河南省熊耳山西段沙沟西银铅矿区地质特征及找矿前景分析

通过对熊耳山地区沙沟西银铅矿区域地质背景、矿区地质特征和矿体特征、矿化富集特点的分析。综合本区地质及地球物理、地球化学特征，提出沙沟西银铅矿区具有大型银铅矿的找矿前景。     

豫西金矿类型划分

豫西金矿矿床类型复杂，在前人的金矿床类型划分的基础上，根据豫西金矿床明显的野外地质特征，提出了豫西金矿类型划分方案，并对各金矿床类型的地质特征进行了简述，同时，对它们之间的共性作了总结。指出：豫西各类金矿类型之间既存明显的区别又具有密切的时间和空间上的成因联系，这一特点对用于拓宽该地区进一步的金矿找矿思路是十分必要的。     

河南内乡-淅川-带的虎睛石矿床及开发利用

研究区虎睛石矿床在地质特征、矿物组合、化学成分及琢雕效果等方面与国外虎睛石矿床是完全不同的，属于一种特殊的罕见类型。在分析虎睛石地质特征、开发利用现状的基础上，认为该区的虎睛石资源丰富，琢雕效果好，在国内外市场上具有一定的竞争力和良好的开发利用前景。     

GEOCHEMICAL EXPLORATION

正20142366Bi Yuanqing(Institute of Geophysical and Geochemical Survey Technology of Anhui Province,Hefei 230022,China);Fang Junhua Analysis of Ore-Prospecting Potential in the Taojiaxiang Mining Site,Zongyang County(Geology of Anhui,ISSN1005-6157,CN34-1111/P,23(4),2013,p.256-260,5illus.,10refs.)     

COAL GEOLOGY

正20141574 Chen Hao(Exploration and Development Research Institute,Daqing Oilfield Company,Daqing 163712,China)High-Resolution Sequences and Coal Accumulating Laws in Nantun Formation of Huhe Lake Sag(Petroleum GeologyOilfield Development in Daqing,ISSN1000-3754,CN23-1286/TQ,32(4),2013,p.15-19,5 illus.,15 refs.)Key words:coal accumulation regularity,coal     

ROCKS & MINERALS DETERMINATION AND ANALYSIS

正20142093Chen Daohua(Guangzhou Marine Geological Survey,Guangzhou 510075,China);Diao Shaobo The Latest Progress of Geological Marine Testing Technology in China(Rock and Mineral Analysis,ISSN0254-5357,CN11-2131/TD,32(6),2013,p.850-859,105refs.)Key words:chemical analysis,China     

河南老湾金矿床上上河矿段矿床地质和成矿流体地球化学

河南桐柏老湾金矿床是桐柏-大别山(北坡)金银成矿带内大型造山带型金矿床之一。文章对该矿床的上上河矿段进行了矿床地质和成矿流体地球化学研究,旨在查明该矿段的流体成矿过程。根据矿脉穿插关系、矿石结构构造、矿物共生组合以及黄铁矿的粒度和晶形,将老湾金矿上上河矿段成矿过程划分为:石英粗粒自形黄铁矿(Ⅰ)、石英细粒半自形-他形黄铁矿(Ⅱ)、石英多金属硫化物(Ⅲ)及石英碳酸盐(Ⅳ)4个阶段。镜下观察显示,矿床中的包裹体类型有含CO_2包裹体(LH_2O+LCO_2+VCO_2)、纯CO_2包裹体(LCO_2+VCO_2)、液相包裹体(LH_2O+VH_2O)及少量含子晶包裹体(LH_2O+VH_2O+S)。第Ⅰ阶段、第Ⅱ阶段和第Ⅲ阶段均可见含CO_2包裹体、纯CO_2包裹体和液相包裹体,有时可见含CO_2包裹体与液相包裹体共存。流体包裹体显微测温结果表明,成矿流体可近似看做中温、低盐度、富CO_2的NaCl-H_2O-CO_2体系,纯CO_2包裹体和液相包裹体所代表的流体可能是由含CO_2包裹体所代表的Na Cl-H_2O-CO_2流体经不混溶形成的,三者在寄主矿物沉淀时,被同时捕获而共存。从第Ⅰ阶段到第Ⅳ阶段,成矿流体温度从303~379℃逐渐降低到138~195℃,盐度w(Na Cleq)从4.07%~9.59%逐渐降低到1.06%~2.74%。在成矿的第Ⅰ阶段成矿流体发生了不混溶作用,而在第Ⅱ阶段和第Ⅲ阶段流体中的CO_2起泡分离再次引发了不混溶作用。从第Ⅰ阶段到第Ⅲ阶段,成矿流体的δ18OH_2O从6.56‰~9.71‰经1.89‰~4.01‰变化到0.08‰,δDH_2O从-78.1‰~-64.2‰经-79.5‰~-76.3‰变化到-72.6‰,表明老湾金矿第Ⅰ阶段成矿流体主要为岩浆热液,第Ⅱ阶段成矿流体中有少量大气降水加入,第Ⅲ阶段成矿流体中大气降水的比例明显加大。     

Characteristic and Geological Significance of Microbially Induced Sedimentary Structures(MISS) in Terrestrial P-T Boundary in Xingyang,Western He’nan Province

Microbially Induced Sedimentary Structures (MISS) are primary sedimentary structures that arise syndepositionally from microbial community activity. Especially valuable are MISS for the analysis of early Archean (and extraterrestrial) deposits. However, most reports of MISS have focused on the Precambrian and Phanerozoic mass extinction marine sediments, and only a few and terrestrial MISS have been studied. The MISS presented in this paper, which mainly consists of mat growth feature, mat destruction feature and mat decay feature, are well preserved in terrestrial clastic rocks around the P-T boundary in Xiyang area, western Henan. Large U ridges, oriented sand quartz, mica grains and thin clayey laminae arranged parallel to bedding plane are the main features visible under the microscope. Several lines of evidence indicate that the Xingyang MISS are of biogenic origin. Abundant MISS in Xingyang may indicate the degradation of terrestrial ecosystems and proliferation of microbial mats immediately after the severe Permian-Triassic mass extinction. Study aiming at MISS helps to analyze their space distribution in the globe and to probe into links between microbial proliferation and environmental stresses following the end-Permian mass extinction in terrestrial ecosystems.     

河南义马地区页岩气储层孔隙非均质性

运用高压压汞、液氮吸附及渗透率测试等实验,利用极差、突进系数、变异系数等参数,表征煤系页岩孔渗特征及孔隙层间非均质性,分析孔隙层间非均质性主控因素。结果表明:河南义马地区上、下石盒子组泥页岩微孔与小孔较为发育,山西组大孔较为发育,分别提供了气体吸附附着面积和储存运移空间;上石盒子组孔容与孔径相对偏差最小,孔隙分布均匀,山西组比表面积相对偏差最小,表面积分布均匀;随围压增大,渗透率不断降低,且满足负指数相关关系;渗透率级差、突进系数和变异系数显示下石盒子组渗透率非均质性较弱,山西组渗透率非均质性很弱,更易于压裂开发。非均质性宏观上主要受沉积物质组成和构造改造作用影响,微观上受成岩演化影响。     

河南嵩县松里沟金矿床中碲化物的发现及其地质意义

松里沟金矿位于华北陆块南缘熊耳山地区,已探明金资源储量26 t。矿体产于中新太古界-古元古界太华群片麻岩NWW向的断裂带中。其热液成矿过程包括4个成矿阶段:黄铁矿-石英阶段、石英-黄铁矿阶段、金-碲化物阶段和石英-碳酸盐阶段。显微镜下发现金-碲化物阶段存在大量与金共生的碲化物。利用电子探针和能谱分析查明碲化物的种类、共生关系和形成条件,确认的碲化物有碲铅铋矿、碲铅矿、碲铋矿、碲金矿、碲金银矿、硫碲铋铅金矿、辉碲铋矿,此外还有大量的自然金和少量的辉铋矿。该矿床为一与岩浆作用有关的碲金矿床。Au主要以自然金和金银碲化物的形式存在。Au、Ag以硫氢络合物的形式发生迁移,Te2(g)和H2Te(g)冷凝进入含贵金属的氯化物溶液是碲化物沉淀主要机制。相图及化学反应方程式分析表明,金-碲化物阶段受温度、碲逸度、硫逸度、氧逸度和酸碱度控制,其中,黄铁矿-石英阶段和石英-黄铁矿阶段形成于logf_(Te2)-14.4和logf_(S2)=-11.1~-6.5的环境。金-碲化物阶段形成于温度为110~313℃、logf_(Te2)=-15.2~-9.4和logf_(S2)=-16.5~-14.6、f_(O_2)升高和pH值降低的环境。碲化物的发现为探讨该矿床成因和熊耳山地区寻找同类型的矿床提供了依据。