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41.
The performance and integrity of a cassette cross-flow ultrafilter(Pellicon 2, Millipore) are examined with a suite of macromolecules of different molecular masses. The retention coefficient during the cross-flow ultrafiltration experiments increases with increasing molecular mass and reaches 90% with 10 kDa dextran in both milli-Q water and ultrafiltered seawater media. Based on a 90% retention coefficient, the molecular mass cut-off for the ultrafiltration membrane is defined at 10 kDa, which is ten times(1 kDa) that rated by the manufacturer. To further validate the accuracy of the laboratory calibration, the samples from the lower Zhujiang River and the Jiulong River Estuary are ultrafiltered with the cassette ultrafiltration membrane and the colloidal organic carbon abundances in these samples are quantified with the ultrafiltration permeation model based on time series permeation subsamples. The colloidal organic carbon abundances are 5.8%–21.1% in the Jiulong River Estuary and 5.6%–11.0% in the lower Zhujiang River. These are consistent with the reported values for both estuaries as well as with the colloidal organic carbon abundances in marine environments over the coastal and open oceans with 10 kDa cut-off membranes. Therefore, these field data support the laboratory calibration result and indicate the validity of the experimental and quantification procedure adopted. The discrepancy between the nominal molecular mass cut-off and the actual pore size of the ultrafiltration membrane should be of great concern for research in colloidal and nanoparticle biogeochemistry. Careful examination of the membrane integrity should be taken during ultrafiltration experiments in order to avoid misleading molecular mass cut-off information. 相似文献
42.
D. A. Robertson 《新西兰海洋与淡水研究杂志》2013,47(3):411-415
Plankton samples taken in the south‐western Pacific Ocean and the Tasman Sea have provided, for the first time in these waters, a series of individuals of the gonostomatid Diplophos rebainsi. Observations are presented on some of the prejuvenile and adult features and on the seasonal distribution of prejuveniles off New Zealand. 相似文献
43.
Penelope A. Luckens 《新西兰海洋与淡水研究杂志》2013,47(4):497-514
The breeding and settlement seasons of the intertidal barnacles Chamaesipho brunnea, C. columna and Elminius plicatus were determined, and experiments using cages on the shore to examine barnacle survival and growth rate at four levels were carried out at Leigh during 1964–66. Chamaesipho brunnea bred in spring and summer; C. columna and E. plicatus bred throughout the year, but settled intermittently. When protected from predators and from overgrowth by algae, all three species survived at levels lower than normal. At higher levels C. columna, E. modestus, Balanus trigonus and Tetraclita purpuraseens survived for significant periods (C. brunnea occurs naturally higher on the shore than the highest experimental level). 相似文献
44.
长江口水域波浪数值计算 总被引:2,自引:0,他引:2
利用高阶非线性抛物型缓坡方程对长江口水域的波浪传播变形作了推算,依据测站的资料分析数值模式中的底摩阻因子和风能输入因子对波浪传播的影响,进而确定其参数。针对不同导堤结构型式,分析了潜堤的波浪传递系数,最后对长江口二期整治工程完成后水域的波浪场作了推算。 相似文献
45.
本文介绍了长江口区水文泥沙概况,举例说明了SSA1-1型声水位计在崇头潮位站比测试验和投产应用情况,结果表明该水位计是收集长江口区潮位资料较理想的仪器。 相似文献
46.
1994年6,7月,调查了广州、深圳、珠海及珠江口海区的空气微生物粒子沉降量状况。发现空气微生物粒子总量、真菌粒子量、真菌粒子数/总菌粒子数百分比在三市中不一致。这三种数据一般是陆上的高于海上。随着距陆的增加,都市影响的减弱和海面的开阔,空气微生物含量呈减少之势,显示出海洋新鲜空气对陆上污染空气的调节、净化作用。文中还分析了空气微生物有关参数与气温、风力或相对湿度间的相关关系。 相似文献
47.
An integrated mass balance and modelling approach for analysis of estuarine nutrient fluxes is demonstrated in the Swan River Estuary, a microtidal system with strong hydrological dependence on seasonal river inflows. Mass balance components included estimation of gauged and ungauged inputs to the estuary and losses to the ocean (outflow and tidal exchange). Modelling components included estimation of atmospheric (N fixation, denitrification) and sediment–water column nutrient exchanges. Gross and net denitrification derived using two independent methods were significantly correlated (r2 = 0.49, p < 0.01) with net rates averaging 40% of gross. Annual nitrogen (N) and phosphorus (P) loads from major tributaries were linearly correlated with annual freshwater discharge and were 3-fold higher in wet years than in dry years. Urban drains and groundwater contributed, on average, 26% of N inputs and 19% of P inputs, with higher relative contributions in years of low river discharge. Overall, ungauged inputs accounted for almost 35% of total nitrogen loads. For N, elevated loading in wet years was accompanied by large increases in outflow (7x) and tidal flushing (2x) losses and resulted in overall lower retention efficiency (31%) relative to dry years (70%). For P, tidal flushing losses were similar in wet and dry years, while outflow losses (4-fold higher) were comparable in magnitude to increases in loading. As a result, P retention within the estuary was not substantially affected by inter-annual variation in water and P loading (ca. 50% in all years). Sediment nutrient stores increased in most years (remineralisation efficiency ca. 50%), but sediment nutrient releases were significant and in some circumstances were a net source of nutrients to the water column. 相似文献
48.
49.
1994年5月—1995年6月,利用黄河口悬浮颗粒物,在实验室内于不同温度、盐度、磷酸盐浓度、pH值及悬浮物粒度条件下进行了悬浮物对磷酸盐的吸附和解吸模拟实验,通过水体中几种磷—钙矿物的离子平衡计算,对黄河口磷酸盐的缓冲机制进行了探讨。结果表明,黄河口现场条件下水体中钙与磷之间存在某些离子平衡,黄河口水体中磷—钙矿物的离子积受温度、悬浮物种类及粒度影响较小,而与水体盐度、磷酸盐及钙含量有关,但不足以形成磷—钙矿物沉淀;磷—钙矿物的沉淀和溶解在黄河口磷酸盐浓度的控制机制上所起的作用较小,而悬浮颗粒物表面对磷酸盐的吸附和解吸起了较大的作用。 相似文献
50.
There has been a revival in hydrocarbon source rock characterization and development associated with growing interest in unconventional resources, where these fine-grained organic-rich rocks act as both source and reservoir. To-date, the exploration focus on shale reservoirs has been largely on marine systems. Lacustrine source rocks for conventional resources are geographically important, dominating regions such as China, Indonesia, and Brazil's resource-base. However, they have been generally untested for unconventional resources.There are a number of key differences in the nature of these hydrocarbon systems that should be considered when assessing whether lacustrine systems may represent future unconventional opportunities in areas where the conventional resource-base is dominated by lacustrine-sourced oil. Among the key differences between these depositional systems is the greater sensitivity to high frequency climatic variability within lacustrine systems. Lacustrine systems are highly sensitive to changes in the balance between precipitation and evaporation, which may lead to rapid changes in lake level, potentially exceeding 600 m. These changes in depositional conditions are geologically rapid and may occur over periods of thousands of years. Such changes can reduce the areal extent of potentially thick source rock intervals to only those portions of a basin where a permanent deep lake was present. Thus the core unconventional target area may be geographically limited compared with their marine counterpart. Although potentially areally limited, a review of many lacustrine source rocks suggests that their thicknesses are often significantly greater than marine source rocks. An examination of the more distal portions of lacustrine systems, where better source rock potential is present reveals that there is generally limited connectivity between source and conventional reservoir. In these settings, such as the Wind River basin (Waltman Shale), the hydrocarbons remain trapped within the shales, potentially leading to over-pressured hydrocarbon charged systems. Such conditions suggest that although areally limited, viable unconventional targets may exist, if suitable reservoir conditions are present. Finally, the character of the oils produced is different in these settings, with lacustrine oils being waxy and displaying different hydrocarbon generation and cracking kinetics. High wax oils display distinct flow characteristics, being more viscous, and may offer different production challenges than their non-waxy marine equivalents. Additionally, differences in their cracking kinetics may indicate that the timing of gas generation for shale gas plays may differ significantly from marine systems. 相似文献