Vertical distribution and water solubility of phosphorus and heavy metals in sediments of the St. Lucie Estuary, South Florida, USA

Accumulation and distribution of heavy metals and phosphorus in sediments impact water quality. There has been an increasing concern regarding fish health in the St. Lucie Estuary, which is related to increased inputs of nutrients and metals in recent decades. To investigate vertical changes of contaminants (P, Cd, Cr, Co, Cu, Ni, Pb, Zn, and Mn) in sediments of the St. Lucie Estuary in South Florida, 117 layer samples from six of the 210 to 420 cm depth cores were analyzed for their total and water-soluble P and heavy metals, clay, total Fe, Al, K, Ca, Mg, Na, and pH. Principal component analysis (PCA) was used in two sets of analytical data (total and water-soluble contaminant concentrations) to document changes of contaminants in each core of sediments. The PCA of total contaminants and minerals resulted in two factors (principal components). The first and second factors accounted for 61.7 and 17.2 % of the total variation in all variables, and contrast indicators associated with contaminants of P, Cd, Co, Cr, Ni, Pb, Zn, and Mn and accumulation of Fe and Al oxides, respectively. The first factor could be used for overall assessment of P and heavy metal contamination, and was higher in the upper 45–90 cm than the lower depths of each core. The concentrations of P and heavy metals in the surface layers of sediments significantly increased, as compared with those in the sediments deeper than 45–90 cm. The PCA of water-soluble contaminants developed two factors. The second factor (Cu–P) was higher in the upper than the lower depths of the sediment, whereas the highest score of the first factor (Cd–Co–Cr–Ni–Pb–Zn–Mn) occurred below 100 cm. The water-soluble Cu and P concentrations were mainly dependent on their total concentrations in the sediments, whereas the water-soluble Cd, Co, Cr, Ni, Pb, Zn, and Mn concentrations were mainly controlled by pH.     

梅雨锋云系的结构特征及其成因分析

利用逐时卫星遥感观测资料和地面测站的降水资料，分析了江淮流域2003年6月22～26日暴雨过程中梅雨锋云系的演变、结构特征和形成原因。结果表明，梅雨锋云系为一条TBB的低值带，稳定少动，其上分布着中尺度对流系统（MCS），而中尺度对流系统是由不同尺度、不同强度．的对流单体（包括中β和中γ尺度对流单体）组成的，从而使得梅雨锋云系产生不均匀的降水分布（包括时间上和空间上）。在该暴雨过程中，梅雨锋云系充分体现了中尺度对流系统中所包括的3类组织结构形式。梅雨锋云系与中高纬度云系或热带辐合带云系之间的相互作用与暴雨过程关系密切，梅雨锋云系的维持和发展与强大的黄淮气旋云系直接相关，它是江淮流域上空冷暖气流交汇的结果。     

非地转强迫对Fitow(0114)暴雨的影响

利用非静力中尺度模式MM5对 0 114号台风Fitow从 2 0 0 1年 8月 31日 0 0时～ 9月 2日 0 0时 (UTC ,下同 )的降水过程进行了模拟研究。结果表明 ,MM5对Fitow登陆过程中暴雨落区和强度的模拟与实况比较一致。模拟结果较好地再现了暴雨的中尺度特征。正是维持少动的台风倒槽和嵌入其中的中小尺度系统相互作用造成了暴雨的发生、发展 ,而高、低空中尺度散度场的配置对暴雨有很好的指示意义。在华南台风暴雨区无论是高层还是低层 ,都存在很强的非地转作用 ,非地转涡度项对散度倾向项是重要的强迫因素 ;但非地转作用的实现与中高纬度地区有本质的区别 ,在低层非地转作用是由于强的位势场气旋涡度 (- 2  <0 )与弱的流场气旋涡度 (fζ >0 )不平衡产生的 ;而高层非地转作用是由于强的位势场反气旋涡度 (- 2  >0 )与弱的流场反气旋涡度 (fζ <0 )不平衡产生的。非地转作用是暴雨中尺度系统上升运动发展的触发机制。从动力学角度解释了用非地转 Q矢量散度场来判断暴雨落区要比用准地转 Q矢量散度场好的原因。     

Evolution of the fogwater composition in Strasbourg (France) from 1990 to 1999

The chemical composition of fogwater has been studied in the city of Strasbourg (France) from 1990 to 1999. During these years, fogwater samples have been collected and analysed for major ions and trace metals. This paper reports on the analysis of the collected dataset. The analysis revealed a significant decrease in acidity of approximately one pH unit over the course of the study. This decrease in acidity appears to be linked to a decrease in SO_2(g) and the resulting SO₄²⁻. Trace metal concentrations have also strongly decreased over the 10-year period. Pb concentrations, following the elimination of leaded gasoline, decreased by more than one order of magnitude.     

Soluble organic compounds in fog and cloud droplets: what have we learned over the past few years?

We have recently set up a new procedure for characterising the water soluble organic compounds (WSOC) in fog water, for which information is still rather limited. Fog samples collected during the 1998–1999 fall–winter season in the Po Valley (Italy) were analysed following this procedure, which allows a quantitative determination of three main classes of organic compounds (neutral species, mono- and di-carboxylic acids, polycarboxylic acids), together accounting for ca. 85% of the total WSOC. This procedure also provides information on the main chemical characteristics of these three classes of compounds (functional groups, aliphatic vs. aromatic character, etc.). The enhanced chemical knowledge on fog/cloud chemical composition opens new scenarios as far as chemical and microphysical processes in clouds and fogs are concerned.     

沿海表层沉积物中重金属的有效结合态

以浙江沿海表层沉积物为研究对象,系统地研究了重金属有效结合态与沉积环境、矿物组成和人为排放等环境因素之间的相互关系.结果表明:沿海表层沉积物中重金属的积累数量,呈现出潮汐河口沉积物>沿海沉积物>强潮汐河口沉积物的趋势,这反映了不同沉积类型对重金属富集作用的差异;重金属的有效结合态,总体上以铁锰氧化物结合态>碳酸盐结合态>硫化物及有机结合态>可交换态的顺序存在,但是不同的重金属或同种重金属在不同的采点,主要有效结合态的比例存在明显的差异,这不仅与重金属的地球化学性质、沉积环境和沉积物中的粘土矿物组成有关,更受到重金属污染物的人为排放量的影响.     

重庆雾的特点及其变化分析

利用重庆市沙坪坝195l一2001年的资料，对重庆市区雾的生消时间、持续时间、能见度等主要特征变量及其相对湿度，温度差等相关气象要素做了较为全面的分析，认为城市热岛效应可能是造成重庆主城区雾日数减少的重要原因之一。     

北京地区一次典型大雾天气的空气污染过程物理量分布特征

2002年11月30至12月4日，北京持续4天大雾天气，空气污染物在持续的稳定层结条件下，空气质量连续3天达5级以上。文中分析了大雾天气各主要污染物的变化特征，以及此次过程中天气形势的特点及演变，并对造成大雾日空气污染天气的物理量分布特征进行分析。结果表明：高空WNW气流、稳定性持续增加、逆温层结持续存在、低空风速较小、相对湿度大，导致局地污染物不能及时随大气扩散；1000～700hPa有弱的上升气流形成和维持，与500hPa高空下沉气流之间在低空的某层高度上形成稳定层结(逆温层)，导致大雾及重污染的形成；850hPa为暖区，850～500hPa为冷平流，有利于大雾的形成和加重。     

Monitoring of rapid salt weathering in the central Namib Desert using limestone blocks

Pre-weighed blocks of a Jurassic Limestone were exposed on the ground surface in the coastal Namib Desert for a period of 2 years. The environment is both salty and foggy. Some of the blocks suffered extensive disintegration, and laboratory analyses (including geochemistry, XRD and SEM) indicate that the weathered samples have a high halite (sodium chloride) content. Cycles of wetting and drying associated with the frequent fog events of the area cause cycles of halite crystallization. Rocks exposed at the surface absorb salts from the surrounding desert surface and then disintegrate, contributing to planation of the landscape.     

Heavy metal retention in secondary precipitates from a mine rock dump and underlying soil, Dalarna, Sweden

This study investigates the retention of heavy metals in secondary precipitates from a sulfidic mine rock dump and underlying podzolic soils by means of mineralogical and chemical extraction methods. The rock dump, which is at least 50 years old, consists of a 5–10-cm-thick leached zone and an underlying 110–115-cm-thick accumulation zone. Optical microscopy and electron microprobe analyses confirm that pyrrhotite weathering has proceeded much further in the leached horizon relative to the accumulation horizon. The weathering of sulfides in the leached zone has resulted in the migration of most heavy metals to the accumulation zone or underlying soils, where they are retained in more stable phases such as secondary ferric minerals, including goethite and jarosite. Some metals are temporarily retained in hydrated ferrous sulfates (e.g., melanterite, rozenite). Received: 28 October 1996 · Accepted: 24 February 1997