An infrared and <Superscript>1</Superscript>H MAS NMR investigation of strong hydrogen bonding in ussingite,Na<Subscript>2</Subscript>AlSi<Subscript>3</Subscript>O<Subscript>8</Subscript>(OH)

The mineral ussingite, Na₂AlSi₃O₈(OH), an interrupted tectosilicate, has strong hydrogen bonding between OH and the other nonbridging oxygen atom in the structure. Infrared spectra contain a strongly polarized, very broad OH-stretching band with an ill-defined maximum between 1500 and 1800 cm^–1, and a possible OH librational bending mode at 1295 cm^–1. The IR spectra confirm the orientation of the OH vector within the triclinic unit cell as determined from X-ray refinement (Rossi et al. 1974). There are three distinct bands in the ¹H NMR spectrum of ussingite: a predominant band at 13.5 ppm (TMS) representing 90% of the structural hydrogen, a second band at 15.9 ppm corresponding to 8% of the protons, and a third band at 11.0 ppm accounting for the remaining 2% of structural hydrogen. From the correlation between hydrogen bond length and ¹H NMR chemical shift (Sternberg and Brunner 1994), the predominant hydrogen bond length (H...O) was calculated to be 1.49 Å, in comparison to the hydrogen bond length determined from X-ray refinement (1.54 Å). The population of protons at 15.9 ppm is consistent with 5–8% Al–Si disorder. Although the ussingite crystal structure and composition are similar to those of low albite, the bonding environment of OH in low albite and other feldspars, as characterized through IR and ¹H NMR, is fundamentally different from the strong hydrogen bonding found in ussingite.     

Linking past flood frequencies in Norway to regional atmospheric circulation anomalies

Analysis of two continuous, high‐resolution palaeo‐flood records from southern Norway reveals that the frequency of extreme flood events has changed significantly during the Holocene. During the early and middle Holocene, flood frequency was low; by contrast, it was high over the last 2300 years when the mean flood frequency was about 2.5–3.0 per century. The present regional discharge regime is dominated by spring/summer snowmelt, and our results indicate that the changing flood frequency cannot be explained by local conditions associated with the respective catchments of the two lakes, but rather long‐term variations of solid winter precipitation and related snowmelt. Applying available instrumental winter precipitation data and associated sea‐level pressure re‐analysis data as a modern analogue, we document that atmospheric circulation anomalies, significantly different from the North Atlantic Oscillation (NAO), have some potential in explaining the variability of the two different palaeo‐flood records. Centennial‐scale patterns in shifting flood frequency might be indicative of shifts in atmospheric circulation and shed light on palaeo‐pressure variations in the North Atlantic region, in areas not influenced by the NAO. Major shifts are found at about 2300, 1200 and 200 years ago (cal. a BP). Copyright © 2011 John Wiley & Sons, Ltd.     

北极涛动对青藏高原冬季变暖的影响

基于青藏高原地区1960-2010年高分辨率(0.5°×0.5°)的逐日地面气温格点资料以及 1960-2010年NCEP/NCAR全球月平均海平面气压场、高度场、风场的再分析格点资料(2.5°×2.5°), 通过计算青藏高原(74.75°~104.25° E, 26.75°~40.25° N)冬季地面温度平均值经标准化处理后得到的区域冬季气温强度指数, 分析了冬季北极涛动(AO)、西伯利亚高压与同期青藏高原地面气温的特征和关系. 结果表明: AO为负(正)相位时, 中高纬西风气流偏弱(强), 有(不)利于极地冷空气向南输送, 西伯利亚地区源地冬季风偏强(弱), 青藏高原冬季气温指数减小(增大), 地面气温偏低(高). 对AO作M-K突变分析, 发现其突变年份为1975年, 通过对突变年份前后高度场和风场作差值场分析, 结果显示: 冬季AO处于高指数时期, 500 hPa上, 欧洲东部槽变浅, 青藏高原北部的高压脊减弱, 环流呈纬向发展, 青藏高原上盛行偏南风, 气温偏高, 青藏高原地区为暖冬期; 200 hPa 上, 青藏高原东部的槽明显加深, 使得青藏高原地区对流层顶至平流层底的环流趋势以经向发展为主, 该区域主要受到偏北的急流控制, 易导致降温.     

吉林腰英台油田油水分布特征及成因探讨

腰英台油田是东北地区新发现的油田，目前刚开始勘探开发，在勘探开发初期遇到不少问题。其中之一是开采时高含水：就油田的实际油水分布特征进行了分析，分析油水同出的可能原因，认为这是受油藏储层物性及构造幅度和实际油柱高度的影响，由于储层低孔、特低渗。实际构造幅度低，实际油柱高度大多低于油藏产纯油所需的油柱高度，致使油藏大都处于油水过渡带。故开采时多含水，油水同出。根据这一分析，认为进一步的油气勘探重点考虑西部水下冲积扇的有利部位。此处储层物性好，有利于接受更多油源。     

上部地壳的流体作用与大理岩的低温塑性

本文应用光学显微镜、透射电子显微镜和阴极发光显微镜系统研究了Ｗａｔｅｒｂｅｒｇ断层带（纳米比亚）内粗晶大理岩中发育的构造岩,宏观碎裂结构与微观糜棱装结构是断层构造岩的主要特点。巨大的孪形碎屑与弥漫的细小粒质形成了鲜明的反差,广泛发育的压溶颖合线与多阶段方解石细脉遍布构造带不同部位,ＴＥＭ亚微粒粒度具有简单的峰值分布（～０．３～０．４μｍ）,但动态重结晶颗粒的粒度却具有较大的变化范围（０．１～３．０     

Development of a new method for efficiently calculating of evaporation from the phreatic aquifer in variably saturated flow modeling

In this paper, we proposed a new method that has been developed based on the surface soil moisture content (SSMC) to more efficiently calculate the groundwater evaporation in variably saturated flow modeling. In this method, the empirical formula to calculate evaporation was modified and the value of the formula varies from zero to one as a closed interval. In addition, the simulation code for calculating the groundwater evaporation based on the SSMC method was incorporated into the EOS9 module of Tough2, a variably saturated flow modeling code. Finally, two numerical tests and a case simulation were conducted to verify the feasibility and accuracy of the SSMC method. Simulation results indicate that the SSMC method is capable of appropriately simulating the characteristics of water flow in vadose zone and the amount of evaporation with the variable water table. And such results are in coincidence with the value calculated by the logistic function method, and fit well with the measured data globally rather than locally.     

Recent Precipitation Trends in Hungary in the Context of Larger Scale Climatic Changes

The time series of monthly precipitation totals from 14 Hungarian observing stations (1901–1998) were analysed to reveal the long term changes in precipitation characteristics occurred in the 20th century. A particular attention was given to the changes in the recent decades and their links with the larger scale climatic and circulation changes over Europe and the Atlantic.The statistical significancesof systematic changes are controlled by linear trend analysis and the Mann–Kendall test. The long term fluctuations are illustrated applying a 15-point Gaussian filter on the time series. The Standardised Precipitation Index is used to evaluate the changes in the drought event frequency. The relationships with larger scale changes are mostly discussed relying on contemporary papers, and the Grosswetterlagen Catalogue is used as well.The annual precipitation total decreased by 15–20% in Hungary during the 20th century. The decline is substantial in both halves of the century, but the precipitation sums in the transition seasons declined in the first 50 years, and the winter precipitation decreased in the latest decades. The precipitation total of the period November–February declined significantly in the last 50 years. In the same time the mean winter value of the North Atlantic Oscillation Index (NAOI) increased, the positions of the main pressure patterns over the Atlantic are shifted northeastward, and lot of other coherent changes detected in the winter climate of the European–Atlantic region. The mean summer precipitation total has hardly changed, but the frequency of summer drought events increased. There are some signs of a shift of the Hungarian summer climate towards a Mediterranean like climate.     

富宁阳文冲-广南菜子垣热液淋滤卡林型金矿区

金矿区构造活动具有多期性：加里东期及海西期在矿区形成的薄弱角度不整合面、近南北向平行的滑脱断层,是含矿热液的运移、沉淀的通道和空间。金矿床应属地下热液淋滤卡林型金矿床。     

Weakness and mechanical anisotropy of phyllosilicate-rich cataclasites developed after mylonites of a low-angle normal fault (Simplon Line,Western Alps)

The Simplon Fault Zone is a late-collisional low-angle normal fault (LANF) of the Western Alps. The hanging wall shows evidence of brittle deformation only, while the footwall is characterized by a c. 1 km-thick shear zone (the Simplon Fault Zone), which continuously evolved, during exhumation and cooling, from amphibolite facies conditions to brittle-cataclastic deformations. Due to progressive localization of the active section of the shear zone, the thermal-rheological evolution of the footwall resulted in a layered structure, with higher temperature mylonites preserved at the periphery of the shear zone, and cataclasites occurring at the core (indicated as the Simplon Line). In order to investigate the weakness of the Simplon Line, we studied the evolution of brittle/cataclastic fault rocks, from nucleation to the most mature ones. Cataclasites are superposed on greenschist facies mylonites, and their nucleation can be studied at the periphery of the brittle fault zone. This is characterized by fractures, micro-faults and foliated ultracataclasite seams that develop along the mylonitic SCC′ fabric, exploiting the weak phases mainly represented by muscovite and chlorite. Approaching the fault core, both the thickness and frequency of cataclasite horizons increase, and, as their thickness increases, they become less and less foliated. The fault core itself is represented by a thicker non-foliated cataclasite horizon. No Andersonian faults or fractures can be found in the footwall damage zone and core zone, whilst they are present in the hanging wall and in the footwall further from the fault. Applying a stress model based on slip tendency, we have been able to calculate that the friction coefficient of the Simplon Line cataclasites was <0.25, hence this fault zone is absolutely weak. In contrast with other fault zones, the weakening effect of fluids was of secondary importance, since they accessed the fault zone only after an interconnected fracture network developed exploiting the cataclasite network.     

Low-pressure evolution of arc magmas in thickened crust: The San Pedro–Linzor volcanic chain,Central Andes,Northern Chile

Magmatism at Andean Central Volcanic Zone (CVZ), or Central Andes, is strongly influenced by differentiation and assimilation at high pressures that occurred at lower levels of the thick continental crust. This is typically shown by high light to heavy rare earth element ratios (LREE/HREE) of the erupted lavas at this volcanic zone. Increase of these ratios with time is interpreted as a change to magma evolution in the presence of garnet during evolution of Central Andes. Such geochemical signals could be introduced into the magmas be high-pressure fractionation with garnet on the liquidus and/or assimilation from crustal rocks with a garnet-bearing residue. However, lavas erupted at San Pedro–Linzor volcanic chain show no evidence of garnet fractionation in their trace element patterns. This volcanic chain is located in the active volcanic arc, between 22°00^′S and 22°30^′S, over a continental crust ∼70 km thick. Sampled lavas show Sr/Y and Sm/Yb ratios <40 and <4.0, respectively, which is significantly lower than for most other lavas of recent volcanoes in the Central Andes. In addition, ⁸⁷Sr/⁸⁶Sr ratios from San Pedro–Linzor lava flows vary between 0.7063 and 0.7094. This is at the upper range, and even higher than those observed at other recent Central Andean volcanic rocks (<0.708). The area in which the San Pedro–Linzor volcanic chain is located is constituted by a felsic, Proterozoic upper crust, and a thin mafic lower crustal section (<25 km). Also, the NW–SE orientation of the volcanic chain is distinctive with respect to the N–S orientation of Central Andean volcanic front in northern Chile. We relate our geochemical observations to shallow crustal evolution of primitive magmas involving a high degree of assimilation of upper continental crust. We emphasize that low pressure AFC- (Assimilation Fractional Crystallization) type evolution of the San Pedro–Linzor volcanic chain reflects storage, fractionation, and contamination of mantle-derived magmas at the upper felsic crust (<40 km depth). The ascent of mantle-derived magmas to mid-crustal levels is related with the extensional regime that has existed in this zone of arc-front offset since Late-Miocene age, and the relatively thin portion of mafic lower crust observed below the volcanic chain.