Untersuchung der Sorptionseigenschaften des Kationenaustauschers KB-2M mit Makronetzstruktur zur Abtrennung von Zinkionen aus Ab- und Spülwässern

Study of Sorptional Properties of the Cation Exchanger KB-2M with Macroreticular Structure for Recovery of Zinc Ions from Sewage and Rinsing Water Although a number of ion-exchange methods have been employed for the recovery of some transition metals from industrial effluents, knowledge about ion-exchange resins with macroreticular structure is poor. The present paper describes the mechanism of sorption on such exchangers and their application for recovery of zinc from sewage rinsing water. Ion exchanger of macroreticular structure are polymers with long-chained cross-linking agents. We have synthesized carboxylic ion-exchange resins by hydrolysis of copolymerisates of methyl acrylate with different cross-linking agents: divinylbenzene, divinyl sulfide, divinyl ester of ethylene glycol and divinyl ester of di- or triethylene glycol. The sorption process on modifications of the carboxylic resins KB-2 of various structure was studied with different methods: potentiometric titration, infrared spectroscopy, electron microscopy, X-ray structural analysis. The initial zinc concentration in rinsing water was 0.05 mol/L at pH from 3 to 6. For the sorption, 0.2…1.0 g of resin were equilibrated with 100 mL of zinc solution. After equilibrium (12 h), the resin was separated from solution. The zinc ions were determined by atomic absorption spectrometry after stripping with 100 mL of 10% sulfuric acid. The distribution ratio D was calculated (D: mmole of Zn sorbed per gram of resin divided by mmole of Zn per millilitre of solution). By means of infrared spectroscopy, the mechanism of sorption of zinc ions from rinsing water was determined. There may be a possibility of the formation of complexes in the cation-exchange resin phase. It was found out in this paper that the cation-exchanger KB-2M of macroreticular structure is the most effective for the sorption of the Zn²⁺-ions from sewage and rinsing water.     

山谷冰川稳定态时积累区面积比率研究

探讨山谷冰川稳定状态时积累区面积比率，即ＡＡＲ值的大小，认为冰川物质平衡高程分布，平面形态及坡面坡度沿程变化形式是影响山谷冰川稳定态ＡＡＲ值的主要因素，并 山谷冰川稳定态ＡＡＲ值与物质平衡高程分布及平面形态之间的定量关系。山谷冰川适合于应用ＡＲ值法来研究古冰川的零平衡线高程。     

古埃磁天平法研究磁流体的磁性及稳定性

本文根据古埃磁天平的测量原理和磁流体的超顺磁性质，首次使用古埃磁天平研究了磁流体的磁性，利用磁流体的磁增重随时间的变化，研究磁流体的稳定性，并用实验证明方法的可行性。     

Radiative Exchange in an Urban Street Canyon

The influence of building geometry on the radiation terms ofthe surface energy balance is a principal reason for surfacetemperature differences between rural and urban areas.Methods exist to calculate the radiation balance in an urban area,but their validity across the range of urban geometries andmaterials has not been carefully considered.Here the exchange of diffuse radiation in an urban street canyon isinvestigated using a method incorporating all reflections of radiation.This exact solution is compared to two commonly used approximationsthat retain either no reflections, or just one reflection of radiation.The area-averaged net radiative flux density from the facets of the canyondecreases in magnitude monotonically as the canyon aspect ratio increases.The two approximate solutions possess unphysical differences from thismonotonic decrease for high canyon aspect ratios or low materialemissivities/high material albedos.The errors of the two approximate solutions are small for near blackbodymaterials and small canyon aspect ratios but can be an order ofmagnitude for intermediate material properties and deep street canyons.Urban street canyon models need to consider at least one reflectionof radiation and multiple reflections are desirable for full applicability.     

许昌麦岭水源地可开采量的水均衡法计算

根据许昌麦岭镇多年地下水动态观测资料,利用水均衡法原理,对水源地边界地质条件、补给与排泄的关系进行研究,对地下水允许开采量进行综合评价,提出水源地水量开采的建议。     

太湖生态环境演化及其原因分析

太湖地处长江下游三角洲,水域面积为2338km²,平均水深1.9m,最大水深不足2.6m,为一典型的大型浅水湖泊。太湖流域地势平坦,河网密布,河湖水力关系复杂。其主要补给径流来自西南部的天目山区及西部的宜溧河流域。每年夏天,大部分入湖洪水通过位于东太湖的太浦河及东北部的望虞河分别排入黄浦江与长江,由于出入湖河道的特殊位置,使得太湖南部的换水周期较短而北部较长。近几十年来,太湖由于污染而逐步呈现富营养化特征,污染物主要来自北部的无锡市和常州市,通过河道排入太湖北部的五里湖与梅梁湾,因此上述两地的水质较南部差。在东太湖,水产养殖对水环境的影响很大,亦呈现出富营养化特征,并殃及该地区的供水,加之该地区为太湖主要的泄洪通道,因此泥沙淤积严重,而且水生植物生长旺盛,呈现出明显的沼泽化趋势;在太湖四周地区,由于湖泊围垦和水利工程建设,其污染净化能力将降低,从而加速水环境恶化的趋势。太湖所面临这些问题,有待于强化湖泊科学管理来解决。     

旱作春小麦蒸散量测算方法的比较

采用波文比—能量平衡法和蒸渗计对农田蒸散量进行了为期3a的对比观测试验。结果表明，在半干旱雨养农业区，两者测算的农田蒸散量平均偏差为20％，波文比—能量平衡法计算值大于蒸渗计实测值，基本满足精度要求；无感热平流时两种方法所得蒸散量相关性较有感热平流时的好；在平流逆温状态下采用波文比—能量平衡法的计算误差大于非平流状态下的计算误差；由于蒸渗计隔断了与周围农田的水热交换，导致了蒸渗计测量的蒸散量较采用波文比—能量平衡法的计算值偏低，其偏差大小需要进一步试验确定。     

Relationship between solar radiation and the development and morphology of small cirque glaciers (Maladeta Mountain massif, Central Pyrenees, Spain)

Abstract Spatial and temporal variations in radiative fluxes influence glacier mass‐balance in mountain areas. The primary goal of this study was to assess differences in solar radiation on three glacial cirques located in the Maladeta Mountain massif (Central Spanish Pyrenees), and analyse their implications on glacier development and morphology. A quantitative approach is adopted to obtain the values of solar radiation (direct, diffuse and global radiation), combining several field data parameters (measured at 55 control‐points) with the solar radiation modelling package Ecosim. The data obtained confirm that the morphologies of the glacial bodies developed in the three cirques have a good correlation with the spatial variation on solar radiation inputs, favouring also the conservation (Aneto and Coronas cirques) or total vanishing (Llosás cirque) of the glacial remnants analysed here. The study shows how strongly in this Alpine‐Mediterranean context solar radiation — firstly as a function of latitude and time of year, and locally as a function of topographic slope, aspect and shadowing — controls the mass‐balance and the spatial distribution of melting in small glaciers, having an effect on the development of their morphologies.     

Spatial Dimensions of Urban Commuting: A Review of Major Issues and Their Implications for Future Geographic Research*

Modern urban transportation systems continuously challenge, and are challenged by, the changing nature of 21st‐century travel demand. Today, congestion is the norm in cities of the United States, and researchers and practitioners are seeking solutions to these problems. Urban commuting is identified as contributing to the suboptimal performance of transportation systems. This paper offers a review and critique of recent research on urban commuting, emphasizing geographical dimensions of this topic. Three broad areas of research related to urban commuting are discussed. These include (1) urban sustainability, (2) land use, and (3) geographic information systems (GIS). Major themes are examined in an effort to elicit thought on future geographic research. At the conclusion of the paper, summary remarks are provided and avenues for research are outlined.     

On the applicability of KirchofPs law and the principle of heat balance in thermal infrared remote sensing:A non-isothermal system

This paper proposes a basic equation of thermal radiation interaction between surface objects on the basis of the principle of heat balance in the interface. The solution of this equation takes account of the contribution of sensible heat flux and latent heat flux more completely, compared with traditional solution for surface cooling and heating processes. By the aid of the experimental data conducted in the Xiaotangshan experimental site, Beijing, both the non-applicability of Kirchoff's law and the measurability of surface emissivity in a non-isothermal system have been highlighted. Two methods called ventilation and time-delay compensations have been proposed to reduce the error induced by change of surface temperatures of non-isothermal objects during the measurement of emissivity. Based on the solution of the basic equation, this paper has analyzed and pointed out the misunderstanding in comprehension and application of Kirchoff's law published in literature.