Evolution of Hydrothermal System at the Dizon Porphyry Cu-Au Deposit, Zambales, Philippines

Abstract. Evolution of hydrothermal system from initial porphyry Cu mineralization to overlapping epithermal system at the Dizon porphyry Cu‐Au deposit in western central Luzon, Zambales, Philippines, is documented in terms of mineral paragen‐esis, fluid inclusion petrography and microthermometry, and sulfur isotope systematics. The paragenetic stages throughout the deposit are summarized as follows; 1) stockwork amethystic quartz veinlets associated with chalcopyrite, bornite, magnetite and Au enveloped by chlorite alteration overprinting biotite alteration, 2) stockwork quartz veinlets with chalcopyrite and pyrite associated with Au and chalcopyrite and pyrite stringers in sericite alteration, 3) stringer quartz veinlets associated with molybdenite in sericite alteration, and 4) WNW‐trending quartz veins associated with sphalerite and galena at deeper part, while enargite and stibnite at shallower levels associated with advanced argillic alteration. Chalcopyrite and bornite associated with magnetite in quartz veinlet stockwork (stage 1) have precipitated initially as intermediate solid solution (iss) and bornite solid solution (bnss), respectively. Fluid inclusions in the stockwork veinlet quartz consist of gas‐rich inclusions and polyphase inclusions. Halite in polyphase inclusions dissolves at temperatures ranging from 360d?C to >500d?C but liquid (brine) and gas (vapor) do not homogenize at <500d?C. The maximum pressure and minimum temperature during the deposition of iss and bnss with stockwork quartz veinlets are estimated to be 460 bars and 500d?C. Fluid inclusions in veinlet stockwork quartz enveloped in sericite alteration (stage 2) consist mainly of gas‐rich inclusions and polyphase inclusions. In addition to the possible presence of saturated NaCl crystals at the time of entrapment of fluid inclusions that exhibit the liquid‐vapor homogenization temperatures lower than the halite dissolution temperatures in some samples, wide range of temperatures of halite dissolution and liquid‐vapor homogenization of polyphase inclusions from 230d?C to >500d?C and from 270d?C to >500d?C, respectively, suggests heterogeneous entrapment of gaseous vapor and hypersaline brine. The minimum pressure and temperature are estimated to be about 25 bars and 245d?C. Fluid inclusions in veinlet quartz associated with molybdenite (stage 3) are dominated by gas‐rich inclusions accompanied with minor liquid‐rich inclusions that homogenize at temperatures between 350d?C and 490d?C. Fluid inclusions in vuggy veinlet quartz associated with stibnite (stage 4) consist mainly of gas‐rich inclusions with subordinate polyphase inclusions that do not homogenize below 500d?C. Fluid inclusions in veinlet quartz associated with galena and sphalerite (stage 4) are composed of liquid‐rich two‐phase inclusions, and they homogenize into liquid phase at temperatures ranging widely from 190d?C to 300d?C (suggesting boiling) and the salinity ranges from 1.0 wt% to 3.4 wt% NaCl equivalent. A pressure of about 15 bars is estimated for the dilute aqueous solution of 190d?C from which veinlet quartz associated with galena and sphalerite precipitated. In addition to a change in temperature‐pressure regime from lithostatic pressure during the deposition of iss and bnss with stockwork quartz veinlets to hydrostatic pressure during fracture‐controlled quartz veinlet associated with galena and sphalerite, a decrease in pressure is supposed to have occurred due to unroofing or removal of the overlying piles during the temperature decrease in the evolution of hydrothermal system. The majority of the sulfur isotopic composition of sulfides ranges from ±0 % to +5 %. Sulfur originated from an iso‐topically uniform and homogeneous source, and the mineralization occurred in a single hydrothermal system.     

Structure of Palaeogene sediments in east Ellesmere Island: Constraints on Eurekan tectonic evolution and implications for the Nares Strait problem

The “Nares Strait problem” represents a debate about the existence and magnitude of left-lateral movements along the proposed Wegener Fault within this seaway. Study of Palaeogene Eurekan tectonics at its shorelines could shed light on the kinematics of this fault. Palaeogene (Late Paleocene to Early Eocene) sediments are exposed at the northeastern coast of Ellesmere Island in the Judge Daly Promontory. They are preserved as elongate SW–NE striking fault-bounded basins cutting folded Early Paleozoic strata. The structures of the Palaeogene exposures are characterized by broad open synclines cut and displaced by steeply dipping strike-slip faults. Their fold axes strike NE–SW at an acute angle to the border faults indicating left-lateral transpression. Weak deformation in the interior of the outliers contrasts with intense shearing and fracturing adjacent to border faults. The degree of deformation of the Palaeogene strata varies markedly between the northwestern and southeastern border faults with the first being more intense. Structural geometry, orientation of subordinate folds and faults, the kinematics of faults, and fault-slip data suggest a multiple stage structural evolution during the Palaeogene Eurekan deformation: (1) The fault pattern on Judge Daly Promontory is result of left-lateral strike-slip faulting starting in Mid to Late Paleocene times. The Palaeogene Judge Daly basin formed in transtensional segments by pull-apart mechanism. Transpression during progressive strike-slip shearing gave rise to open folding of the Palaeogene deposits. (2) The faults were reactivated during SE-directed thrust tectonics in Mid Eocene times (chron 21). A strike-slip component during thrusting on the reactivated faults depends on the steepness of the fault segments and on their obliquity to the regional stress axes.Strike-slip displacement was partitioned to a number of sub-parallel faults on-shore and off-shore. Hence, large-scale lateral movements in the sum of 80–100 km or more could have been accommodated by a set of faults, each with displacements in the order of 10–30 km. The Wegener Fault as discrete plate boundary in Nares Strait is replaced by a bundle of faults located mainly onshore on the Judge Daly Promontory.     

Salinisation des nappes côtières : cas de la nappe nord du Sahel de Sfax,Tunisie

The intensive agricultural and economic activities induce the increase of the risk of groundwater quality degradation through high groundwater pumping rates. The salinization and contamination are the main sources of this pollution, especially in coastal aquifers. The explanation of the origin of salinity for the shallow aquifer of Northern Sahel of Sfax was analysed by a chemical study of the groundwater main compounds. The partitioning of groundwaters into homogenous groups is undertaken by graphical techniques, including a Stiff pattern diagram, an expanded Durov diagram and several binary diagrams. The study indicates the presence of various salinization processes. In the recharge area, salinization is the result of dissolution/precipitation of the aquifer formation material (group I). The irrigation water return and the intensive pumping have been identified as major sources of salinization in the south by direct cation exchange and mixing reactions (groups II and III). The anomaly of high groundwater salinity observed near the Hazeg zone was explained by the presence of a seawater intrusion in this area. This hypothesis is related to the high chloride concentration, to the presence of inverse cation exchange reactions (group IV), and to the piezometric level inferior to sea level. To cite this article: R. Trabelsi et al., C. R. Geoscience 337 (2005).     

Tectono-sedimentary control on modern sand deposition on the forebulge of the Western Taiwan Foreland Basin

Whether the formation of the isolated sand body deposition in the forebulge area of a foreland basin system is structure- or deposition-controlled has puzzled geologists for decades, although sand body deposition is generally believed to be indicative of the position of the flexural forebulge in a foreland basin. The formation of a modern sand body in the forebulge area is thus examined by multi-scale geophysical observations based on combined reflection seismic profiles and compressed high-intensity radar pulse (CHIRP) profiles across the sand deposition along the forebulge of the Western Taiwan Foreland Basin (WTFB), which is a Late Miocene-present foreland basin in the overfilled stage. These profiles suggest that the accumulation of the sand deposits along the forebulge of the WTFB is not directly associated with forebulge faultings. The relief map of the forebulge deposit substratum shows a northwestward tilting slope, and the isopach of the forebulge sand body indicates that a large part of the sand body accumulated along the axis of the Taiwan Strait and the subdued forebulge of the WTFB. The difference between the prevailing directions of tidal currents between the Taiwan Strait and the East China Sea reflects the probable sedimentary influence of the cratonward migrating fold-thrust belt within a foreland shelf. We suggest that the formation and distribution of the sand deposits along the forebulge of the WTFB are generally controlled not only by the transverse downslope sedimentation but also longitudinal hydrodynamic processes at distal parts of the foreland basin. Our explanation provides a plausible tectono-sedimentary cause of the sand body deposition in the forebulge area in an overfilled foreland basin. The sedimentary dynamics of the sand body in the Taiwan Strait may be applicable for understanding the formation of isolated sand bodies in the distal part of the Cretaceous Western Interior Foreland Basin.     

Deformation structures associated with the Trachyte Mesa intrusion,Henry Mountains,Utah: Implications for sill and laccolith emplacement mechanisms

Deformation structures in the wall rocks of igneous intrusions emplaced at shallow crustal depths preserve an important record of how space was created for magma in the host rocks. Trachyte Mesa, a small Oligocene age intrusion in the Henry Mountains, Utah, is composed of a series of stacked tabular, sheet-like intrusions emplaced at 3–3.5 km depth into sandstone-dominated sedimentary sequences of late Palaeozoic–Mesozoic age. New structural analysis of the spatial distribution, geometry, kinematics and relative timings of deformation structures in the host rocks of the intrusion has enabled the recognition of distinct pre-, syn-, and late-stage-emplacement deformation phases. Our observations suggest a two-stage growth mechanism for individual sheets where radial growth of a thin sheet was followed by vertical inflation. Dip-slip faults formed during vertical inflation; they are restricted to the tips of individual sheets due to strain localisation, with magma preferentially exploiting these faults, initiating sill (sheet) climbing. The order in which sheets are stacked impacts on the intrusion geometry and associated deformation of wall rocks. Our results offer new insights into the incremental intrusion geometries of shallow-level magmatic bodies and the potential impact of their emplacement on surrounding host rocks.     

Tide,Wind, and River Forcing of the Surface Currents in the Fraser River Plume

A long-term record of surface currents from a high-frequency radar system, along with near-surface hydrographic transects, moored current meter records, and satellite imagery, are analyzed to determine the relative importance of river discharge, wind, and tides in driving the surface flow in the Fraser River plume. The observations show a great deal of oceanographic and instrumental variability. However, averaged quantities yielded robust results. The effect of river flow, which determines buoyancy and inertia near the river mouth, was found by taking a long-term average. The resulting flow field was dominated by a jet with two asymmetric gyres; the anticyclonic gyre to the north had flow speeds consistent with geostrophy. The mean flow speed near the river mouth was 14.3?cm?s^–1, while the flow further afield was 5?cm?s^–1 or less. Wind stress and surface currents were highly coherent in the subtidal frequency band. Northwesterly winds drive a surface flow to the southeast at speeds of nearly 30?cm?s^–1. Southeasterly winds drive a surface flow to the northwest at speeds reaching 20?cm?s^–1; however, there is more spatial variability in speed and direction relative to the northwesterly wind case. A harmonic analysis was used to extract the tidally driven flows. Ellipse parameters for the major tidal constituents varied considerably in both alignment and aspect ratio over the radar domain, in direct contrast to a barotropic model which predicted rectilinear flow along the Strait of Georgia. This is a result of water filling and draining the shallow mud flats north of the Fraser's main channel. The M₂ velocities at the surface were also weaker than their barotropic counterparts. However, the shallow water constituent MK₃ was enhanced at the surface and nearly as strong as the mean flow, implying that non-linear interactions are important to surface dynamics.     

东中国海黑潮海洋锋的季节变化特征及其成因

利用高分辨率海洋和大气再分析资料研究了东中国海黑潮海洋锋的季节变化特征及其成因。研究表明,东海黑潮海洋锋存在明显的季节变化,从冬季到次年春季逐渐增强,并在春季达到最强,初夏以后强度逐渐减弱,9—10月达到全年最弱。通过诊断混合层热流量方程发现,东海黑潮区一年四季均表现为暖的温度平流,有利于海洋锋的形成和维持,该暖平流也存在季节变化并在春季达到最大,对海洋锋在春季达到最强起了重要作用。海气界面净热通量在秋冬季对海洋锋的形成有促进作用,有利于海洋锋增强,而在春夏季则起抑制作用,促进海洋锋消亡。温度垂直输送全年对海洋锋起一定程度的抑制作用。总之,在海温水平平流和海表净热通量的共同作用下导致海洋锋春季达到最强,而夏秋季海表净热通量和温度垂直输送作用的共同作用致使海洋锋减弱并最后消失。因此,海洋的动力和热力共同作用导致了东海黑潮海洋锋的季节变化,其中海温水平平流和海表净热通量对海洋锋的季节变化起主要作用,而温度垂直输送项对海洋锋的发展起抑制作用,但影响相对较小。     

台湾海峡西岸海雾研究现状与未来发展方向

台湾海峡是一个海雾多发的交通要道,海雾灾害往往会导致人员和财产损失。对当前有关的海雾研究现状进行总结,以海峡西岸为代表,比较台湾海峡海雾和其他海域的大雾研究进展状况,主要包括海雾发生时的天气气候学特征、监测手段、微物理特征研究和海雾数值预报研究等。结果表明,台湾海峡西岸在天气气候学方面已经取得了一定的成果;监测手段随着科学技术的发展,也不断的完善,但在如何对卫星遥感监测结果进行反演方面还需进一步研究;海雾的微物理特征研究有助于海雾模式的改进和卫星遥感海雾反演技术的提高,但台湾海峡西岸尚未开始研究,是下一步的研究重点;台湾海峡海雾数值模拟工作较少,伴随观测技术的不断进步、动力统计方法的不断完善,可通过数值预报产品与传统的天气学方法相结合,提高台湾海峡海雾预报水平。     

Population genetic diversity and structure of a dominant tropical seagrass,Cymodocea rotundata,in the Western Pacific region

Cymodocea rotundata is an ecologically important tropical pioneer seagrass species distributed in the Indo‐Pacific region. The population genetic diversity and structure of this species were analysed at 46 sites spanning the Philippines, Ryukyu Islands (northern limit) and Hainan Island, by using microsatellite simple sequence repeat (SSR) markers. Analyses revealed the persistence of C. rotundata likely relies on local population dynamics and fitness influenced by environmental gradients, with sexual reproduction prevalent in the Philippines while the Ryukyu and Hainan populations were predominantly established by clonal spread. Analysis of molecular variance showed significant genetic differentiation (P < 0.001) among three geographic regions: the Philippines, Ryukyu and Hainan. Furthermore, the mean fixation index value was very high (F_ST = 0.36), indicating poor dispersal potential or limited gene flow. Allelic richness and heterozygosity of C. rotundata was comparable in the Philippines and Ryukyu Islands populations. More private alleles were found in the Philippines and excess heterozygotes in the Ryukyu Islands. STRUCTURE analysis revealed that the Ryukyu and Hainan populations were mosaics of admixed alleles of individuals from the Philippines. An assignment test suggested that recruitment occurs from the Northeast Philippines to Ryukyu Islands. These results suggest that the Philippine populations are tropical seagrass hotspots and perhaps the origin of the populations in the Ryukyu and Hainan Islands. This scenario is most likely driven by the Kuroshio Current and island integration events during plate tectonic activities. The Philippine Archipelago is considered of high importance for conservation objectives and management plan of seagrasses. Likewise, the Ryukyu Islands are also important in terms of conserving regional diversity because locally adapted genotypes have important evolutionary potential in the face of environmental change.     

南海上层经向翻转环流的低频变化

The low-frequency variability of the shallow meridional overturning circulation(MOC) in the South China Sea(SCS) is investigated using a Simple Ocean Data Assimilation(SODA) product for the period of 1900–2010. A dynamical decomposition method is used in which the MOC is decomposed into the Ekman, external mode, and vertical shear components. Results show that all the three dynamical components contribute to the formation of the seasonal and annual mean shallow MOC in the SCS. The shallow MOC in the SCS consists of two cells: a clockwise cell in the south and an anticlockwise cell in the north; the former is controlled by the Ekman flow and the latter is dominated by the external barotropic flow, with the contribution of the vertical shear being to reduce the magnitude of both cells. In addition, the strength of the MOC in the south is found to have a falling trend over the past century, due mainly to a weakening of the Luzon Strait transport(LST) that reduces the transport of the external component. Further analysis suggests that the weakening of the LST is closely related to a weakening of the westerly wind anomalies over the equatorial Pacific, which leads to a southward shift of the North Equatorial Current(NEC) bifurcation and thus a stronger transport of the Kuroshio east of Luzon.