Sulfur Determination in Geological Samples Based on Coupled Analytical Techniques: Electric Furnace-IC and TGA-EGA

A study has been undertaken to determine sulfur in geological samples by coupled analytical techniques. Two measurement methods have been developed: one using an electric furnace coupled to an ion chromatograph (electric furnace-IC) and another using infrared (IR) and quadrupole mass spectrometry (QMS) for evolved gas analysis (EGA) coupled with a thermogravimetric analyser (TGA). In the electric furnace-IC method, measurement was performed without any sample pre-treatment. The measurement conditions were optimised by varying sample quantity, type of catalyst (WO₃, Cu, W and V₂O₅) and sample/catalyst ratio, and the detection limit was 10 μg g⁻¹. Sulfur ores decompose at different temperatures. However, TGA-EGA allowed identification of the different forms of sulfur in the sample, even when they were found in very low concentrations, because the sulfur was continuously analysed. The developed chromatographic method allowed simultaneous analysis of several sample components, such as S, Cl and F, with a low detection limit. The method was much faster and more specific than the methods described in the literature. The results of the sulfur determination had low scatter, possibly because the samples underwent little handling during analysis: the operator only weighed and placed the sample in the furnace, the rest of the measurement process was fully automated. The results obtained by both the developed methods have been validated by using reference materials and comparison with combustion-IR spectroscopy, a standard method for determining total sulfur in a sample.     

海陆边缘沉积磷在全球变化研究中的意义

从磷的生物地球化学循环的角度,讨论了磷与大气圈O2、CO2的关联模式,并通过研究磷的环境地球化学行为,揭示了海陆边缘沉积磷对古气候、古环境变化的记录及其对指示古全球变化的关键性,同时提出了中国东部沿海近代沉积磷的积累与全球变化的耦合作用关系,在中短时间尺度的全球变化研究中所具有的特殊意义。     

大洋热盐环流研究的一个焦点：北太平洋是否有深水形成

现代大洋热盐环流的特点之一是北大西洋有深水形成而北太平洋没有，这种不对称性对周边气候产生了重要影响。尽管理论上认为大洋热盐环流可能存在对应不同气候的多平衡态，但北太平洋是否曾有过深水形成已成为目前学术争论的一个热点。简要介绍了最新的热盐环流研究成果，重点分析现代北太平洋无深水形成的原因，其中亚洲季风的水汽输送和低蒸发是两个重要的影响因子。     

Impact of Boundary-Layer Parameterisation Schemes on the Prediction of the Asian Summer Monsoon

The impact of two boundary-layer parameterisation schemes on the prediction of Indian monsoon systems by a global spectral model has been investigated. The turbulent kinetic energy closure scheme shows a positive impact on the prediction of some important synoptic features, including the genesis of monsoon lows, the tracking of monsoon depressions, and precipitation.     

湖泊水位资料与模型模拟恢复的6000年前全球湿润状况的对比研究

本项研究是ＰＭＩＰ（ＰａｌａｅｏｃｌｉｍａｔｅＭｏｄｅｌｉｎｇＩｎｔｅｒｃｏｍｐａｒｉｓｏｎＰｒｏｊｅｃｔ）国际合作项目中有关模型模拟与观测资料对比的一部分。模型试验对象是６０００ｙｒ．ＢＰ的全球湿润状况。模拟试验以检测太阳辐射变化对全球大尺度气候系统的影响为主要目的。观测资料是利用地质证据恢复的古湖泊水位变化,实际上是某一地区的有效降水（降水减蒸发）的变化。通过两者的比较发现,所有模拟试验均能重现６０００ｙｒ．ＢＰ在亚洲南部与非洲北部的湿润环境,从而证实了因太阳辐射变化导致的亚洲与非洲季风的增强。但模拟的季风增强无论是强度还是范围均小于地质记录。原因很可能是模拟试验中下垫面特征用“现代”的来处理。模拟试验对北半球夏季辐射增加造成的西风带北移及由此引起的中纬度地区的气候变化不够成功。绝大多数模拟对受洋流与海温影响较大的地区是失败的。主要原因可能是所有ＰＭＩＰ中的模拟试验都未考虑海洋的作用。     

全球地面天气报数据集错站情况分析及处理方法的研究

全面分析了全球地面天气报数据集区站号存在的问题、错误区站号的存在对使用资料的影响以及错误区站号产生的原因,提出了解决错误区站号的相应处理方法.同时,对处理后的全球地面天气报数据集区站号的情况和原数据集区站号进行比较分析.     

全球契约与企业应对气候变化

全面分析了气候变化给企业带来的机遇与挑战。全球契约的"关注气候"倡议为企业响应全球号召应对气候变化带来了机遇,全球契约是全球企业共同应对气候变化、实现企业社会责任和树立企业形象的良好平台。另外,通过调查研究分析了中国民营企业应对气候变化的现状,并提出了相关政策建议。     

CMIP5模式对辽宁省气温模拟能力及未来2℃升温阈值出现时间评估

利用全球气候模式、多模式集合和辽宁省气象观测数据,评估了不同典型浓度路径下19个全球气候模式和多模式集合对辽宁省气温变化模拟能力和可信度。结果表明:最优模式模拟结果优于多模式集合,具有较高的可信度。随着全球二氧化碳排放浓度增加,气温变化率和可信度呈增加趋势,首次达到2℃年份呈提前趋势,大部分站点出现在2011年之前,且出现年份越晚,升幅往往越高,反之亦然。大部分站点首次稳定到达2℃阈值开始年份在2022年之前,结束年份出现在2019—2026年,持续时间在13 a以下,开始年份均呈西早—东晚分布形势,结束时间和持续时间分布较均匀,且随着全球二氧化碳排放浓度增加,升温幅度呈上升趋势。不同典型浓度路径下各区域最高温、最低温和平均气温出现年份和变化特征均比较一致。     

基于多源监测数据的雷电预警方法

以浙江省气象台已经业务运行多年的基于雷达数据的雷电预警产品(预警时效为60min,分辨率为1km×1km,4个预警等级)为基础,融合闪电定位系统数据和大气电场数据,提出一种基于多源监测数据的雷电预警方法。使用2018年的观测数据进行预警效果检验,结果表明:雷电预警的漏报率为31.89%,空报率为30.54%,临界成功指数为60.53%,比使用单一监测数据的雷电预警效果有所提高。由此可见,该雷电预警方法对浙江省雷电天气的预警具有参考价值和指示意义。     

Mapping global patterns of land use decision-making

Humans have changed most of the terrestrial surface by changing land-use and land-cover. The spatial distribution and extent of land-cover changes have been studied and mapped widely, using remote sensing and geospatial technologies. Although there are numerous studies on the human decisions underlying such changes, they are limited to local case-studies. How such local-scale patterns of decision-making can be used to explain land-use change globally is unknown. Using a collection of local studies from a literature review, we studied the contextual conditions of different modes of land-use change decision-making and present global maps of the potential distribution of decision-making in land-use change. We find that decision-making in land-use can be explained, to a large extent, by the socio-economic, climatic and soil conditions of a location, captured by global data proxies of these conditions. Survival and livelihood objectives are positively associated to the spatial variation in childhood malnutrition and distance to roads, and negatively to total economic output of an area. Economic objectives on the other hand, are positively associated to total economic output, but also to the annual precipitation at the location. Similar trends are observed when looking at more detailed decision-making types: survivalist, subsistence-oriented and market-oriented smallholder decision-making types are more likely found in areas with higher poverty levels and overall lower levels of socio-economic development. The spatial distribution can be used to understand the occurrence of land-use intensification trajectories and to account for variation in decision-making in global land-use models. Finally, we provide a representation of the spread of case-studies and which contexts are poorly represented by case-studies.