空间思维视角下李白漫游轨迹与其诗歌风格形成的关系解析

从地理空间分析的角度对李白的漫游轨迹以及诗歌中的地理空间进行研究,分析李白的行为空间与诗歌空间。研究表明:(1)李白行程数的积累为他的诗歌创作奠定了基础;(2)在政治行为空间内,李白的空间行为被放大。对于李白来说,政治行为空间对他的影响最大;(3)李白的诗歌风格很大部分在于他在漫游中建立的阔大的空间想象力以及他一生都在不停追求的政治愿望。     

Development of Synthetic Clinopyroxene Reference Materials for In Situ Lithium Isotope Measurement by LA-MC-ICP-MS

The isotopic composition of lithium (Li) in clinopyroxene (Cpx), determined via in situ micro-analysis, has been employed as a potential geochemical tool for studying various geological processes such as crust-mantle recycling, silicate weathering and fluid-rock interaction. To obtain precise and accurate Li isotopic compositions in Cpx by LA-MC-ICP-MS, synthetic Cpx matrix-matched reference materials (RMs) were prepared in this study. Six Cpx-matrix RMs were prepared by mixing metallic oxides with GSP-2 (granodiorite) or pure L-SVEC solution and melting them into glasses (GSP-2 + oxide; L-SVEC + oxide). Two representative synthetic glasses, CPXA01 and CPXB01, were subjected to a series of analyses to investigate the possible qualification of the RMs for in situ Li isotope measurement by LA-MC-ICP-MS, including elemental homogeneity analysis (elemental mapping analysis and spot analysis), Li isotopic homogeneity analysis and accurate Li isotopic determination. The applicability of the synthetic Cpx-matrix RMs was highlighted by comparing the δ⁷Li values of three natural Cpx calibrated against the synthetic Cpx-matrix RMs and other commonly used RMs with different matrices (NIST SRM 612, BCR-2G, GOR128-G, StHs6/80-G, KL2-G and T1-G), respectively. Additionally, CPXB01-05 RMs with the same matrix but different Li contents were prepared to explore the Li content mismatch effect, which is significant for accurate determination of in situ Li isotopic composition by LA-MC-ICP-MS. The results of the cross-calibration of Li isotopes in CPXA01 and CPXB01 suggested no obvious Li isotopic fractionation between the two types of glasses (GSP-2 + oxide; L-SVEC + oxide). Thus, the two methods of producing Cpx-matrix RMs are suitable for preparing the matrix-matched RMs for in situ microanalysis for Li isotopes.     

Recognition of the hydrogeological potential using electrical sounding in the Khemisset-Tiflet region,Morocco

The low recharge of reservoirs and the increasing demand for water limit the potential of mobilized resources, especially in arid to semi-arid areas like Morocco. Integrated management is essential to safeguard this resource. In respect with this perspective, this work provides the analysis of hydrogeological potential of Khemisset-Tiflet region, which falls within the action area of the Sebou Hydraulic Basin Agency. The basis of our studies was as follows:(1) The interpretation of the existing geoelectric data;(2) application of geophysical methods for non-destructive reconnaissance and their integration into a Geographic Information System(GIS). The analysis demonstrates that: The map of the isohypses and the geoelectric cross-section of the substratum of the superficial roof aquifer show clearly a plunge associated with development of the Paleozoic roof in the South and the direction of flow of the surface water is from south to north, from the upper zone to the north of the El Kansera dam. These conclusions constitute very useful contribution for any resource management projects in this area.     

Vibrational spectroscopy of beta-eucryptite (LiAlSiO<Subscript>4</Subscript>): optical phonons and phase transition(s)

The structural behavior of -eucryptite (LiAlSiO₄) has been investigated using infrared (IR) spectroscopy over a temperature range of 20 to 900 K and FT-Raman spectroscopy at room temperature. IR reflectance measurements show that -eucryptite possesses high reflectivity in the far-IR region, as is consistent with its reported superionic conductivity along the c-axis. On heating, the Li-related IR bands near 246 and 300 cm^–1 (with A₂ symmetry) broadened and weakened dramatically, presumably as a result of Li⁺ positional disordering along the structural channels parallel to c. The disordering process appears to induce a framework distortion, as is evidenced by the broadening of some vibrations of Si(Al)–O with increasing temperature. A change in slope in the temperature dependence of the phonon frequency near 300 cm^–1 and the linewidth of the 760 cm^–1 band at 715 K indicates that Li becomes completely disordered above this temperature. In addition, the temperature dependence of the linewidth for the 760 cm^–1 band exhibits an additional change in slope at 780 K, implying the existence of an intermediate state within this temperature range. The detailed structure of this intermediate phase, however, needs further study. Our IR data provide no indication of structural changes between room temperature and 20 K.     

祁连党河南山北坡中-基性火山岩地质特征及时代

根据地质研究、区域对比，结合首次获得的Rb-Sr等时线年龄数据，从祁连党河南山(又称乌兰达坂山）北坡原中奥陶统地层中厘定出晚震旦纪中－基性火山岩系。根据这一新成果，认为该区中基性火山岩，斜长角闪岩基底以及侵入其中的扎子沟等花岗闪长岩岩基在大地构造分区上应划归中祁连地块；晚震旦纪该区无疑有过扩张、地壳减薄的地质事件，震旦纪晚期有过挤压闭合事件。     

美国西部Owens湖地球化学记录及其古气候意义

美国加州中部Owens湖的稳定同位素、稀酸可溶相锂元素浓度及其它地球化学指标揭示本区0.155MaB.P.～62500aB.P.间的气候变化。在0.155～0.140MaB.P.,0.122～0.114MaB.P.,91000～83000aB.P.和72000～62500aB.P.期间,气候冷湿,对应于深海氧同位素(MIS)6,5d,5b和4阶段。这些期间内湖泊开放,^δ18 O和^δ13 C无协变性,Li和有机碳浓度很低。在0.140～0.122MaB.P.,0.114MaB.P.～91000aB.P.和83000～72000aB.P.期间,气候干热,对应于MIS5e,5c和5a阶段。湖泊在这些期间内封闭,^δ18 O和^δ13 C有很好的协变性,封闭湖^δ18 O的变化代表了湖水体积的变化。来自湖中自生镁硅酸盐的锂元素浓度的变化反映了盐度和温度的变化。Owens湖的记录与DevilsHole洞穴流石记录和格陵兰冰芯记录有很好的对比,进一步证实了终结期Ⅱ在海相记录中的年龄滞后。本文讨论了冰期与间冰期之间,美国西部和中国黄土地区气候模式的差异及其互动机制。     

Sodic Pyroxene and Sodic Amphibole as Potential Reference Materials for In Situ Lithium Isotope Determinations by SIMS

Two large pegmatitic crystals of sodic pyroxene (aegirine) and sodic amphibole (arfvedsonite) from the agpaitic igneous Ilímaussaq Complex, south Greenland were found to be suitable as reference materials for in situ Li isotope determinations. Lithium concentrations determined by SIMS and micro‐drilled material analysed by MC‐ICP‐MS generally agreed within analytical uncertainty. The arfvedsonite crystal was homogeneous with [Li] = 639 ± 51 μg g^?1 (2s, n = 69, MC‐ICP‐MS and SIMS results). The aegirine crystal shows strongly developed sector zoning, which is a common feature of aegirines. Using qualitative element mapping techniques (EPMA), the homogeneous core of the crystal was easily distinguished from the outermost sectors of the crystals. The core had a mean [Li] of 47.6 ± 3.6 μg g^?1 (2s, n = 33) as determined by SIMS. The seven micro‐drilled regions measured by solution MC‐ICP‐MS returned slightly lower concentrations (41–46 μg g^?1), but still overlap with the SIMS data within uncertainty. Based on MC‐ICP‐MS and SIMS analyses, the variation in δ⁷Li was about 1‰ in each of the two crystals, which is smaller than that in widely used glass reference materials, making these two samples suitable to serve as reference materials. There was, however, a significant offset between the results of MC‐ICP‐MS and SIMS. The latter deviated from the MC‐ICP‐MS results by ?6.0 ± 1.9‰ (2s) for the amphibole and by ?3.9 ± 1.9‰ (2s) for the aegirine. This indicates the presence of a significant matrix effect in SIMS determinations of Li isotopes for amphibole and pyroxene relative to the basalt glasses used for calibration. Based on the MC‐ICP‐MS results, mean δ⁷Li values of +0.7 ± 1.2‰ (2s, n = 10) for the arfvedsonite crystal and of ?3.7 ± 1.2‰ (2s, n = 7) for the core of the aegirine crystal were calculated. Adopting these values, SIMS users can correct for the specific IMF (instrumental mass fractionation) of the ion probe used. We propose that these two crystals serve as reference materials for in situ Li isotope determinations by SIMS and pieces of these two crystals are available from the first author upon request.     

都江堰水利系统的地球科学思想

岷江中游的都江堰水利系统为256BC战国时代蜀郡太守李冰主持修建,经长期发展完善,至今仍发挥着巨大的作用,为世界上使用历史最长的古老水利系统.该水利系统利用岷江由上游山区进入中游平原的自然条件,根据河流地质作用的原理,因地制宜,因势利导,修建了分流、泄洪、治沙和引水等工程,达到了灌溉、防洪和通航的目的.而且,设置了相应的监测设施,确立了维护制度,营造了我国西部地区最大的水田农业生态区,与岷江上游山地森林生态区组成森林-水田农业生态系统.     

共轭伸展褶劈理夹角的定量解析

９０ 年代初以来,中国地质学者先后在浙、皖、赣、湘的“板溪群”及震旦系中发现了古生代的生物化石。因此,再次将“板溪群”是否是前震旦纪的一个变质地层单位、江南古陆是否存在以及华南大地构造格局是否需要重新厘定等问题提了出来。１９９３ 年笔者于赣东北蛇绿混杂岩带内的“双桥山群”岩块中,首次发现了含晚古生代的放射虫硅质岩。１９９６ 年又在该混杂岩带多处的“双桥山群”岩块和“下震旦统志棠组”中找到了含晚古生代的放射虫硅质岩,还首次在“登山群拔竹坑组”中发现了早古生代的几丁虫化石。经数年野外多次观察和对室内化石鉴定、岩石地球化学测试结果以及岩石学特征的综合分析表明,所发现的含晚古生代放射虫硅质岩及其岩石组合是一套洋盆深水相沉积;登山群拔竹坑组,是早古生代的一套浅水陆棚 深水陆棚 半深海相沉积。结合同行学者在邻区“板溪群”研究方面取得的新成果,笔者认为：“板溪群”不是前震旦纪的一个变质地层单位,而是一个复杂的构造岩带,江南古陆是不存在的,华南从早古生代到中生代早期还经历了一次洋盆演化过程,现在的构造格局是印支运动奠定的