中国西北部盆地岩石热导率和生热率特征

本文根据大量实测数据,首次系统地报道了中国西北地区塔里木盆地、准噶尔盆地和柴达木盆地内的岩石热导率、岩石放射性生热率数据及其分布特征.对600多个岩石热导率和100多个实测岩石生热率的统计分析表明,沉积盆地中岩石的热物理性质与其岩性、埋藏深度和地层时代密切相关.随深度和地层时代的加大,岩石热导率增大;塔里木盆地的岩石热导率的总体平均值最大,而柴达木盆地的最小.岩石生热率在上地壳的分布是随深度的增加而减小的,但在沉积盆地的深度范围内几乎不变,其分布是均匀的,仅不同岩性的生热率差别较大.估算的岩石放射性生热产生的热量可以占到盆地地表热流的25%～45%.因此,岩石热物理性质的参数不仅与盆地的地温分布和大地热流特征密切相关,还可以为该地区盆地热历史恢复及深部地球物理的研究提供有效的参数和边界条件.     

土壤离子电导率测量在可地浸砂岩铀矿找矿勘查中的实验研究

土壤离子电导率测量是隐伏金属矿床、贵金属矿床普查找矿的重要技术方法,本研究应用该方法对隐伏可地浸砂岩铀矿进行普查找矿实验研究。实验表明,本区土壤离子电导率背景值为22.91μs/cm,异常平均值为513.96μs/cm,最高异常值达1349.30μs/cm。它可以圈定舌状蚀变砂岩体与未蚀变砂岩的接触边界,从而可以圈定隐伏砂岩铀矿的产出位置,是隐伏可地浸砂岩铀矿普查找矿的既经济又有效的方法。     

EH-4系统观测资料的非远区场校正研究

EH－4系统实测的卡尼亚视电阻率在非远区场时应作必要的校正。基于导出的EH－4系统的卡尼亚电阻率ρxy和ρyx的表达式，采用多项式分段逼近的方法，建立EH－4系统测深数据的全频域的视电阻率算法。根据建立的算法对均匀大地、二层大地和三层大地模型的EH－4系统测深数据进行非远区场校正的结果表明：均匀大地时，全频域的视电阻率与真电阻率吻合很好，D型、K型和Q型断面的视电阻率曲线与MT法的接近，G型、H型和A型的视电阻率曲线得到很大改善。     

离散裂隙渗流方法与裂隙化渗透介质建模

流体渗流模拟的连续介质方法通常适用于多孔地质体，并不一定适用于裂隙岩体，由于裂隙分布及其特征与孔隙差异较大。若流体渗流主要受裂隙的控制，对于一定尺寸的裂隙岩体，多孔介质假设则较难刻划裂隙岩体的渗流特征。离散裂隙渗流方法不但可直接用于模拟裂隙岩体非均质性和各向异性等渗流特征，而且可用其确定所研究的裂隙岩体典型单元体及其水力传导（渗透）张量大小。主要讨论了以下问题：（1）饱和裂隙介质中一般的离散流体渗流模拟；（2）裂隙岩体中的REV（典型单元体）及其水力传导（渗透）张量的确定；（3）利用离散裂隙网络流体渗流模型研究裂隙方向几何参数对水力传导系数和REV的影响；（4）在二维和三维离散裂隙流体渗流模型中对区域大裂隙和局部小裂隙的处理方法。调查结果显示离散裂隙流体渗流数学模型可用来评价不同尺度上的裂隙岩体的水力特征，以及裂隙方向对裂隙化岩体的水力特征有着不可忽视的影响。同时，局部小裂隙、区域大裂隙应当区别对待，以便据其所起的作用及水力特征，建立裂隙化岩体相应的流体渗流模型。     

Heat flow and thermal modeling of the Yinggehai Basin, South China Sea

Geothermal gradients are estimated to vary from 31 to 43 °C/km in the Yinggehai Basin based on 99 temperature data sets compiled from oil well data. Thirty-seven thermal conductivity measurements on core samples were made and the effects of porosity and water saturation were corrected. Thermal conductivities of mudstone and sandstone range from 1.2 to 2.7 W/m K, with a mean of 2.0±0.5 W/m K after approximate correction. Heat flow at six sites in the Yinggehai Basin range from 69 to 86 mW/m², with a mean value of 79±7 mW/m². Thick sediments and high sedimentation rates resulted in a considerable radiogenic contribution, but also depressed the heat flow. Measurements indicate the radiogenic heat production in the sediment is 1.28 μW/m³, which contributes 20% to the surface heat flow. After subtracting radiogenic heat contribution of the sediment, and sedimentation correction, the average basal heat flow from basement is about 86 mW/m².Three stages of extension are recognized in the subsidence history, and a kinematic model is used to study the thermal evolution of the basin since the Cenozoic era. Model results show that the peak value of basal heat flow was getting higher and higher through the Cenozoic. The maximum basal heat flow increased from 65 mW/m² in the first stage to 75 mW/m² in the second stage, and then 90 mW/m² in the third stage. The present temperature field of the lithosphere of the Yinggehai Basin, which is still transient, is the result of the multistage extension, but was primarily associated with the Pliocene extension.     

Low-temperature thermodynamic properties of disordered zeolites of the natrolite group

 The heat capacity of paranatrolite and tetranatrolite with a disordered distribution of Al and Si atoms has been measured in the temperature range of 6–309 K using the adiabatic calorimetry technique. The composition of the samples is represented with the formula (Na_1.90K_0.22Ca_0.06)[Al_2.24Si_2.76O₁₀]·nH₂O, where n=3.10 for paranatrolite and n=2.31 for tetranatrolite. For both zeolites, thermodynamic functions (vibrational entropy, enthalpy, and free energy function) have been calculated. At T=298.15 K, the values of the heat capacity and entropy are 425.1 ± 0.8 and 419.1 ±0.8 J K⁻¹ mol⁻¹ for paranatrolite and 381.0 ± 0.7 and 383.2 ± 0.7 J K⁻¹ mol⁻¹ for tetranatrolite. Thermodynamic functions for tetranatrolite and paranatrolite with compositions corrected for the amount of extraframework cations and water molecules have also been calculated. The calculation for tetranatrolite with two water molecules and two extraframework cations per formula yields: C _p (298.15)=359.1 J K⁻¹ mol⁻¹, S(298.15) −S(0)=362.8 J K⁻¹ mol⁻¹. Comparing these values with the literature data for the (Al,Si)-ordered natrolite, we can conclude that the order in tetrahedral atoms does not affect the heat capacity. The analysis of derivatives dC/dT for natrolite, paranatrolite, and tetranatrolite has indicated that the water- cations subsystem within the highly hydrated zeolite may become unstable at temperatures above 200 K. Received: 30 July 2001 / Accepted: 15 November 2001     

Premelting and calcium mobility in gehlenite (Ca2Al2SiO7) and pseudowollastonite (CaSiO3)

 Premelting effects in gehlenite (Ca₂Al₂SiO₇) have been studied by Raman spectroscopy and calorimetry, and in gehlenite and pseudowollastonite (CaSiO₃) by electrical conductivity. The enthalpy of premelting of gehlenite is 17.3 kJ mol⁻¹ and represents 9% of the reported enthalpy of fusion, which is in the range of the reported fraction of other minerals. The Raman and electrical conductivity experiments at high temperatures, for gehlenite and pseudowollastonite, show that the premelting effects of both compositions are associated with enhanced dynamics of calcium atoms near the melting point. This conclusion agrees with the results obtained for other minerals like diopside, but contrasts with those found for sodium metasilicate in which the weaker bonding of sodium allows the silicate framework to distort near the melting temperature and deform in such a way to prefigure the silicate entities present in the melt. Received: 30 April 2002 / Accepted: 7 August 2002 Acknowledgements We thank Y. Linard for help with DSC measurements and two anonymous reviewers for their constructive comments. This work has been partly supported by the EU Marie-Curie fellowship contract no. HPMF-CT-1999-00329, the CNRS-Carnegie Institution of Washington program PICS no.192, and the NSF grants EAR-9614432 and EAR-9901886 to B.O.M.     

Fluid permeability of sedimentary rocks in a complete stress–strain process

The permeability of sedimentary rocks during triaxial compression tests was investigated to relate it to the complete strain–stress process. It was found that the permeability was not constant, but varied with the stress and strain states in the rocks. Prior to the peak strength, the permeability decreases with increasing load. A dramatic increase in permeability occurs during the strain softening period. In the present study, in situ measurements of fluid flow and pressure in floor strata was carried out in a double longwall mining face in the Yangzhuang colliery. These measurements show that both the strata pressure and the position with respect to the mining face influence the hydrogeologic properties. The permeability increased in the floor strata behind the mining face because those mining induced fractures opened as the strata pressure decreased. To better understand this change in hydraulic behavior around the mining faces, 3-D numerical modeling was carried out. The model provides the general picture of the stress distribution and failure zone both in the floor and roof strata. The field and model results demonstrate the importance of changes in the stress and strain states on the hydrogeology of a site.     

A method to estimate hydraulic conductivity while drilling

A field test and analysis method has been developed to estimate the vertical distribution of hydraulic conductivity in shallow unconsolidated aquifers. The field method uses fluid injection ports and pressure transducers in a hollow auger that measure the hydraulic head outside the auger at several distances from the injection point. A constant injection rate is maintained for a duration time sufficient for the system to become steady state. Exploiting the analogy between electrical resistivity in geophysics and hydraulic flow two methods are used to estimate conductivity with depth: a half-space model based on spherical flow from a point injection at each measurement site, and a one-dimensional inversion of an entire dataset.

The injection methodology, conducted in three separate drilling operations, was investigated for repeatability, reproducibility, linearity, and for different injection sources. Repeatability tests, conducted at 10 levels, demonstrated standard deviations of generally less than 10%. Reproducibility tests conducted in three, closely spaced drilling operations generally showed a standard deviation of less than 20%, which is probably due to lateral variations in hydraulic conductivity. Linearity tests, made to determine dependency on flow rates, showed no indication of a flow rate bias. In order to obtain estimates of the hydraulic conductivity by an independent means, a series of measurements were made by injecting water through screens installed at two separate depths in a monitoring pipe near the measurement site. These estimates differed from the corresponding estimates obtained by injection in the hollow auger by a factor of less than 3.5, which can be attributed to variations in geology and the inaccurate estimates of the distance between the measurement and the injection sites at depth.     

The experimental studies on electrical con-ductivities and P-wave velocities of anortho-site at high pressure and high temperature

Introduction The measurements of the compressional wave velocity and electrical conductivity of minerals and rocks are of fundamental importance to look into the earths interior, including composition, geotherm, generation and distribution of fluids and melts. Hydrous minerals formed by metamatu-siom are abundant within the earth. Previous studies have been carried out on the dehydration effect on the electrical conductivity and wave velocity of rocks such as serpentine, amphibole, most of whi…