The chemical mass balance of calcrete genesis is studied on a typical sequence developed in granite, in the Toledo mountains, Central Spain.
Field evidence and petrographic observations indicate that the texture and the bulk volume of the parent rock are strictly preserved all along the studied calcrete profile.
Microscopic observations indicate that the calcitization process starts within the saprolite, superimposed on the usual mechanisms of granite weathering: the fresh rock is first weathered to secondary clays, mainly smectites, which are then pseudomorphically replaced by calcite. Based on this evidence, chemical mass transfers are calculated, assuming iso-volume transformation from the parent rock to the calcrete.
The mass balance results show the increasing loss of matter due to weathering of the primary phases, from the saprolite towards the calcrete layers higher in the sequence. Zr, Ti or Th, which are classically considered as immobile during weathering, are also depleted along the profile, especially in the calcrete layer. This results from the prevailing highly alkaline conditions, which could account for the simultaneous precipitation of CaCO3 and silicate dissolution.
The calculated budget suggests that the elements exported from the weathering profile are provided dominantly by the weathering of plagioclase and biotite. We calculate that 8–42% of the original Ca remains in granitic relics, while only 15% of the authigenic Ca released by weathering is reincorporated in the calcite. This suggests that 373 kg/m2 of calcium (i.e., three times the original amount) is imported into the calcrete from allochtonous sources, probably due to aeolian transport from distant limestone formations. 相似文献
The development of settlement and building activity is the result of socioeconomic, political and demographic changes in the past. However, accurate information on temporal variation in building activity is rather limited. Dendrochronological databases containing dated historical wooden constructions provide an important resource. We used 6514 tree-felling dates to reconstruct building activity in the Czech lands for the period 1450–1950. Comparing felling dates with historical events demonstrated that building activity was negatively associated with intense wars, particularly during the Thirty Years' War (1618–1648). After the Peace of Westphalia (1648), socioeconomic renewal and demographic growth were reflected in an upsurge of building activity, especially ecclesiastical buildings. While the construction of ecclesiastical and noble buildings culminated around the 1720s, rural buildings peaked in the 1780s and the 1820s. Although no direct effect of climate was demonstrated, adverse climatic conditions leading to harvest failures and subsequent famines (e.g. the ‘Hunger Years’ 1770–1772) significantly contributed to declines in building activity. In contrast, a higher number of felling dates were detected when strong and/or frequent windstorms occurred. This study provides a comprehensive understanding of building activity in Central Europe and advocates the use of dendrochronological databases for the investigation of human activities in history. 相似文献
Multi-hazard susceptibility prediction is an important component of disasters risk management plan. An effective multi-hazard risk mitigation strategy includes assessing individual hazards as well as their interactions. However, with the rapid development of artificial intelligence technology, multi-hazard susceptibility prediction techniques based on machine learning has encountered a huge bottleneck. In order to effectively solve this problem, this study proposes a multi-hazard susceptibility mapping framework using the classical deep learning algorithm of Convolutional Neural Networks (CNN). First, we use historical flash flood, debris flow and landslide locations based on Google Earth images, extensive field surveys, topography, hydrology, and environmental data sets to train and validate the proposed CNN method. Next, the proposed CNN method is assessed in comparison to conventional logistic regression and k-nearest neighbor methods using several objective criteria, i.e., coefficient of determination, overall accuracy, mean absolute error and the root mean square error. Experimental results show that the CNN method outperforms the conventional machine learning algorithms in predicting probability of flash floods, debris flows and landslides. Finally, the susceptibility maps of the three hazards based on CNN are combined to create a multi-hazard susceptibility map. It can be observed from the map that 62.43% of the study area are prone to hazards, while 37.57% of the study area are harmless. In hazard-prone areas, 16.14%, 4.94% and 30.66% of the study area are susceptible to flash floods, debris flows and landslides, respectively. In terms of concurrent hazards, 0.28%, 7.11% and 3.13% of the study area are susceptible to the joint occurrence of flash floods and debris flow, debris flow and landslides, and flash floods and landslides, respectively, whereas, 0.18% of the study area is subject to all the three hazards. The results of this study can benefit engineers, disaster managers and local government officials involved in sustainable land management and disaster risk mitigation. 相似文献