SO₄ to Cl–SO₄–HCO₃. Compared to river water, the mean DIC concentrations were 2 times higher in shallow groundwater, 7 times higher in deep groundwater and 24 times higher in island groundwater. The δ¹³C_DIC indicate that DIC production in groundwater is from organic matter oxidation and in island groundwater from organic matter oxidation and dissolution of sodium carbonate salts. The ionic and isotopic evolution of the groundwater relative to evaporated river water indicates two independent pools of DIC.