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981.
A Double Solid Reactant Method was elaborated from a suggestion of Marini (Geological sequestration of carbon dioxide: Thermodynamics,
kinetics, and reaction path modeling. Developments in Geochemistry, Elsevier, Amsterdam, 2007) to simulate the release of
trace elements during the progressive dissolution of solid phases. The method is based on the definition, for each dissolving
solid, of both an entity whose thermodynamic and kinetic properties are known (either a pure mineral or a solid mixture) and
a special reactant, that is, a material of known stoichiometry and unknown thermodynamic and kinetic properties. The special
reactant is utilised to take into account the concentrations of trace elements in the dissolving solid phase. In this communication,
the influence of several trace elements on the ΔG
f
o, ΔG
r
o and log K of the minerals considered by Lelli et al. (Environ Geol, 2007) and Accornero and Marini (Geobasi, 2007a; Proceedings of
IMWA symposium, Cagliari, 27–31 May 2007b) was evaluated assuming ideal mixing in the solid state. These effects were found
to be negligible for albite and the leucite–latitic glass, limited for muscovites and chlorites, and slightly more important
for apatites. These influences become progressively higher with increasing concentration of trace elements in these minerals.
Based on these deviations in thermodynamic parameters, special reactants should not include oxide components with molar fractions
higher than 0.003.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.
相似文献
Luigi MariniEmail: |
982.
Heavy metals and rare earth elements (REEs) in soil from the Nam Co Basin,Tibetan Plateau 总被引:1,自引:0,他引:1
Chaoliu Li Shichang Kang Xiaoping Wang F. Ajmone-Marsan Qianggong Zhang 《Environmental Geology》2008,53(7):1433-1440
Twenty-eight soil samples collected from the Nam Co Basin, Tibetan Plateau, have been analyzed for heavy metals (Cd, Cr, Ni,
Cu, Zn, Pb and Mn), arsenic (As) and rare earth elements (REEs). In addition, for establishing the basic physio-chemical characteristics
of the soil, pH, total organic concentration, electrical conductivity, and effective cation exchange capacity were measured.
The results indicate that soil in the Nam Co Basin is still at an early alkaline weathering stage (pH = 7.94). Mean concentrations
of heavy metals and As decreased as follows: Mn > Cr > Zn > Pb > Ni > Cu > As > Cd. The values of Cd, Cr, As, Pb and REEs
in soil from the Nam Co Basin are higher relative to averaged background values over China. The chondrite-normalized diagrams
of REEs suggest high REE(ΣLa → Eu)—enrichment, HREE(ΣGd → Lu)—depletion and Eu—depletion. Vertical profiles indicate that
both heavy metals (except As) and REEs primarily exist in the surface soil. However, heavy metals and REEs vary in the surface
soil between the southern and the northern bank of Nam Co. These differences are controlled mainly by parent materials. 相似文献
983.
Distribution of trace elements in the coastal sea sediments of Maslinica Bay, Croatia 总被引:1,自引:0,他引:1
Nenad Mikulic Visnja Orescanin Loris Elez Ljiljana Pavicic Durdica Pezelj Ivanka Lovrencic Stipe Lulic 《Environmental Geology》2008,53(7):1413-1419
Spatial distributions of trace elements in the coastal sea sediments and water of Maslinica Bay (Southern Adriatic), Croatia
and possible changes in marine flora and foraminifera communities due to pollution were investigated. Macro, micro and trace
elements’ distributions in five granulometric fractions were determined for each sediment sample. Bulk sediment samples were
also subjected to leaching tests. Elemental concentrations in sediments, sediment extracts and seawater were measured by source
excited energy dispersive X-ray fluorescence (EDXRF). Concentrations of the elements Cr, Cu, Zn, and Pb in bulk sediment samples
taken in the Maslinica Bay were from 2.1 to over six times enriched when compared with the background level determined for
coarse grained carbonate sediments. A low degree of trace elements leaching determined for bulk sediments pointed to strong
bonding of trace elements to sediment mineral phases. The analyses of marine flora pointed to higher eutrophication, which
disturbs the balance between communities and natural habitats. 相似文献
984.
对2006年10月采自长江巫山段一级支流大宁河河底的三根岩芯作了常量元素(K、Na、Ca、Mg)的分析。研究结果表明,沉积物中稀酸可溶相常量元素的含量能够反映沉积物的特征和来源。大宁河中—上游沉积物中碳酸盐含量平均为23%,反映岩溶地区石灰岩风化的影响;而与长江交接处的沉积物中碳酸盐含量平均为10%,显示长江主流有明显不同的沉积物来源。三峡大坝的建成蓄水,水位提高,使得碳酸盐含量低的红色粘土进入双龙镇段大宁河沉积,造成碳酸盐含量、稀酸可溶相常量元素含量急剧下降、沉积物的颜色发生显著变化。受到蓄水作用的影响,大宁河泥沙沉积速率大幅度提高,自2004年12月蓄水以来,大宁河双龙镇附近沉积物厚达10cm以上。 相似文献
985.
986.
Chemical weathering was investigated by collecting samples from five selected weathering profiles in a high elevation granitic
environment located in Seoul, Korea. The overall changes of chemistry and mineralogical textures were examined reflecting
weathering degrees of the samples, using polarization microscopy, X-ray diffraction (XRD), electron probe micro analysis (EPMA),
X-ray fluorescence spectroscopy (XRF), and inductively coupled plasma–mass spectroscopy (ICP–MS). The chemical distribution
in the weathering profiles shows that few trace elements are slightly immobile, whereas most major (particularly Ca and Na)
and trace elements are mobile from the beginning of the granite weathering. On the other hand, there were mineralogical changes
initiated from a plagioclase breakdown, which shows a characteristic circular dissolved pattern caused by a preferential leaching
of Ca cation along grain boundaries and zoning. The biotite in that region is also supposed to be sensitive to exterior environmental
condition and may be easily dissolved by acidic percolated water. As a result, it seems that some rock-forming minerals in
the granitic rock located in Seoul are significantly unstable due to the environmental condition of acidic rainfall and steep
slopes, where they are susceptible to be dissolved incongruently leading some elements to be highly depleted. 相似文献
987.
Petrogenesis of Volcanic Rocks from Saipan and Rota, Mariana Islands, and Implications for the Evolution of Nascent Island Arcs 总被引:2,自引:0,他引:2
Reagan Mark K.; Hanan Barry B.; Heizler Matthew T.; Hartman Brian S.; Hickey-Vargas Rosemary 《Journal of Petrology》2008,49(3):441-464
An 40Ar/39Ar age of 45·1 Ma determined for lavas fromnorthern Saipan confirms that these high-silica rhyolites eruptedduring the proto-arc stage of volcanism in theIzu–Bonin–Mariana system, which is characterizedelsewhere by eruption of boninitic lavas. Incompatible traceelement concentrations and Sr, Hf, Nd, and Pb isotope ratiosfor these rhyolites are transitional between those of c. 48Ma boninitic lavas and post-38 Ma first-arc andesitesand dacites from Saipan and Rota that have typical subduction-relatedcompositions. These transitional compositions are modeled bycrystal fractionation of parental tholeiitic basalt combinedwith assimilation of young boninitic crust. A second stage ofRayleigh fractionation in the upper crust is required by SiO2concentrations that exceed 77 wt % and near-zero compatibleelement concentrations. First-arc magma compositions are consistentwith fractionation of basalt and assimilation of crust similarin composition to the first-arc magmas themselves. The mantlesources of the proto-arc and first-arc lavas from Saipan andRota are similar to those of Philippine back-arc basin basaltsbased on Nd and Hf isotopic compositions. The Pb isotope compositionsof these lavas are between those of Pacific sea-floor basaltsand Jurassic and younger cherty and clay-rich sediments. Thiscontrasts with the boninitic proto-arc volcanic rocks from Guamand Deep Sea Drilling Project Sites 458 and 459 that have Pbisotope compositions similar to Pacific basin basalts and volcaniclasticsediments. The preferred explanation for the difference in thenature of proto-arc volcanism between Saipan and other fore-arclocations is that the crust ceased extending 3–4 Myr earlierbeneath Saipan. This was caused by a change from mantle upwelling,fore-arc extension, and shallow melting to an environment dominatedby more normal mantle wedge convection, stable crust, and deepermelting. KEY WORDS: rhyolite; andesite; Mariana arc; isotope ratios; trace elements 相似文献
988.
Distribution Characteristics of Sulfur and the Main Harmful Trace Elements in China's Coal 总被引:1,自引:1,他引:0
To promote the rational development and use of clean coal resources in China,data on the regional and age distribution of sulfur,arsenic and other harmful elements in Chinese coal was broadly collected,tested for content,and analyzed.Coal in northwestern China is characterized by low to extremely low levels of sulfur;the coal of the Taiyuan Formation in northern China mainly has high-sulfur content;that of the Shanxi Formation is mainly characterized by low sulfur coal;and the Late Permian coal in southern China has overall higher sulfur content;other regions have low sulfur coal.The average content of harmful trace elements in the bulk of China's coal is similar to the corresponding content in the coal of the North America and the rest of the world,whereas the content of various elements(Hg,Sb and Se)is different in magnitude to the corresponding percentage in the crust.The average content of the elements Cr,Se,Co,Be,U,Br in Late Permian coal in S China ranks first in the country whereas the average content of Hg and Cl in the coals of Late Carboniferous to Early Permian age in N China are the highest.The average content of Mn in Early and Middle Jurassic coal is higher in NW China.The high content of harmful elements in some coal should cause particular concern both in the development and utilization of coal. 相似文献
989.
990.
针对航空高光谱数据几何畸变严重的问题,该文探索了利用POS数据辅助航空高光谱影像几何校正的研究现状,分析了基于POS系统的导航数据的线阵推扫高光谱数据解算成像瞬间外方位元素的原理,以及行方位数据支持的线中心投影影像通过改进的共线方程方法几何校正的过程,实现了无地面控制点数据的直接几何校正。采用高光谱影像分块处理方法,实现了高吞吐快速几何校正。HySpex SWIR-384高光谱影像的实验结果表明,该文的校正算法可达到9.15m的绝对定位精度,最终利用少量地面控制点进行几何精校正,其均方根误差达到0.93m。 相似文献