The heat capacity of two natural chlorite group minerals derived from differential scanning calorimetry

The heat capacity of natural chamosite (X_Fe=0.889) and clinochlore (X_Fe=0.116) were measured by differential scanning calorimetry (DSC). The samples were characterised by X-ray diffraction, microprobe analysis and Mössbauer spectroscopy. DSC measurements between 143 and 623?K were made following the procedure of Bosenick et?al. (1996). The fitted data for natural chamosite (CA) in J?mol^?1?K^?1 give: C _p,CA = 1224.3–10.685?×?10³?×?T ^??0.5???6.4389?× 10⁶?×T ^??2?+?8.0279?×?10⁸?×?T ^??3 and for the natural clinochlore (CE): C _p,CE = 1200.5–10.908?×?10³?×T ^??0.5?? 5.6941?×?10⁶?×?T ^??2?+?7.1166?×?10⁸?×?T ^??3. The corrected C _p-polynomial for pure end-member chamosite (Fe₅Al)[Si₃AlO₁₀](OH)₈ is C _p,CAcor = 1248.3–11.116?× 10³?×?T ^??0.5???5.1623?×?10⁶?×?T ^??2?+?7.1867?×?10⁸×T ^??3 and the corrected C _p-polynomial for pure end-member clinochlore (Mg₅Al)[Si₃AlO₁₀](OH)₈ is C _p,CEcor = 1191.3–10.665?×?10³?×?T ^??0.5???6.5136?×?10⁶?×?T ^??2?+ 7.7206?×?10⁸?×?T ^??3. The corrected C _p-polynomial for clinochlore is in excellent agreement with that in the internally consistent data sets of Berman (1988) and Holland and Powell (1998). The derived C _p-polynomial for chamosite (C _p,CAcor) leads to a 4.4% higher heat capacity, at 300?K, compared to that estimated by Holland and Powell (1998) based on a summation method. The corrected C _p-polynomial (C _p,CAcor) is, however, in excellent agreement with the computed C _p-polynomial given by Saccocia and Seyfried (1993), thus supporting the reliability of Berman and Brown's (1985) estimation method of heat capacities.     

青藏高原东南缘热流估算及与地震活动相关性分析

青藏高原东南缘地区内部构造运动强烈,是地热资源发育与地震事件频发的活动地区.大地热流记录了发生在地球深部各种作用过程的热学信息,可以作为地质构造活动和地震活动研究的有效约束,但是大范围的热流数据测量很难实现,因此,本文根据居里面深度结合放射性元素分布等计算了青藏高原东南缘的大地热流分布.首先,通过地表放射性元素的分布计算出地表产热量的分布,然后,利用相关地热参数之间的关系迭代计算出该地区地壳上下层的热导率分布,最终估算出地表热流及地下不同深度处热流值的分布.本文结果表明：（1）青藏高原东南缘的大地热流位于44~108 mW·m^-2之间,平均75 mW·m^-2,符合研究地区西南高、东北低的背景趋势,地壳内部热流值随深度的增加而降低.大部分地区地表热流异常与实际地热带分布相吻合,如川西、藏东南与滇西地区等地为地热高值区,川东和楚雄等地为热流低值区.（2）结合其他地球物理探测结果,总结了地壳内部热流与地震事件的联系：在地热梯度带地区,当两侧地层在一定深度范围内存在明显物性差异时,地震事件高发.

     

利用卫星遥感资料反演感热和潜热通量的研究综述

区域平均感热和潜热通量是气象、水文、生态模式中的关键物理因子，卫星遥感反演为观测区域平均感热和潜热通量提供了可能。对利用卫星遥感资料反演地气通量的方法进行了总结和评述。首先描述了现在常用的反演方法，分析了方法中的各种假定对反演结果的影响，并对不同的模式反演结果进行了比较。还指出了评价卫星反演通量的精度时需要注意的问题。最后对该领域内现存的问题与发展方向进行探讨。     

The geothermal formation mechanism in the Gonghe Basin: Discussion and analysis from the geological background

The Gonghe Basin, a Cenozoic down-warped basin, is located in the northeastern part of the Qinghai-Xizang (Tibetan) Plateau, and spread over important nodes of the transfer of multiple blocks in the central orogenic belt in the NWW direction. It is also called “Qin Kun Fork” and “Gonghe Gap”. The basin has a high heat flow value and obvious thermal anomaly. The geothermal resources are mainly hot dry rock and underground hot water. In recent years, the mechanism of geothermal formation within the basin has been controversial. On the basis of understanding the knowledge of predecessors, this paper proposes the geothermal formation mechanism of the “heat source–heat transfer–heat reservoir and caprock–thermal system” of the Gonghe Basin from the perspective of a geological background through data integration-integrated research-expert, discussion-graph, compilation-field verification and other processes: (1) Heat source: geophysical exploration and radioisotope calculations show that the heat source of heat in the basin has both the contribution of mantle and the participation of the earth’s crust, but mainly the contribution of the deep mantle. (2) Heat transfer: The petrological properties of the basin and the exposed structure position of the surface hot springs show that one transfer mode is the material of the mantle source upwells and invades from the bottom, directly injecting heat; the other is that the deep fault conducts the deep heat of the basin to the middle and lower parts of the earth’s crust, then the secondary fracture transfers the heat to the shallow part. (3) Heat reservoir and caprock: First, the convective strip-shaped heat reservoir exposed by the hot springs on the peripheral fault zone of the basin; second, the underlying hot dry rock layered heat reservoir and the upper new generation heat reservoir and caprock in the basin revealed by drilling data. (4) Thermal system: Based on the characteristics of the “heat source-heat transfer-heat reservoir and caprock”, it is preliminarily believed that the Gonghe Basin belongs to the non-magmatic heat source hydrothermal geothermal system (type II2₁) and the dry heat geothermal system (type II2₂). Its favorable structural position and special geological evolutionary history have given birth to a unique environment for the formation of the geothermal system. There may be a cumulative effect of heat accumulation in the eastern part of the basin, which is expected to become a favorable exploration area for hot dry rocks.     

Expression of heat shock protein 70 in a permanent cell line (EPC) exposed to sediment extracts from the North Sea and the Baltic Sea

Heat shock proteins 70 (hsp70) are known to be induced by a great variety of chemical stressors. The effects of different environmental contaminants, which were identified in sediments of the North Sea and the Baltic Sea as main contaminants or as contaminants of special toxicological interest, on the extent of expression of hsp70 in a permanent cell line Epithelioma papulosum cyprini (EPC) were investigated. Concentrations of the single contaminants leading to elevated hsp70 levels were compared to the respective concentrations of these contaminants encountered in the sediment extracts thus allowing an assessment of their contribution to the toxicity of these sediments. Analysis of hsp70 was performed using western blotting techniques with subsequent comparative quantification by densitometry. Eleven of thirteen contaminants have shown a dose-dependent increase in hsp70 levels. An expression of hsp70 was observed in most cases between 0.1 and 10 microg/mL test solution. Some of the investigated stressors led to extremely high hsp70 contents even at low concentrations. However, in most cases contaminant concentrations in sediments were too low to cause an effect. For this reason, effects of the tested sediments are attributed to other contaminants or rather to mixtures of stressors.     

On the recent warming of the southeastern Bering Sea shelf

During the last decade, the southeastern Bering Sea shelf has undergone a warming of 3 °C that is closely associated with a marked decrease of sea ice over the area. This shift in the physical environment of the shelf can be attributed to a combination of mechanisms, including the presence over the eastern Bering Sea shelf of a relatively mild air mass during the winter, especially from 2000 to 2005; a shorter ice season caused by a later fall transition and/or an earlier spring transition; increased flow through Unimak Pass during winter, which introduces warm Gulf of Alaska water onto the southeastern shelf; and the feedback mechanism whereby warmer ocean temperatures during the summer delay the southward advection of sea ice during winter. While the relative importance of these four mechanisms is difficult to quantify, it is evident that for sea ice to form, cold arctic winds must cool the water column. Sea ice is then formed in the polynyas during periods of cold north winds, and this ice is advected southward over the eastern shelf. The other three mechanisms can modify ice formation and melt, and hence its extent. In combination, these four mechanisms have served to temporally and spatially limit ice during the 5-year period (2001–2005). Warming of the eastern Bering Sea shelf could have profound influences on the ecosystem of the Bering Sea—from modification of the timing of the spring phytoplankton bloom to the northward advance of subarctic species and the northward retreat of arctic species.     

北京平原区水源热泵应用适宜区划分

北京市水源热泵的应用,宏观上未充分考虑地下水水源地的分布,微观上未注重应用场地的水文地质条件,地下水回灌率低造成了水资源浪费。本文针对北京平原区的水文地质条件,以浅层含水层导水系数、有效导水系数、地下水中的铁和总硬度为评价因子,以水源地保护区及补给区、地面沉降中心区为约束因子,利用叠加分析技术,将平原区分为适宜发展区、较适宜发展区、限制发展区和禁止发展区,为水源热泵的理性推广提供了技术参考。     

1961-2010年辽宁省高温日数和高温热浪特征分析

利用1961-2010年辽宁省52个气象站日最高气温资料,分析辽宁地区高温日数及热浪的分布特征和变化趋势,结果表明：辽宁省区域年平均高温日数为7.72 d/ a。辽宁高温日数呈东少西多的空间分布,沿海地区较少甚至部分地区无高温情况出现。高温日出现最多的朝阳站,为26.48 d/ a。从20世纪60年代开始,高温日数呈缓慢增加趋势,其中2000年为有气象记录以来高温日最多的年份。热浪也呈东少西多的分布特征,热浪最多的朝阳站发生频次为2.90次/ a。辽宁省以持续3-5 d的轻度热浪为主,占86.27 %,中度热浪占12.58 %,超过10 d的重度热浪占1.14 %,仅有喀左、北票和羊山地区发生过持续10 d以上的重度热浪。     

辐射板强化喷管换热与红外抑制效果试验研究

试验研究了在发动机喷管中加装金属辐射板前后,喷管壁面温度、热喷流温度与喷管红外辐射特征的变化。结果表明,加装金属辐射板后,热喷流与喷管壁面之间的热量传递显著增强,热喷流中心温度降低,壁面温度明显升高,在90°方向上,热喷流3～5μm波段的红外辐射强度降低了38.5%。文中从热喷流、喷管壁面以及金属辐射板等相关部件的温度变化情况对红外辐射强度的变化原因进行了解释。      

人为热源对城市边界层结构影响的数值模拟研究

用南京大学多尺度模式系统在不同区域进行了多种人为热源引入方案的研究,结果表明：考虑时空变化的人为热源按比例分别引入到地表能量平衡方程和大气热量守恒方程是将人为热源引入模式的最优方案.人为热通量密度变化的敏感性试验结果发现：人为热源的存在对城市热岛的生成有重要作用.计算结果表明,南京现有的人为热源排放量对该地区的城市热岛贡献率约为29.6％,若人为热通量密度在现有量值的基础上增大1倍,则其热岛贡献率可达42.9％;此外,人为热的排放对清晨城市边界层逆温结构有一定程度的破坏作用,能明显升高夜间近地层气温达0.5～1.0℃,并能使白天湍流活动的影响范围增大,混合层高度抬高,使夜间城市热岛环流的影响范围扩大.