The Tallinn Temperature Series Reconstructed Back Half a Millennium by Use of Proxy Data

In order to extend the Tallinn temperature series backward in time, three different climate proxies were used. These were: the first day of ice break-up in Tallinn port, a proxy for the mean winter air temperature (December to March); the first day of ice break-up on the rivers in northern Estonia, a proxy for the beginning of spring; and, the first day of the rye harvest, a proxy for the mean air temperature in spring and summer (April to July). On the basis of these proxies the mean winter temperature could be extended back to the year AD 1500, and the spring and summer temperature back to 1731. The series of winter temperatures was analysed for long-term trends and variations on different timescales. The most striking feature is the warming of the winters from about the mid nineteenth century to the present. The warming is especially noticeable over the latest decades. The climate from the start of the series (AD 1500) to the mid nineteenth century was in general somewhat colder, and should be recognised as a part of the Little Ice Age, though the period was intercepted by warmer winters in the first half of the eighteenth century.     

Behaviour of H2O2, NH3, and black carbon in mixed-phase clouds during CIME

We investigated the partitioning of trace substances during the phase transition from supercooled to mixed-phase cloud induced by artificial seeding. Simultaneous determination of the concentrations of H₂O₂, NH₃ and black carbon (BC) in both condensed and interstitial phases with high time resolution showed that the three species undergo different behaviour in the presence of a mixture of ice crystals and supercooled droplets. Both H₂O₂ and NH₃ are efficiently scavenged by growing ice crystals, whereas BC stayed predominantly in the interstitial phase. In addition, the scavenging of H₂O₂ is driven by co-condensation with water vapour onto ice crystals while NH₃ uptake into the ice phase is more efficient than co-condensation alone. The high solubility of NH₄⁺ in the ice could explain this result. Finally, it appears that the H₂O₂–SO₂ reaction is very slow in the ice phase with respect to the liquid phase. Our results are directly applicable for clouds undergoing limited riming.     

小冰期以来中国十年尺度气候变化时空分布特征的初步研究

依据10年际的冰芯、树轮和历史文献记录，首先进行了聚类分析，近400年来中国温度变化大体上可分为两类：第一类包括高原南部、高原西部、东北和闽台地区；第二类包括西南、华南、华中、华东、西北和华北地区。接着分析了近600年、500年和400年三种不同时间尺度上中国气温的时空分布，第一特征向量显示中国东部温度值高于西部，第二特征向量中高原南部、高原东北部与高原西部的反位相变化趋势在不同时间惊讶的EOF结果中都有表现。西南、华南区与华北、华东区在后两种时间尺度上温度变化位相相反。以上这些变化型在近40年来的年际变化中同样发生。小冰期在不同时间尺度的第一特征向量的权重系数中均有明显表现。将中国温度变化与北半球和北极进行比较，发现它们变化非常类似，且以北半球和北级滞后中国温度20年时相关相关最好。     

ICE Particle Size and Shape Effect on Solar Energy Scattering Angular Distribution

The rare occurrence of te halos produced by cirrus ice crystals in nature has been investigated by modelling the incident solar (visible) light scattering angular distribution using the Monte Carlo/ray tracing method.The results show that the irregular shapes of ice crystals and large population of small ice particles in cirrus are responsible forthe rare occurrence of halos.     

Assessment of potential transport of pollutants into the Barents Sea via sea ice--an observational approach

The present estimates of ice drift in the Arctic include utilization of satellite imagery data (special sensor microwave/imager) and a reconstruction of air pressure for the period 1899-1998. A significant part of the sea ice in the Arctic Ocean has its origin in the Kara Sea and melts in the Greenland and the Barents Sea (BS). Consequently there may be a particular risk of pollutants in the Kara Sea entering the food webs of the Greenland and BS. The ice export from the Kara Sea between 1988 and 1994 was about 208,000 km2 (154 km3) per year. The import of ice into the BS was during the same period 161,000 km2 (183 km3) per year while the ice drift through the Fram Strait into the Greenland Sea was 583,000 km2 (1859 km3) per year. Ice which formed adjacent to the Ob and Yenisey rivers in early January, drifted into the BS within two years (with a probability of about 50%.     

Paleohydrology of Andean saline lakes from sedimentological and isotopic records, Northwestern Argentina

The paleohydrological evolution of several high altitude, saline lakes located in the southernmost Altiplano (El Peinado and San Francisco basins, Catamarca province, NW Argentina) was reconstructed applying sedimentological, geochemical and isotopic techniques. Several playa lakes from the San Francisco basin (26° 56 S; 68° 08 W, 3800-3900 m a.s.l.) show evidence of a recent raise in the watertable that led to modern deposition of carbonate and diatomaceous muds. A 2 m - long core from El Peinado Lake (26° 29 59 S, 68°05 32 W, 3820 m a.s.l.) consists of calcitic crusts (unit 3), overlaid by an alternation of macrophyte-rich and travertine clast- rich, laminated muds (unit 2), and topped by travertine facies (unit 1). This sedimentary sequence illustrates a paleohydrological evolution from a subaerial exposure (unit 3) to a high lake stand (unit 2), and a subsequent smaller decrease in lake level (unit 1). The ¹³C_{organic matter}record also reflects the lake transgression between units 3 and 2. Although there is a general positive correlation between ¹⁸O_carbonate and salinity proxies (Na, Li and B content), the large data dispersion indicates that other factors besides evaporation effects control chemical and isotopic composition of lakewater. Consequently, the oxygen isotopic composition cannot be interpreted exclusively as an indicator of salinity or evaporation ratio. The degassing of CO₂ during groundwater discharge can explain the enriched ¹³C values for primary carbonates precipitated. The carbon budget in these high altitude, saline lakes seems to be controlled by physical rather than biological processes.The Altiplano saline lakes contain records of environmental and climatic change, although accurate ¹⁴C dating of these lacustrine sediments is hindered by the scarcity of terrestrial organic material, and the large reservoir effects. Sedimentologic evidence, a ²¹⁰Pb-based chronology, and a preliminary U/Th chronology indicate a very large reservoir effect in El Peinado, likely as a result of old groundwaters and large contributions of volcanic and geothermal ¹⁴C-free CO₂ to the lake system. Alternative chronologies are needed to place these paleorecords in a reliable chronological framework. A period of increased water balance in the San Francisco basin ended at about 1660 ± 82 yr B.P. (calendar yr U/Th age), and would correlates with the humid phase between 3000 and 1800 yr B.P detected in other sites of the southern Altiplano. Both, ²¹⁰Pb and preliminary U/Th dating favor a younger age for the paleohydrological changes in El Peinado. The arid period reflected by subaerial exposure and low lake levels in unit 3 would have ended with a large increase in effective moisture during the late 17th century. The increased lake level during deposition of unit 2 would represent the period between AD1650 - 1900, synchronous to the Little Ice Age. This chronological framework is coherent with other regional records that show an abrupt transition from more arid to more humid conditions in the early 17th century, and a change to modern conditions in the late 19th century. Although there are local differences, the Little Ice Age stands as a significant climatic event in the Andean Altiplano.     

Humid Little Ice Age in arid central Asia documented by Bosten Lake, Xinjiang, China

Short sediment cores retrieved from Bosten Lake, the largest inland freshwater lake in China, were used to explore humidity and precipitation variations in arid central Asia during the past millennium. The chronology of the cores was established using 137Cs, 210Pb and AMS 14C dating re- sults. Multi-proxy high-resolution analysis, including pollen ratios of Artemisia and Chenopodiaceae (A/C), carbonate content and grain size, indicates that the climate during the past millennium can be divided into three stages: a dry climate between 1000―1500 AD, a humid climate during the Little Ice Age (LIA) (c. 1500―1900 AD), and a warm dry period after 1900 AD. On centennial timescales, the climate change in northwestern China during the past 1000 years is characterized by oscillations between warm-dry and cold-humid climate conditions. All the proxies changed significantly and indi- cate increased precipitation during the LIA, including increased pollen A/C ratios and pollen concen- trations, decreased carbonate content and increased grain size. The humid period during the LIA re- corded by the Bosten Lake sediments is representative of arid central Asia and is supported by nu- merous records from other sites. During the LIA, the water runoff into the Keriya River and Tarim River in the Tarim Basin increased, while the ice accumulation in the Guliya ice core increased. Additionally, the lake levels of the Aral and Caspian Sea also rose, while tree-ring analysis indicates that precipita- tion increased. We hypothesize that both the lower temperature within China and the negative anomalies of North Atlantic Oscillation (NAO) during this period may have contributed to the humid climate within this area during LIA.     

Analysis of rock drainage and cooling experiments for underground cryogenic LNG storage

Hydrogeological monitoring was conducted around a pilot cavern for underground cryogenic LNG (Liquefied Natural Gas) storage. The monitoring was mainly focused on the operation of a drainage and recharge system. After the operation of the drainage system commenced, the drainage rate decreased rapidly in the initial stages and then decreased gradually. Hydrogeological monitoring revealed that the rock drainage system operated effectively. During drainage, the water table was maintained below the cavern roof. The recharge for ice-ring formation was performed in two phases. The first phase involved the cessation of pumping in downward-drainage holes and the second involved the closure of upward boreholes. Since the water table was maintained below the cavern roof, artificial recharge was planned at first. However, it was not implemented due to heavy rainfall in the recharge stage. On the basis of hydrogeological monitoring and hydraulic tests, it was found that the fractures above the roof and on the right wall of the pilot cavern mainly affected seepage into the cavern and thermal variation due to the storage of liquid nitrogen. Thermal variation was examined by the thermometers installed around the pilot cavern. The cooling and thawing processes reveal the characteristics of thermal distribution in the rock and the 0 °C isotherm. The cooling phase lasted for six months, and the 0 °C isotherm progressed in time after the injection of liquid nitrogen into the cavern. The isotherm propagated up to about 4 m from the floor and the sidewall of the cavern and about 3 m from the cavern roof. The cooling rate of the rock mass above the cavern roof was lower than that of the other cavern sides due to the gaseous space in the upper part of the containment. The fractures were analyzed and considered for thermal modeling. A two-dimensional finite element analysis was performed to compare the field monitoring at the pilot cavern. The numerical modeling shows the distance between the ice ring and heat transfer pattern of the fractures around the pilot cavern. The propagation of the measured and calculated 0 °C isotherm reveals that the water-conveying joint on the right wall might affect thermal propagation through a thermal pipe.     

The Kuwae (Vanuatu) eruption of<Emphasis Type="SmallCaps"> AD</Emphasis> 1452: potential magnitude and volatile release

Sometime during AD 1452, according to new evidence, a large-magnitude, initially phreatomagmatic eruption, destroyed the island of Kuwae (16.83°S, 168.54°E), located in the present-day Republic of Vanuatu. It created a 12×6-km submarine caldera composed of two adjacent basins. Based on estimates of caldera volume, between 30 and 60 km³ DRE of dacite magma was ejected as pyroclastic flow and fall deposits during this event. Annual layers of ice dating from the period AD 1450–1460 contain acidity peaks representing fallout of sulfuric acid onto both the Greenland and Antarctic ice caps. These acidity peaks have been attributed by others to the sedimentation of H₂SO₄ aerosols that originated from sulfur degassing during the Kuwae eruption. Improved dating techniques and new data from nineteen ice cores reveal a single acidity peak attributed to Kuwae lasting from 1453 to 1457. In this study, we present new electron microprobe analyses of the S, Cl, and F contents of matrix glasses and glass inclusions in phenocrysts from tephra ejected during the Kuwae eruption. We establish that the Kuwae event did indeed yield a large release of sulfur gases. From our glass inclusion data and analysis, we calculate that the total atmospheric aerosol loading from the 1452 Kuwae eruption was ≫100 Tg H₂SO₄. Much of the volatile mass released during the eruption was probably contained in a separate, volatile-rich, fluid phase within the pre-eruptive Kuwae magma body. Comparing the volatile release of the Kuwae eruption with other large-magnitude eruptions, places Kuwae as the greatest sulfuric acid aerosol producer in the last seven centuries, larger even than sulfur emissions from the eruption of Tambora (Indonesia) in 1815, and possibly Laki (Iceland) in 1783. The severe and unusual climatic effects reported in the mid- to late-1450s were likely caused by the Kuwae eruption.