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41.
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43.
Wenjun Yong E. Dachs A. C. Withers E. J. Essene 《Contributions to Mineralogy and Petrology》2008,155(2):137-146
The low-temperature heat capacity (C
p) of Si-wadeite (K2Si4O9) synthesized with a piston cylinder device was measured over the range of 5–303 K using the heat capacity option of a physical
properties measurement system. The entropy of Si-wadeite at standard temperature and pressure calculated from the measured
heat capacity data is 253.8 ± 0.6 J mol−1 K−1, which is considerably larger than some of the previous estimated values. The calculated phase transition boundaries in the
system K2O–Al2O3–SiO2 are generally consistent with previous experimental results. Together with our calculated phase boundaries, seven multi-anvil
experiments at 1,400 K and 6.0–7.7 GPa suggest that no equilibrium stability field of kalsilite + coesite intervenes between
the stability field of sanidine and that of coesite + kyanite + Si-wadeite, in contrast to previous predictions. First-order
approximations were undertaken to calculate the phase diagram in the system K2Si4O9 at lower pressure and temperature. Large discrepancies were shown between the calculated diagram compared with previously
published versions, suggesting that further experimental or/and calorimetric work is needed to better constrain the low-pressure
phase relations of the K2Si4O9 polymorphs.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
44.
断裂构造能够引起重力场的异常分布,温泉热源的形成和空间展布主要受深大断裂、基底构造等地质因素控制。基于这一思路,根据该区重力资料,结合地质及其它地球物理资料对深部地质结构做了一些探讨。对重力资料进行了一些处理,挖掘深部地质信息,根据所得信息推断出了一些基底断裂,有一些是本次重力结果新发现的断裂。此外,还证实了前人已圈定的断裂构造,这些构造在控热、导热作用方面起着重要作用,深大断裂、基底构造它们交汇部位附近是寻找温泉热源的有利地区。 相似文献
45.
Wenjun Yong E. Dachs A. C. Withers E. J. Essene 《Physics and Chemistry of Minerals》2007,34(2):121-127
A multi-anvil device was used to synthesize 24 mg of pure γ-Fe2SiO4 crystals at 8.5 GPa and 1,273 K. The low-temperature heat capacity (C
p) of γ-Fe2SiO4 was measured between 5 and 303 K using the heat capacity option of a physical properties measurement system. The measured
heat capacity data show a broad λ-transition at 11.8 K. The difference in the C
p between fayalite and γ-Fe2SiO4 is reduced as the temperature increases in the range of 50–300 K. The gap in C
p data between 300 and 350 K of γ-Fe2SiO4 is an impediment to calculation of a precise C
p equation above 298 K that can be used for phase equilibrium calculations at high temperatures and high pressures. The C
p and entropy of γ-Fe2SiO4 at standard temperature and pressure (S°298) are 131.1 ± 0.6 and 140.2 ± 0.4 J mol−1 K−1, respectively. The Gibbs free energy at standard pressure and temperature (ΔG°
f,298) is calculated to be −1,369.3 ± 2.7 J mol−1 based on the new entropy data. The phase boundary for the fayalite–γ-Fe2SiO4 transition at 298 K based on current thermodynamic data is located at 2.4 ± 0.6 GPa with a slope of 25.4 bars/K, consistent
with extrapolated results of previous experimental studies. 相似文献
46.
西太平洋赤道海域的热量平衡 总被引:1,自引:0,他引:1
本文利用1986年11月中国科学院实验3号考察船在西太平洋赤道海域(0°~5°N,130°~150°E)考察所获得的29天辐射资料和同期取得的温、压、湿、风和探空等资料,计算了这一海域11月份的热量平衡各量值和整层气柱的加热量。结果表明:该海域是一个强热源区,其上空大气也是一个强热源区。 相似文献
47.
48.
Juan Pedro Montávez Juan Ignacio Jiménez Antonio Sarsa 《Boundary-Layer Meteorology》2000,96(3):433-452
A model for the urban canyon is formulated for meteorologicalconditions of weak winds at night time. Thermal radiation, conductivity and convection are simulated by means of the Monte Carlo method. These are the main physical processesof energy transfer that give rise to the characteristic temperaturedistribution in these systems. The model has been satisfactory tested under ideal conditions for which analytical solutions exist.The predictions of the model under morerealistic conditions accurately reproduce the observationalresults. A strong temperature gradient across streets, with the canyon corners up to 4 °C warmer than the canyon centre, is found for the deepest canyons. This theoretical predictionhas been successfully verified with measurementstaken in a number of streets of the city of Granada in Spain. 相似文献
49.
The responses of sea surface temperature (SST) in the western equatorial Pacific warm pool to the west erly wind bursts (WWBs) play an important role in the relationship between WWB and ENSO. By using da ta collected from eight buoys of TOGA (Tropical Ocean-Global Atmosphere)-COARE (Coupled Ocean-Atmosphere Response Experiment), the heat balances of the upper ocean in the western equatorial Pacific around 0°. 156°E during two WWB events were calculated according to Stevenson and Niiler's (1983) method. In both events, SST increased before and after the WWBs, while decreased within the WWBs. The SST amplitudes approximated to l℃. Although sometimes the horizontal heat advections may become the biggest term in the heat balance, the variation of SST was dominated by the surface heat flux. On the other aspect, some different features of the two events are also revealed. The two cases have different variation of mixed layer depth. The depth of mixed layer is almost double in the first case (35 m to 70 m), which is caused by Ekman convergence, while only 10m increments due to entrainment in the second one. There are also differences in the currents structure. The different variations of thermal and currents struc ture in the mixing layers accounted for the different variation of the heat balance during the two events, es pecially the advection and residue terms. The seasonal variation of SST in this area is also investigated sim ply. The first WWB event happened just during the seasonal transition. So we considered that it is a normal season transition rather than a so-called anomaly. That also suggested that the seasonal distinction of the WWB is worthy of more attention in the researches of its relationship to ENSO. 相似文献
50.
The transfer processes within and above a simulated urban street canyon were investigated in a generic manner. Computational
fluid dynamics (CFD) was used to aid understanding and to produce some simple operational parameterisations. In this study
we addressed specifically the commonly met situation where buoyancy effects arising from elevated surface temperatures are
not important, i.e. when mechanical forces outweigh buoyancy forces. In a geophysical context this requires that some suitably
defined Richardson number is small. From an engineering perspective this is interpreted as the important case when heat transfer
within and above urban street canyons is by forced convection. Surprisingly, this particular scenario (for which the heat
transfer coefficient between buildings and the flow is largest), has been less well studied than the situation where buoyancy
effects are important. The CFD technique was compared against wind-tunnel experiments to provide model evaluation. The height-to-width
ratio of the canyon was varied through the range 0.5–5 and the flow was normal to the canyon axis. By setting the canyon’s
facets to have the same or different temperatures or to have a partial temperature distribution, simulations were carried
out to investigate: (a) the influence of geometry on the flow and mixing within the canyon and (b) the exchange processes
within the canyon and across the canyon top interface. Results showed that the vortex-type circulation and turbulence developed
within the canyon produced a temperature distribution that was, essentially, spatially uniform (apart from a relatively thin
near-wall thermal boundary layer) This allowed the temperatures within the street canyon to be specified by just one value
T
can
, the canyon temperature. The variation of T
can
with wind speed, surface temperatures and geometry was extensively studied. Finally, the exchange velocity u
E
across the interface between the canyon and the flow above was calculated based on a heat flux balance within the canyon
and between the canyon and the flow above. Results showed that u
E
was approximately 1% of a characteristic wind velocity above the street canyon. The problem of radiative exchange is not
addressed but it can, of course, be introduced analytically, or computationally, when necessary. 相似文献