The energy balance experiment EBEX-2000. Part II: Intercomparison of eddy-covariance sensors and post-field data processing methods

The eddy-covariance method is the primary way of measuring turbulent fluxes directly. Many investigators have found that these flux measurements often do not satisfy a fundamental criterion—closure of the surface energy balance. This study investigates to what extent the eddy-covariance measurement technology can be made responsible for this deficiency, in particular the effects of instrumentation or of the post-field data processing. Therefore, current eddy-covariance sensors and several post-field data processing methods were compared. The differences in methodology resulted in deviations of 10% for the sensible heat flux and of 15% for the latent heat flux for an averaging time of 30 min. These disparities were mostly due to different sensor separation corrections and a linear detrending of the data. The impact of different instrumentation on the resulting heat flux estimates was significantly higher. Large deviations from the reference system of up to 50% were found for some sensor combinations. However, very good measurement quality was found for a CSAT3 sonic together with a KH20 krypton hygrometer and also for a UW sonic together with a KH20. If these systems are well calibrated and maintained, an accuracy of better than 5% can be achieved for 30-min values of sensible and latent heat flux measurements. The results from the sonic anemometers Gill Solent-HS, ATI-K, Metek USA-1, and R.M. Young 81000 showed more or less larger deviations from the reference system. The LI-COR LI-7500 open-path H₂O/CO₂ gas analyser in the test was one of the first serial numbers of this sensor type and had technical problems regarding direct solar radiation sensitivity and signal delay. These problems are known by the manufacturer and improvements of the sensor have since been made. The National Center for Atmospheric Research is supported by the National Science Foundation.     

Alternative Validation of a LC-MS/MS-Multi-Method for Pesticides in Drinking Water

The development of instrumental analytics such as the LC-MS/MS has made it possible to quickly determine many component concentrations in a single chromatogram. However, the validation of such multi-methods needs new strategies for robustness and optimization. Statistical execution of analytical tests is one tool that can be utilized to meet this requirement. A Central Composite Design (CCD) was utilized for the validation of an LC-MS/MS multi-method for 84 analytes. The experimental design includes six design variables and two non-design variables (response variables). Concentration, ionization temperature, dwell time, gradient, flow (of eluent), and spraying/curtain gas (continuous design variables) were varied on five different levels; the whole design encompassed 91 runs. To investigate the robustness of a LC-MS/MS method both peak sensitivity and chromatographic separation had to be verified. Therefore, two non-design variables were necessary. The distribution of the peaks over analysis time was applied to describe the quality of the chromatographic separation. The sensitivity was described with the signal to noise ratio (S/N). The evaluation of the measured data was accomplished with the Analysis of Variance (ANOVA) and the Response Surface Methodology (RSM). Three main effects (concentration, ionization temperature, dwell time) and no significant interaction effect were found for the response variable “S/N”. The variables of concentration, ionization temperature, and dwell time had no significant effects for the response variable “S/N”. The ANOVA of the response variable chromatographic separation abandoned no significant effects as well. Therefore, robustness of the method can be guaranteed for all non significant design variables.     

Quasi-stationary flow structure in turbidity currents

A turbidity current is a particle-laden current driven by density differences due to suspended sediment particles. Turbidity currents can transport large amounts of sediment down slopes over great distances, and play a significant role in fluvial, lake and submarine systems. To better understand the sediment transport process, the flow system of an experimentally produced turbidity current in an inclined flume was investigated using video processing. We observed that the current progresses with constant frontal velocity and maintains an unchanged global interface geometry. In addition, the spatio-temporal profiles of the inner mean and turbulence velocity obtained by ultrasound velocity profiler (UVP) showed that similar distributions were maintained, with low dissipation. The results indicate that the turbidity current progressed in a quasi-stationary state, which enabled long-distance sediment transport. To understand the mechanisms behind the quasi-stationary flow, we analyzed the forces acting on the turbidity current. We found that under particular densities of suspended particles, the gravitational force is balanced by the viscous forces along the slope direction. We conclude that this specific force balance induces the quasi-stationary flow structure, enabling the long-distance transport of a substantial amount of sediment downstream with low dissipation.     

Mass flows and river response in rapid uplifting regions – A case of lower Yarlung Tsangpo basin,southeast Tibet,China

The fluvial geomorphology in tectonically active (particularly rapid uplift) regions often undergoes continuous change. The rapid uplift is coincident with high erosion rates; consequently, incised valleys are formed. Mass flows (for example, avalanches, landslides, and debris flows) in incised valleys can markedly influence fluvial processes and even reshape valley geomorphology. However, these processes and long-term evolution corresponding to mass flows require further clarification. Field campaigns were carried out in the region near the Yigong Tsangpo and Palong Tsangpo Rivers (hereafter the Yigong and Palong Rivers), the two largest tributaries of the lower Yarlung Tsangpo River, to examine the feedback between fluvial processes and mass flows. Remote sensing images from recent decades were used to compare the channel morphology before and after typical mass flows (particularly catastrophic ones). The morphology of the lower Yigong River has evidently been impacted by landslides, while that of the Palong River has mainly been shaped by glacial processes and debris flows. At present, the morphology of the latter consists of alternating sections of gorges and wide valleys, with a staircase-like longitudinal profile. The gorge sections exhibit single and deeply incised channels with a high-gradient channel bed and terraces. In contrast, the wide valley sections consist of lakes, braided or anabranching channels, gentle bed gradients, and thick alluvial deposits. Debris flows occur more frequently in gullies in the reaches of the gorge sections and rarely in gullies along the wide valley sections. The occurrence of mass flow events has resulted in an imbalance of the previous (quasi-)equilibrium in the river morphology; however, this has triggered negative feedback that is driving the transient river morphology to a new state of (quasi-)equilibrium.     

Geological factors influencing the concentration of trace elements in the Philippi peatland, eastern Macedonia, Greece

Six peat samples obtained from the Holocene and the Weichselian of the Philippi peat deposit, eastern Macedonia, Greece, were analyzed for 48 trace elements by Inductively Coupled Plasma–Mass Spectrometry (ICP–MS). The ash contents of these samples were also determined. Most of the trace elements are associated with the minerals in the peat, while Ge, Mo, Pb, Se, Ta, Tl, U, and W display a greater affinity with the organic matter. Compared with crustal averages (Clarke concentrations), the Philippi peat is enriched in some elements (Ag, As, Au, Cd, Mo, Se, Te, U, and W) because of the respective mineralizations in the area. The Philippi peat is also enriched in Cr, Cu, Mo, Pb, Sc, Sn, T, V, Y, and Zn in comparison with typical fen peats, as well as in As, Cr, Mo, Se, and U in comparison with typical coals. Climatic and hydrogeological conditions strongly influenced the peat-forming environment resulting in a differentiation between Holocene and Weichselian peat. Generally, the Holocene peat contains lower concentrations of trace elements in the northern and southern part of the fen, than the Weichselian one. The opposite trend is observed in the fen area close to the western basin margins.     

Erosion and deposition by debris flows at Mt Thomas,North Canterbury,New Zealand

The grass-covered slopes on the southern flank of Mt Thomas, an upfaulted block of highly sheared sandstone and argillite 40 km NW of Christchurch, New Zealand, are presently undergoing severe erosion by a combination of mass-wasting processes. Gully erosion, soil slips, and debris flows have carved out a number of steep, deeply incised ravines, from which coarse debris is transported (primarily by debris flows) to alluvial fans below. Geologic and historical evidence indicates that debris flows have been episodically active here for at least the last 20,000 years and have been the dominant process in fan building. This demonstrates that catastrophic geomorphic processes, rather than processes acting at relatively uniform rates, can be dominant in humid-temperate areas as well as in arid and semi-arid regions. In April 1978, debris flows were triggered in one of two unstable ravines in the Bullock Creek catchment by a moderate intensity, long duration rainstorm with a return period in excess of 20 years. Surges of fluid debris, moving at velocities up to 5 m/s, transported a dense slurry of gravel, sand, and mud up to 3·5 km over a vertical fall of 600 m. Deposition on the alluvial fan occurred when the flows left the confines of an entrenched fan-head channel and spread out as a 0·16 km² sheet averaging 1·2 m thick. In all, 195,000 m³ were deposited, roughly a third of that being reworked sediments from the head of the fan. Sediment yield from this one event would be equivalent to several thousand years worth of erosion at average sediment discharge rates for small South Island mountain catchments. Samples of viscous fluid debris during surges contained up to 84 per cent solids, composed of 70 per cent gravel, 20 per cent silt, and 4 per cent clay. Fluid density of the material ranged between 1·95 and 2·13 g/cm³, and it was extremely poorly sorted. Between surges the fluid was less viscous, less dense, and unable to carry gravel in suspension. Severe fan-head entrenchment of the stream channel (approximately 10 m in less than 24 hours) was accomplished by the erosive action of the surges. Tectonic uplift of the Mt Thomas block and the weak, crushed condition of the bedrock appear to be ultimately responsible for the catastropic erosion of slopes in the Bullock Creek catchment. However, forest clearing within the last few centuries appears to have greatly increased the rate of mass wasting and gully erosion on these slopes.     

The numerical simulation on the PBL structure and its evolution over small-scale concave terrain

A high-resolution, nonhydrostatic, three-dimensional diagnostic PBL model over small-scale concave terrain was established in this paper. A two-dimensional prognostic model was developed based on the diagnostic model. The hydrostatic approximation was abandoned and the simple energy (E-ε) closure scheme was used in both mod-els. Using the two models, characteristics of PBL structure and its evolution were fully studied. The main characteris-tic of the PBL is the circulation, and it fairly affects the distribution of the pollutant in the pit.     

Impact of Boundary-Layer Parameterisation Schemes on the Prediction of the Asian Summer Monsoon

The impact of two boundary-layer parameterisation schemes on the prediction of Indian monsoon systems by a global spectral model has been investigated. The turbulent kinetic energy closure scheme shows a positive impact on the prediction of some important synoptic features, including the genesis of monsoon lows, the tracking of monsoon depressions, and precipitation.     

Analysis of Astex-Stratocumulus Observational Data Using a Mass-Flux Approach

A mass-flux approach is applied to observational data obtained in a convective boundary layer topped with stratocumulus clouds. The observational data were obtained from aircraft measurements during the Atlantic Stratocumulus Transition Experiment (ASTEX). A conditional sampling method is used to calculate average updraft and downdraft values. The vertical fluxes calculated with the mass-flux approach are found to be proportional to the real (measured) fluxes, with a proportionality factor being about 0.6. This value is predicted by theory for two variables having a joint Gaussian distribution function; proportionality factor = 2^-1 0.637. The horizontal fractional entrainment and detrainment rates calculated from the data ( 1–2 × 10^-2 m^-1) are an order of magnitude higher than the rates obtained by large eddy simulations for cumulus convection ( 2–3 × 10^-3 m^-1) and two orders of magnitude higher than those used in modelling cumulus convection with a mass-flux scheme in an operational weather forecast model ( 3 × 10^-4 m^-1). A numerical mass-flux model for the thermodynamics was developed and showed that results are in good agreement when compared with measured profiles of the liquid water content.     

An effect of closure on the structure of principal components

The principal components transformation generates, from any data array, a new set of variables—the scores of the components—characterized by a total variance exactly equal to that of the initial set. It is in this sense that the transformed variables are said to contain, preserve, or account for, the variance of the original set. The scores, however, are uncorrelated. In the course of the transformation, what becomes of the strong interdependence of variance and covariance so characteristic of closed arrays? The question seems to have attracted little attention; we are aware of no study of it in the earth sciences. Experimental work reported here shows quite clearly that the overall equivalence of variance and covariance imposed by closure, though absent from the component scores,may emerge in relations between the coefficientsof each of the lower-order components; if the raw data are complete rock analyses, the sum of all the covariances of the coefficients of such a component is negative, and is very nearly equal to the sum of all the variances in absolute value. (In all cases so far examined, the absolute value of the first sum is a little less than that of the second.) The principal components transformation provides an elegant escape from closure correlation if a petrographic problem can be restated entirely in terms of component scores, but not if a physical interpretation of the component vectors is required.