赤道太平洋海域上层海洋热含量及其变化机制的诊断分析*

基于1992—2015年国际共享的ECCO v4 (Estimating the Circulation and Climate of the Ocean Version 4)同化产品, 利用热含量控制方程定量地诊断赤道太平洋(118°E—75°W, 5°S—5°N, 0~300m)和Niño 3.4区(170°W—120°W, 5°S—5°N, 0~80m)这两块区域热含量变化机制。对于去掉季节平均后的年际变化, 在赤道太平洋地区, 时间趋势项主要由经向输送和海表热通量项共同驱动。通过5°N断面的输送决定了时间趋势项的幅值和正负符号。在Niño 3.4区, 时间趋势项主要由海表热通量项和热量输送项共同驱动, 其中垂向输送对总输送贡献最大。赤道太平洋地区经向热量输送异常领先于Niño 3.4区垂向热量输送异常, 这解释了在年际尺度上赤道太平洋热含量异常领先Niño 3.4指数变化的原因。尽管EP(Eastern Pattern)型El Niño和CP(Central Pattern)型El Niño有许多不同之处, 合成分析表明, 两类El Niño的共同点为: 在赤道太平洋地区, 两类El Niño事件的热量输送异常在发展期和衰退期由经向输送主导; 在Niño 3.4区, EP型El Niño和CP型El Niño的热量输送在发展期和衰退期由垂向输送主导。     

牙膏用六水氯化锶的制备

以不同纯度的自制氢氧化锶为原料与盐酸充分反应,经提纯、结晶,制备六水氯化锶（SrCl2·6H2O）。通过X射线衍射（XRD）和场发射扫描电子显微镜（FESEM）对SrCl2·6H2O的结构、形貌进行表征,通过能谱仪（EDS）和差热-热重分析仪（TG）对SrCl2·6H2O进行元素含量和热失重分析,并将制备的样品与中华人民共和国化工行业牙膏用氯化锶标准进行对比。结果表明,高纯氢氧化锶与分析纯盐酸制备的SrCl2·6H2O可以达到牙膏用标准。     

基于Matlab和灰色模型GM（1,1）预测海岸线变化*

使用灰色模型的“少数据”建模寻求现实规律的良好特性用于海岸线变迁预测,结合 MATLAB 强大的计算能力,解决了灰色预测模型在矩阵计算方面复杂的问题.利用1975-2005年珠江口内伶仃洋海区6个时期的海图提取局部时序海岸线,设置原点和28条侧线,使用侧线与海岸线的交点,建立灰色模型 GM (1,1)模型原始数列,使用 MATLAB 编制程序计算出海岸线变化的预测点,并使用2005年实际海岸线对预测结果进行验证,结果表明灰色模型 GM (1,1)进行海岸线预测是合理可靠的.     

海洋自由生活线虫群落和环境的关系研究

以2007年春季在渤海湾近岸海域进行的调查为基础,分析了海洋自由生活线虫的群落组成和环境之间的关系.以等级聚类(Cluster)、非度量多维标度(MDS)和生物-环境分析(BIO-ENV)等多元统计方法为主,采用 PRIMER 5.2软件进行数据处理和分析.在测定的约30个环境因素中,有10个因素对底栖线虫群落产生了重要影响,包括水体的 pH、硝酸盐、悬浮物、活性硅酸盐、温度、盐度、溶解氧和沉积物的脱镁色素、叶绿素 a、平均粒径等因素.一些沉积物因素和水环境因素组合后较好地解释了底栖线虫群落结构情况,这反映了水环境和沉积环境的关联性,今后的底栖生物研究中应注意水体和沉积物环境的耦合.     

Late Quaternary climatic changes in southern Chile, as recorded in a diatom sequence of Lago Puyehue (40°40′ S)

A late Quaternary diatom stratigraphy of Lago Puyehue (40°40′ S, 72°28′ W) was examined in order to infer past limnological and climatic changes in the South-Chilean Lake District. The diatom assemblages were well preserved in a 1,122 cm long, ¹⁴C-dated sediment core spanning the last 17,900 years, and were in support of an early deglaciation of Lago Puyehue. The presence of a short cold spell in South Chile, equivalent to the Younger Dryas event in the Northern Hemisphere, the Antarctic Cold Reversal in Antarctica, or the Huelmo-Mascardi event in southern South America, was not clearly evidenced in the diatom data, although some climate instability may have occurred between 13,400 and 11,700 cal. yr. BP, and a relatively long period (between 16,850 and 12,810 cal. yr. BP) with low absolute abundances and biovolumes could be tentatively interpreted as a period of low rainfall and/or temperatures. An increase in the moisture supply to the lake was tentatively inferred at 12,810 cal. yr. BP. After 9,550 cal. yr. BP, inferred stronger and longer persisting summer stratification, may have been the result of the higher temperatures associated with an early-Holocene thermal optimum. The mid-Holocene appeared to be characterized by a decrease in precipitation, culminating around 5,000 cal. yr. BP, and rising again after 3,000 cal. yr. BP, likely associated with a previously documented lowered frequency and amplitude of El Niño events. An increase in precipitation during the late Holocene (3,000 cal. yr. BP–present) might have marked subsequent increased frequency of El Niño occurrences, leading to drier summers and slightly moister winters in the area.     

Palaeoecology of Holocene peat deposits from Nordvestø, north-west Greenland

Two extensive peat deposits on Nordvestø, between Greenland and Canada, were examined for macroscopic remains of plants and animals. One of the peat deposits accumulated during the period from c. 7,100 to 5,100 cal. years BP. This peat is guanogenic and completely dominated by the coprophilous bryophyte Aplodon wormskioldii, and also contains frequent remains of feathers. The peat formed close to a large former sea bird colony, probably a puffin (Fratercula arctica) colony. Puffins are now rare in the region, but the population may have been larger during the mid Holocene, when the sea was ice-free for a longer period than at present. The other peat deposit is dated to c. 9,300–7,400 cal. years BP, it is minerogenic and the macrofossils reflect deposition in a shallow, richly vegetated pond. This peat formed during warmer summers than at present.     

On the geodynamics of the Alpine collisional granitoids from Central Anatolia: petrology,age and isotopic characteristics of the granitoids of the Ekecikdağ Igneous Association (Aksaray/Turkey)

Granitoids of the Ekecikda? Igneous Association (Central Anatolia/Turkey) are products of collisional–post-collisional magmatism in the Ekecikda? area. These granitoids are granodiorite, microgranite and leucogranite. Field relations of granodiorites with microgranites is obscured, but leucogranites intrude both rock types. Mean zircon laser ablation (LA)-ICP-MS ²⁰⁶Pb-²³⁸U ages of granodiorites and microgranites are 84.52 ± 0.93 Ma and 80.7 ± 1.6 Ma, respectively, and age of leucogranites is suggested as 80 Ma, based on field relations combined with ²⁰⁶Pb/²³⁸U and Rb-Sr ages. Crystallisation temperatures of granodiorites, microgranites and leucogranites are 728°C-848°C, 797°C-880°C, 704°C-809°C, respectively.

Geochemical characteristics including Sr-Nd isotopic evidences infer a non-cogenetic character, as there is a high crustal contribution in I-type granodiorite sources, a crustal source with insignificant and significant mantle inputs in S-type microgranites and leucogranites, respectively. LA-ICP-MS Lu-Hf isotope data from zircons reveal their crustal nature (εHf_(t): ?1.3 ± 0.5 to ?8.8 ± 0.5). Crustal melting linked to the Alpine thickening during the Late Cretaceous led to formation of heterogeneous sourced granitoids with crustal dominated sources in the Ekecikda? area. Understanding of the nature and evolution of collisional Ekecikda? granitoids is not only important to put contribution in the geodynamic evolution of Central Anatolia and surrounding Alpine area, but also to better understand systematics of collisional magmatic systems.     

Preparation,Characterization of a Novel Chelating Resin Functionalized with o‐Hydroxybenzamide and Its Application for Preconcentration of Trace Metal Ions

A stable extractor of metal ions was synthesized through azo linking of o‐hydroxybenzamide (HBAM) with Amberlite XAD‐4 (AXAD‐4) and was characterized by elemental analyses, IR spectral, and thermal studies. Its water regain value and hydrogen ion capacity were found to be 12.93 and 7.68 mmol g^?1, respectively. The optimum pH range (with the half‐loading time [min], t_1/2) for Cu(II), Cr(III), Ni(II), Co(II), Zn(II), and Pb(II) ions were 2.0–4.0 (5.5), 2.0–4.0 (7.0), 2.0–4.0 (8.0), 4.0–6.0 (9.0), 4.0–6.0 (12.0), and 2.0–4.0 (15.0), respectively. Comparison of breakthrough and overall capacities of the metals ascertains the high degree of column utilization (>70%). The overall sorption capacities for Cu(II), Cr(III), Ni(II), Co(II), Zn(II), and Pb(II) ions were found to be 0.29, 0.22, 0.20, 0.16, 0.13, and 0.11 mmol g^?1 with the corresponding preconcentration factor of 400, 380, 380, 360, 320, and 320, respectively. The limit of preconcentration was in the range of 5.0–6.3 ng mL^?1. The detection limit for Cu(II), Cr(III), Ni(II), Co(II), Zn(II), and Pb(II) were found to be 0.39, 0.49, 0.42, 0.59, 0.71, and 1.10 ng mL^?1, respectively. The AXAD‐4‐HBAM has been successfully applied for the analysis of natural water, multivitamin formulation, infant milk substitute, hydrogenated oil, urine, and fish.     

Large-scale climate teleconnections with South Korean streamflow variability

ABSTRACT

Leading patterns of observed seasonal extreme and mean streamflow on the Korean peninsula were estimated using an empirical orthogonal teleconnection (EOT) technique. In addition, statistical correlations on a seasonal basis were calculated using correlation and regression analyses between the leading streamflow patterns and various climate indices based on atmospheric–ocean circulation. The spatio-temporal patterns of the leading EOT modes for extreme and mean streamflow indicate an upstream mode for the Han River, with increasing trends in summer, and a downstream mode for the Nakdong River, with oscillations mainly on inter-decadal time scales in winter. The tropical ENSO (El Niño Southern Oscillation) forcing for both extreme and mean streamflow is coherently associated with summer to winter streamflow patterns. The western North Pacific monsoon has a negative correlation with winter streamflow variability, and tropical cyclone indices also exhibit significant positive correlation with autumn streamflow. Leading patterns of autumn and winter streamflow time series show predictability up to two seasons in advance from the Pacific sea-surface temperatures.     

Fault plane parameters of Tancheng M8? earthquake on the basis of present-day seismological data

The great Tancheng earthquake of M8? occurred in 1668 was the largest seismic event ever recorded in history in eastern China. This study determines the fault geometry of this earthquake by inverting seismological data of present-day moderate-small earthquakes in the focal area. We relocated those earthquakes with the double-difference method and found focal mechanism solutions using gird test method. The inversion results are as follows: the strike is 21.6°, the dip angle is 89.5°, the slip angle is 170°, the fault length is about 160 km, the lower-boundary depth is about 32 km and the buried depth of upper boundary is about 4 km. This shows that the seismic fault is a NNE-trending upright right-lateral strike-slip fault and has cut through the crust. Moreover, the surface seismic fault, intensity distribution of the earthquake, earthquake-depth distribution and seismic-wave velocity profile in the focal area all verified our study result.