Untersuchung der Sorptionseigenschaften des Kationenaustauschers KB-2M mit Makronetzstruktur zur Abtrennung von Zinkionen aus Ab- und Spülwässern

Study of Sorptional Properties of the Cation Exchanger KB-2M with Macroreticular Structure for Recovery of Zinc Ions from Sewage and Rinsing Water Although a number of ion-exchange methods have been employed for the recovery of some transition metals from industrial effluents, knowledge about ion-exchange resins with macroreticular structure is poor. The present paper describes the mechanism of sorption on such exchangers and their application for recovery of zinc from sewage rinsing water. Ion exchanger of macroreticular structure are polymers with long-chained cross-linking agents. We have synthesized carboxylic ion-exchange resins by hydrolysis of copolymerisates of methyl acrylate with different cross-linking agents: divinylbenzene, divinyl sulfide, divinyl ester of ethylene glycol and divinyl ester of di- or triethylene glycol. The sorption process on modifications of the carboxylic resins KB-2 of various structure was studied with different methods: potentiometric titration, infrared spectroscopy, electron microscopy, X-ray structural analysis. The initial zinc concentration in rinsing water was 0.05 mol/L at pH from 3 to 6. For the sorption, 0.2…1.0 g of resin were equilibrated with 100 mL of zinc solution. After equilibrium (12 h), the resin was separated from solution. The zinc ions were determined by atomic absorption spectrometry after stripping with 100 mL of 10% sulfuric acid. The distribution ratio D was calculated (D: mmole of Zn sorbed per gram of resin divided by mmole of Zn per millilitre of solution). By means of infrared spectroscopy, the mechanism of sorption of zinc ions from rinsing water was determined. There may be a possibility of the formation of complexes in the cation-exchange resin phase. It was found out in this paper that the cation-exchanger KB-2M of macroreticular structure is the most effective for the sorption of the Zn²⁺-ions from sewage and rinsing water.     

Regional moment tensor uncertainty due to mismodeling of the crust

The retrieval of earthquake moment tensor (MT) requires the response of the medium, in which seismic waves travel from the hypocenter to the stations, to be known. In inverting long-period (LP) seismic data (teleseismic and LP regional records), a gross earth model is sufficient; with decreasing periods, a more detailed model is needed. This is the case when waveforms of weak earthquakes at regional distances are to be inverted. Regional moment tensors (RMTs) of mostly Mediterranean earthquakes are determined on a routine basis by the Swiss Seismological Survey (SED) by using averaged models of the earth's crust. By inverting broad-band records of the M_w=4.8 earthquake near Udine, N Italy, on Feb. 14, 2002, we tested the sensitivity of the MT solution with respect to possible errors in the earth model used and in the location of the hypocenter depth. We perturbed the P and S velocities and the thickness in the 1-D earth model in the range from 3% to 30% of the parameter values and constructed estimates of confidence regions of the MT and error bars of the source time function (STF) and scalar moment in three frequency bands. Similarly, these error characteristics were determined assuming a mislocation in the hypocenter depth. We found that, in the band of periods from 25 to 50 s, the mechanism is resolved well (at the confidence level 95% at least) up to an earth model uncertainty of 30%, in the passband 10–25 s up to about 10%, but it is undetermined completely at periods of 5–10 s. An error in hypocenter depth of as much as double the value reported by the location procedure does not destroy the resolution of the mechanism at periods above 10 s. In the RMT catalog of the SED, earthquakes of M_w greater than about 3.5 are processed at periods above 30 s; thus, the solutions for these events are robust with respect to a possible uncertainty in the earth model used. Mechanisms of weaker earthquakes, retrieved from short periods, should be interpreted with caution.     

湿地旅游生态约束机制研究

引入湿地旅游资源"资产化管理"和"生态承载能力"两个概念,通过资源资产化管理厘清湿地生态资源所有权和经营权关系,着眼于源头市场化监管,责任约束;通过生态承载能力监控,将湿地生态旅游开发限制在生态良好可控范围之内,从而形成以生态向好带动旅游开发,以旅游开发促进生态投入的良性均衡形态。     

Governance and technology transfer in the Clean Development Mechanism in India

Despite significant technological advances in emerging economies, the further development of clean energy technologies in developing countries remains crucial to reducing the greenhouse gas emissions associated with economic development. In this paper we address two significant gaps in the growing body of literature that has assessed the role of the Clean Development Mechanism in promoting the transfer of clean technologies to developing countries. First, we present a qualitative analysis of the governance of the Clean Development Mechanism in India. This provides a basis for understanding the extent to which and the ways in which governance may impact upon the likelihood that projects promote technology transfer. Second, we provide a novel quantification of the level and nature of technology transfer that has occurred in Indian Clean Development Mechanism projects, based on insights from literature on technological capability building. We find that the Clean Development Mechanism in India has produced a negligible number of projects that promote technology transfer if technology transfer is understood as a process of learning about technology. Together these qualitative and quantitative analyses show how politics and governance have contributed to the current form of the Clean Development Mechanism market in India, in which processes of building indigenous technological capabilities have been neglected.     

对蓬安县三元水库大坝外坡裂缝产生的原因及整治工程的探讨

本文通过对蓬安县三元水库大坝外坡裂缝产生的原因分析，进而运用岩、土力学的理论与方法反算推论出了裂缝的产生不是深层坝体土滑动引起的，而是局部浅层坝体土在水的诱发作用下作蠕滑-拉裂变形所产生的。在明确了大坝裂缝产生的原因后，提出了一系列相应整治工程措施，以达到彻底根治裂缝和稳固大坝的目的。     

晚石炭世腕足动物古生物地理区形成机制—环境控制论

晚石炭世腕足动物地理分布以及散布过程受环境控制。在控制腕足动物地理分布的诸多环境因素中，温度是首要因素，板块构造亦具巨大影响。在腕足动物散布过程中，温度的驱赶作用，洋流的携带作用，海浸与海退等环境因素犹如传送带一样，将腕足动物（幼虫）携带到能满足其生态需要的生存、繁衍场所。腕足动物具快速散布的潜能，该潜能的发挥取决于环境。由于研究的类别以及其所处地质年代不同，各种环境因素控制作用的主次地位可能变更。这就是环境控制论的主要内容。     

大化水库地震分析

大化水库自1983年蓄水后出现频繁的微弱地震,延续时间达7年,最大震为Ms1.7级,地震系列属震群型,初步判断属水库诱发地震。由于库区有活动断层且岩溶发育,地震诱发机制可能为断层孔隙水压力效应或岩液塌陷。从地震发展趋势分析,目前已处于衰减程过,预测今后不会有强震发生。     

晶体生长机理

从扩散控制，成核控制，位错控制和综合控制等几个方面阐述了自溶液中生长晶体的晶体生长机理．     

热带海气耦合距平模式中的ENSO循环及其形成机制

本文研制设计了一包含海洋表面边界层和大气辐合反馈过程的热带太平洋海气耦合异常模式。进而利用该模式对ＥＮＳＯ循环进行了成功的模拟。通过对模式ＥＮＳＯ循环的演变特征及其形成机制的细致分析，揭示了ＥＮＳＯ暖位相的一种机制。     

快速工业化区域土地利用变迁机制研究:发展模式视角——以佛山市南海区为例

从发展模式及其变迁的全新视角研究快速工业化区域土地利用变迁,有利于深刻揭示发展模式对区域土地利用变迁的重要影响机制,从而为制定合理有效的调控对策提供理论依据。文中利用历史普查、更新调查和逐年统计数据,结合卫星影像资料和实地调研,在简要分析典型案例区域佛山市南海区耕地变化和建设用地扩张时空特征的基础上,重点从发展模式及其变迁的视角,综合研究快速工业化区域土地利用变迁的动力机制与过程,并进一步探讨新形势下区域发展与土地利用的耦合调控对策。