中国数字地质调查系统的基本构架 及其核心技术的实现

数字地质调查系统是贯穿整个地质矿产资源调查全过程的软件,涵盖地质矿产调查、矿产资源勘查、矿体模拟、品住估计、资源量估算、矿山开采系统优化等内容。考虑数字地质调查系统的应用技术层面,从数据“层”模型、数据流“池”技术、不同阶段数据模型继承技术、数据互操作技术等几个方面讨论了核心技术及其实现,通过基于无缝一体化技术的数据采集、管理、综合处理与成果表达,在实体或矿块的矿床建模技术与品住估计、储量估算等方面展现了全地质调查过程的数字化,不但为地质人员应用高新技术降低了门坎,而且极大地提高了研究精度和效率,丰富了成果的表现形式和服务形式。随着数字地质调查系统的完善和应用水平的提高,数字地质调查系统将成为中国地质调查的主流软件体系。     

测井仪器的故障分析与排除思路

TYSC-3Q与PSJ-2型数字测井仪是目前煤田测井中常用的二种测井仪器,在使用过程中难免发生诸如测井控制故障、声速探管故障、密度三侧向探管故障、井温、井液电阻率探管故障、电法面板故障、数字测井面板故障、电测井故障等常见故障类型。通过对各类故障因素进行剖析,指出了故障易发生的部位,并详细的介绍了检查的方法及故障的排除步骤。     

葛店矿双庙扩大区三维地震勘探

葛店煤矿双庙扩大区位于豫、皖两省交界处。勘探区为一轴向北北东向的不对称向斜构造,地层倾角26°～30°,测区深部有岩浆岩侵入体,严重影响煤层赋存形态;地表条件复杂,村庄密集、河流较多,测区东侧塌陷区水塘大面积分布．三维地震勘探野外施工难度大。本区地震勘探观测系统设计为12线18炮制,为避免偏移归位及叠加次数降低等问题,在向斜轴部两侧、村子周边及河岸处适当加密炮点,并在塌陷区利用钢钎插置检波器以保证CDP点完整性。数据处理采取了叠前反褶积、叠前时间偏移等技术,数据处理效果显著。遵循多波组对比、多个数据体综合解释的原则,以纵向、横向和任意时间剖面相结合,充分利用三维可视化技术进行地震资料解释。本次勘探成果查明了主采煤层三2^2、二2煤层的构造形态及埋藏深度;解释落差5m以上断层34条,其中修改原有断层5条;另外新发现小于5m的异常断点22个。经巷道验证煤层底板标高误差0．43％～1．96％,巷道已揭露断层7条,与解释成果基本一致。     

初至层析静校正在复杂山地三维地震勘探中的应用

随着地形高差增大、地貌单元多变、近地表模型复杂,目前被广泛应用的初至折射静校正的精度已无法满足精细勘探的要求。初至层析静校正技术,由给定的初始模型进行正演,用射线追踪方法得到初始模型的初至波,利用该初至波和实际拾取的初至波进行比较,计算地表模型的修正量,反复迭代求得准确的地表模型。山西省国阳新能股份有限公司二矿390水平九采扩区地表标高940～1100m,地貌单元复杂,在对该区资料处理时,利用初至层析折射静校正,经9次迭代计算后,真实地刻划出近地表模型。在二种静校正技术对比中,初至折射静校正不但近地表模型精度低于层析折射静校正,而且其叠加剖面精细程度也远低于层析静校正,如在初至折射静校正叠加剖面同相轴上呈现的凹凸形态,在层析静校正叠加剖面并无显示,且后者剖面的信噪比也比前者明显提高。     

努力提高三维地震勘探精度，为西部煤炭工业做出新贡献

以国家重大产业技术开发专项“西部煤炭资源高精度三维地震勘探技术”项目的由来、意义和总体研究目标为引,概括的介绍了项目依托工程中各个专项技术研究完成情况,并对非均匀介质成像技术、高精度三维地震静校正技术、高密度采集技术、特观技术、岩性反演技术、属性体解释技术等六项重大关键技术取得的突破性进展进行了重点说明。指出随着我国煤炭生产重点的逐步西移,应加强诸如叠前、叠后深度偏移技术的研究,以解决复杂山区三维地震面元内地震反射波散射问题,提高其三维地震勘探精度,为西部煤炭工业做出新贡献!     

三维地震小面元采集技术在晋城矿区的应用

依托“西部煤炭资源高精度三维地震勘探技术”工程,对晋城矿区进行了旨在提高小断层,小陷落柱探测能力的高密度三维地震勘探。根据面元选择因素及该区地质任务,采用5m×5m网格进行野外数据采集;考虑炮检距、方位角、覆盖次数、排列片横纵比及煤层埋深（350～500m）等因素,采用中点放炮、60道接收,24次覆盖（横向4次,纵向6次）的8线16炮束状观测系统,基岩中激发。原始资料经同一处理流程后,获得5m×5m×1ms、5m×10m×1ms、10m×10m×1ms及2.5m×2.5m×1ms不同单元的三维数据体多个,通过对比可以发现小断层,小陷落柱在其小面元叠加时间剖面、顺层切片及相干切片都有清晰的反映。实例说明,小面元采集技术可以提高对小构造的纵、横向分辨能力,满足山区对三维地震精确勘探的要求。     

小面元三维地震勘探技术在西山屯兰矿南五采区的应用

屯兰矿南五采区地形复杂,最大高差达271m,地表大面积为第四系黄土覆盖,激发困难。为探索研究小面元三维地震勘探技术的应用效果。在常规三维地震勘区域内划出1km^2,采用5m×5m小面元进行采集。在地震数据采集过程中,采取了加大激发井深、提高覆盖次数、减小CMP面元网格和加大接收排列等技术措施,做到“四小三高、二中一深、两个等高面”。通过插值、抽线及扩大面元处理。获得2．5m×2．5m×1ms、5m×5m×1ms、5m×10m×1ms、10m×10m×1ms以及不同叠加次数的三维数据体。资料解释工作主要是在5m×5m×1ms、2．5m×2．5m×1ms两个数据体上进行,解释落差大于或等于5m的断层6条,落差3～5m的断层8条;查明长轴直径20～30m的陷落柱4个。30～100m的陷落柱1个,大于100m的陷落柱3个。与相邻区常规三维地震比较,小面元三维地震勘探有利于对小陷落柱、小断层的控制和解释。     

Rate constants for the reactions of the NO3 radical with HCOOH/HCOO− and CH3COOH/CH3COO− in aqueous solution between 278 and 328 K

The kinetics of the aqueous phase reactions of NO₃ radicals with HCOOH/HCOO^– and CH₃COOH/CH₃COO^– have been investigated using a laser photolysis/long-path laser absorption technique. NO₃ was produced via excimer laser photolysis of peroxodisulfate anions (S₂O ₈ ^2– ) at 351 nm followed by the reactions of sulfate radicals (SO ₄ ^– ) with excess nitrate. The time-resolved detection of NO₃ was achieved by long-path laser absorption at 632.8 nm. For the reactions of NO₃ with formic acid (1) and formate (2) rate coefficients ofk ₁=(3.3±1.0)×10⁵ l mol^–1 s^–1 andk ₂=(5.0±0.4)×10⁷ l mol^–1 s^–1 were found atT=298 K andI=0.19 mol/l. The following Arrhenius expressions were derived:k ₁(T)=(3.4±0.3)×10¹⁰ exp[–(3400±600)/T] l mol^–1 s^–1 andk ₂(T)=(8.2±0.8)×10¹⁰ exp[–(2200±700)/T] l mol^–1 s^–1. The rate coefficients for the reactions of NO₃ with acetic acid (3) and acetate (4) atT=298 K andI=0.19 mol/l were determined as:k ₃=(1.3±0.3)×10⁴ l mol^–1 s^–1 andk ₄=(2.3±0.4)×10⁶ l mol^–1 s^–1. The temperature dependences for these reactions are described by:k ₃(T)=(4.9±0.5)×10⁹ exp[–(3800±700)/T] l mol^–1 s^–1 andk ₄(T)=(1.0±0.2)×10¹² exp[–(3800±1200)/T] l mol^–1 s^–1. The differences in reactivity of the anions HCOO^– and CH₃COO^– compared to their corresponding acids HCOOH and CH₃COOH are explained by the higher reactivity of NO₃ in charge transfer processes compared to H atom abstraction. From a comparison of NO₃ reactions with various droplets constituents it is concluded that the reaction of NO₃ with HCOO^– may present a dominant loss reaction of NO₃ in atmospheric droplets.     

LonGSp: A near infra-red spectrometer

We present a new cooled grating near infra-red spectrometer designed to acquire spectra at the TIRGO telescope in the 0.9÷2.5m region with a resolving power of 300÷4000, equipped with a Rockwell NICMOS 3 detector.     

Latitudinal variation of measured O3 photolysis frequencies J(O1D) and primary OH production rates over the Atlantic Ocean between 50° N and 30° S

The latitudinal variation of the photolysis frequency of ozone to O(¹D) atoms, J(O¹D), was measured using a filter radiometer during the cruise ANT VII/1 of the research vessel Polarstern in September/October 1988. The J(O¹D) noon values exhibited a maximum of 3.6×10^-5 s^-1 (2 sr) at the equator and decreased strongly towards higher latitudes. J(O¹D) reached highest values for clean marine background air with low aerosol load and almost cloudless sky. The J(O¹D) data, measured under these conditions and a temperature of 295 K, can be expressed by: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOsaiaacI% cacaqGpbWaaWbaaSqabeaaiiaacqWF8baFaaGccaqGebGaaeykaiaa% bccacqWF9aqpcaqGGaGaaeyzaiaabIhacaqGWbGaaeiiaiaabUhacq% GHsislcaaI4aGaaiOlaiaaicdacaaIYaGaeyOeI0IaaGioaiaac6ca% caaI4aGaaiiEaiaaigdacaaIWaWaaWbaaSqabeaacqGHsislcaaIZa% aaaOGaaeiiaiaabIhacaqGGaGaam4uaiabgUcaRiaaiodacaGGUaGa% aGinaiaacIhacaaIXaGaaGimamaaCaaaleqabaGaeyOeI0IaaGOnaa% aakiaadofadaahaaWcbeqaaiaaikdaaaGccaGG9bGaaeikaiaaboha% daahaaWcbeqaaiabgkHiTiaaigdaaaGccaGGPaaaaa!5EE9!\[J({\text{O}}^| {\text{D) }} = {\text{ exp \{ }} - 8.02 - 8.8x10^{ - 3} {\text{ x }}S + 3.4x10^{ - 6} S^2 \} {\text{(s}}^{ - 1} )\] where S represents the product of the overhead ozone column (DU) and the secant of the solar zenith angle. The meridional profile of the primary OH radical production rate P(OH) was calculated from the J(O¹D) measurements and simultaneously recorded O₃ and H₂O mixing ratios. While the latitudinal distribution of J(O¹D) and water vapour was nearly symmetric to the equator, high tropospheric ozone levels up to 40 ppb were observed in the Southern Hemisphere, SH, resulting in higher P(OH) in the SH.