Electrical aerosol spectrometer of Tartu University

The electrical aerosol spectrometer (EAS) of the parallel measuring principle at Tartu University is an efficient instrument for rapid measurement of the unstable size spectrum of aerosol particles. The measuring range from 10 nm to 10 μm is achieved by simultaneously using a pair of differential mobility analyzers with two different particle chargers. The particle spectrum is calculated and measurement errors are estimated in real time by using a least-squares method. Experimental calibration ensures reliability of measurement. The instrument is well suited for continuous monitoring of atmospheric aerosol.     

Optimal design of passive energy dissipation systems based on H∞ and H2 performances

Passive energy dissipation devices (EDDs), such as viscous dampers, viscoelastic dampers, etc., have been used to effectively reduce the dynamic response of civil infrastructures, such as buildings and bridges, subject to earthquakes and strong winds. The design of these passive energy dissipation devices (EDDs) involves the determination of the optimal locations and the corresponding capacities. In this paper, we present two optimal design methodologies for passive EDDs based on active control theories, including H_∞ and H₂ performances, respectively. The optimal design methodologies presented are capable of determining the optimal locations and the corresponding capacities of EDDs. Emphasis is placed on the application of linear matrix inequality (LMI) for the effective design of passive EDDs using the popular MATLAB toolboxes. One important advantage of the proposed approaches is that the computation of the structural response is not needed in the design process. The proposed optimal design methodologies have been applied to: (i) a 10‐storey building and a 24‐storey building both subject to earthquake excitations, and (ii) a 76‐storey wind‐excited benchmark building, to demonstrate the advantages of the proposed design methodologies over the conventional equal capacity design. Copyright © 2002 John Wiley & Sons, Ltd.     

Damaging properties of ground motions and prediction of maximum response of structures based on momentary energy response

Dynamic damaging potential of ground motions must be evaluated by the response behaviour of structures, and it is necessary to indicate what properties of ground motions are most appropriate for evaluation. For that purpose, the behaviour of energy input process and hysteretic energy dissipation are investigated in this study. It is found that the momentary input energy that is an index for the intensity of input energy is related to the characteristics of earthquakes such as cyclic or impulsive, and to the response displacement of structures immediately. On the basis of these results, a procedure is proposed to predict inelastic response displacement of structures by corresponding earthquake input energy to structural dissipated damping and hysteretic energy. In this procedure the earthquake response of structures is recognized as an input and dissipation process of energy, and therefore structural properties and damaging properties of ground motions can be taken into account more generally. Lastly, the studies of the pseudodynamic loading test of reinforced concrete structure specimens subjected to ground motions with different time duration are shown. The purpose of this test is to estimate the damaging properties of ground motions and the accuracy of the proposed prediction procedure. Copyright © 2002 John Wiley & Sons, Ltd.     

25～75℃酸性NaCl溶液中方铅矿的溶解动力学

在25～75℃、pH=0.43～2.45的1mol/LNaCl溶液中进行了方铅矿的溶解动力学实验。发现在远平衡条件下,方铅矿的溶解速率r与氢离子活度犤H+犦呈线性关系,溶解速率方程(速率定律)为:r=k犤H+犦,即对H+而言,溶解反应为一级。其中速率常数k为2.344×10-7mol/m2·s(25℃)、1.380×10-6mol/m2·s(50℃)、7.079×10-6mol/m2·s(75℃)。溶解反应的活化能为43.54kJ/mol,方铅矿的溶解机理为表面化学反应,速率决定步骤为表面配合物的离解。     

Spectroscopic evidence for pressure-induced phase transitions in diopside

 Raman spectra of diopside were collected from atmospheric pressure to 71 GPa. The pressure dependences of 22 modes were determined. Changes occurred in the spectra at three different pressures. First, at approximately 10 GPa, the two Raman modes at 356 and 875 cm⁻¹ disappeared, while the mode at 324 cm⁻¹ split into two modes, diverging at this pressure with significantly different pressure shifts; second, at approximately 15 GPa, a small (1 to 2 cm⁻¹) drop in several of the frequencies was observed accompanied by changes in the pressure dependency of some of the modes; and third, above 55 GPa, the modes characteristic of chains of tetrahedrally coordinated silicon disappeared, while those for octahedrally coordinated silicon appeared. The first change at 10 GPa appears to be a C2/c to C2/c transition involving a change in the Ca coordination. The third change above 55 GPa appears to be a change in the silicon coordination. At 15 GPa, it is suggested that a change in compressional mechanism takes place. Received: 14 November 2000 / Accepted: 9 January 2002     

Analyzing CO2 emissions mitigation by technology improvement in Central and Eastern Europe

As a legacy of the centrally planned economy, the economies in transition of Central and Eastern Europe (CEE) have a unique potential to reduce their greenhouse gas emissions through the improvement in their high energy intensities. Since much of this `low-hanging fruit' in energy-efficiency improvements can be highly cost-effective, many developed countries facing difficulties in meeting their greenhouse gas (GHG) emission targets domestically are eager to find such opportunities in the CEE region. Therefore, studies analysing the potentials and costs of carbon dioxide reduction through technology improvement in the region have come into the limelight. While there are a few excellent studies in the region aimed at analysing climate change abatement potentials, they all embark on different assumptions, methodologies and boundary conditions. It is hence difficult, if not impossible, to compare and analyse the results of these studies across different authors, countries or time horizons. Consequently, the purpose of this paper is to place four leading studies on GHG mitigation through technology improvement from the CEE region into an internationally comparable framework. Four studies were selected from three countries, Poland, Hungary and Estonia, which are all the results of major national and international efforts to assess costs and potentials of GHG reduction. The paper places their assumptions, methods and final results into a framework which enables policy-makers and project designers to compare these across geographical and technological boundaries. Since other studies from around the globe have been analysed in this framework in the literature, this paper provides a vehicle for the findings of these four studies to be compared to others worldwide. In addition, the paper highlights a few areas where similar studies to be completed in the future in the region may be enhanced by incorporating features used in GHG mitigation research in other parts of the world. This revised version was published online in July 2006 with corrections to the Cover Date.     

A methodology for the evaluation of long-term volcanic risk from pyroclastic flows in Campi Flegrei (Italy)

The volcanological history of Campi Flegrei suggests that the most frequent eruptions are characterized by the emplacement of pyroclastic flow and surge deposits erupted from different vents scattered over a 150-km² caldera. The evaluation of volcanic risk in volcanic fields is complex because of the lack of a central vent. To approach this problem, we subdivided the entire area of Campi Flegrei into a regular grid and evaluated the relative spatial probability of opening of vents based on geological, geophysical and geochemical data. We evaluated the volcanic risk caused by pyroclastic flows based on the formula proposed by UNESCO (1972), R=H×V×Va, where H is the hazard, V is the vulnerability and Va is the value of the elements at risk. The product H×V was obtained by performing simulations of type eruptions centered in each cell of the grid. The simulation is based on the energy cone scheme proposed by Sheridan and Malin [J. Volcanol. Geotherm. Res. 17 (1983) 187–202], hypothesizing a column collapse height of 100 m for eruptions of VEI=3 and 300 m for eruptions of VEI=4 with a slope angle of 6°. Each simulation has been given the relative probability value associated with the corresponding cell. We made use of the GIS software ArcView 3.2 to evaluate the intersection between the energy cone and the topography. The superposition of the areas invaded by pyroclastic flows (124 simulations for VEI=3 and 37 for VEI=4) was used to obtain the relative hazard map of the area. The relative volcanic risk map is obtained by superimposing the urbanization maps.     

城市震害高危害小区的研究和GIS的实现技术

论述了在城市地震灾害中如何考虑诸方面因素来评价城市的灾害轻重分布情况。中建立坑危害小区分析模型，设想将城市划分等面积网格，给每个单元网格赋予灾害指数，以确定城市中受灾较为严重的区域，为求灾指挥提供决策信息。同时，将高危害小区的模型研究结果转化为计算机技术可以实现的GIS模型。该研究结果已应用于泰安市防震减灾示范研究项目中。     

关于绝对重力仪的发展和我们的思考

介绍了近年来出现的新型绝对重力仪，认为该仪器是控制地球重力场信息的重要工具，特别对FG5型的如何改进及我国绝对重力仪的如何发展，提出了建议。     

Nonlinear earthquake response analysis and energy calculation for seismic slit shear wall structures

Based on the concept of structural passive control, a new type of slit shear wall, with improved seismic performance when compared to an ordinary solid shear wall, was proposed by the authors in 1996. The idea has been verified by a series of pseudo-static and dynamic tests. In this paper a macro numerical model is developed for the wall element and the energy dissipation device. Then, nonlinear time history analysis is carried out for a 10-story slit shear wall model tested on a shaking table. Furthermore, the seismic input energy and the individual energy dissipated by the components are calculated by a method based on Newmark-β assumptions for this shear wall model, and the advantages of this shear wall are further demonstrated by the calculation results from the viewpoint of energy. Finally, according to the seismic damage criterion on the basis of plastic accumulative energy and maximum response, the optimal analysis is carried out to select design parameters for the energy dissipation device.