Chemical Profiles across a Jurassic Stratiform Manganese Deposit at Katsuyama in the Mino Terrane of Central Japan: Implications for Depositional Environment, Diagenetic Metal Redistribution and Paleoceanography

Abstract. Inorganic chemical compositions are determined for a series of rocks crossing an Early Jurassic stratiform manganese ore deposit in a chert‐dominant sequence at Katsuyama, in the Mino Terrane of central Japan. The lithology in the vicinity of the manganese ore bed is classified into lower bedded chert, black shale, massive chert, manganese ore and upper bedded chert, in ascending order. The rocks surrounding the manganese deposit are anomalously high in certain elements: Pb (max. 29 ppm), Ni (1140) and Co (336) in the lower bedded chert, Mo (438), As (149), Tl (29) and U (12) in the black shales, V (210) and Cr (87) in the massive chert, and MnO and W (24) in the manganese ore. The aluminum‐normalized profiles reveal a distinct zonation of redox‐sensitive elements: Pb‐Zn, Ni‐Co‐Cu(‐Zn) and U‐Cr in the lower bedded chert, Mo‐As‐Tl in the black shale, V(‐Cr) in the massive chert, and Mn‐Fe‐Ba‐W in the manganese ore, in ascending order. The lower and upper bedded cherts and manganese ore generally exhibit flat rare earth element patterns with positive Ce anomalies, whereas the uppermost part of the lower bedded chert, the black shale and massive chert have flat patterns with weak or nonexistent negative Ce anomalies and weak positive Eu anomalies. The strong enrichment in Ni, Co, W, Tl and As detected in the Katsuyama section is not recognized in other sediments, including those of anoxic deposition origin, but is identified in modern ferromanganese nodules, suggesting that metal enrichment in the Katsuyama section is essentially due to the formation of ferromanganese nodules rather than to deposition in an anoxic environment. The observed elemental zonation is well explained by equilibrium calculations, reflecting early diagenetic formation and associated gradual reduction with depth. The concentration profiles in combination with litho‐ and biostratigraphical features suggest that formation of these bedded manganese deposits was triggered by an influx of warm, saline and oxic water into a stagnant deep ocean floor basin in Panthalassa at the end of the middle Early Jurassic. Paleoceanographic environmental controls thus appear to be important factors in the formation and preservation of this type of stratiform manganese deposit.     

Exhumation Paths of High-Pressure-Low-Temperature Metamorphic Rocks from the Lycian Nappes and the Menderes Massif (SW Turkey): a Multi-Equilibrium Approach

The Menderes Massif and the overlying Lycian Nappes occupy anextensive area of SW Turkey where high-pressure–low-temperaturemetamorphic rocks occur. Precise retrograde P–T pathsreflecting the tectonic mechanisms responsible for the exhumationof these high-pressure–low-temperature rocks can be constrainedwith multi-equilibrium P–T estimates relying on localequilibria. Whereas a simple isothermal decompression is documentedfor the exhumation of high-pressure parageneses from the southernMenderes Massif, various P–T paths are observed in theoverlying Karaova Formation of the Lycian Nappes. In the uppermostlevels of this unit, far from the contact with the MenderesMassif, all P–T estimates depict cooling decompressionpaths. These high-pressure cooling paths are associated withtop-to-the-NNE movements related to the Akçakaya shearzone, located at the top of the Karaova Formation. This zoneof strain localization is a local intra-nappe contact that wasactive in the early stages of exhumation of the high-pressurerocks. In contrast, at the base of the Karaova Formation, alongthe contact with the Menderes Massif, P–T calculationsshow decompressional heating exhumation paths. These paths areassociated with severe deformation characterized by top-to-the-eastshearing related to a major shear zone (the Gerit shear zone)that reflects late exhumation of high-pressure parageneses underwarmer conditions. KEY WORDS: exhumation; high-pressure–low-temperature metamorphism; multi-equilibrium P–T estimates; Lycian Nappes; Menderes Massif     

Critical rainfall statistics for predicting watershed flood responses: rethinking the design storm concept

Recent advances have been made to modernize estimates of probable precipitation scenarios; however, researchers and engineers often continue to assume that rainfall events can be described by a small set of event statistics, typically average intensity and event duration. Given the easy availability of precipitation data and advances in desk‐top computational tools, we suggest that it is time to rethink the ‘design storm’ concept. Design storms should include more holistic characteristics of flood‐inducing rain events, which, in addition to describing specific hydrologic responses, may also be watershed or regionally specific. We present a sensitivity analysis of nine precipitation event statistics from observed precipitation events within a 60‐year record for Tompkins County, NY, USA. We perform a two‐sample Kolmogorov–Smirnov (KS) test to objectively identify precipitation event statistics of importance for two related hydrologic responses: (1) peak outflow from the Six Mile Creek watershed and (2) peak depth within the reservoir behind the Six Mile Creek Dam. We identify the total precipitation depth, peak hourly intensity, average intensity, event duration, interevent duration, and several statistics defining the temporal distribution of precipitation events to be important rainfall statistics to consider for predicting the watershed flood responses. We found that the two hydrologic responses had different sets of statistically significant parameters. We demonstrate through a stochastic precipitation generation analysis the effects of starting from a constrained parameter set (intensity and duration) when predicting hydrologic responses as opposed to utilizing an expanded suite of rainfall statistics. In particular, we note that the reduced precipitation parameter set may underestimate the probability of high stream flows and therefore underestimate flood hazard. Copyright © 2016 John Wiley & Sons, Ltd.     

Fingerprinting the 8.2 ka event climate response in a coupled climate model

Using results from coupled climate model simulations of the 8.2 ka climate event that produced a cold period over Greenland in agreement with the reconstructed cooling from ice cores, we investigate the typical pattern of climate anomalies (fingerprint) to provide a framework for the interpretation of global proxy data for the 8.2 ka climate event. For this purpose we developed an analysis method that isolates the forced temperature response and provides information on spatial variations in magnitude, timing and duration that characterise the detectable climate event in proxy archives. Our analysis shows that delays in the temperature response to the freshwater forcing are present, mostly in the order of decades (30 a over central Greenland). The North Atlantic Ocean initially cools in response to the freshwater perturbation, followed in certain parts by a warm response. This delay, occurring more than 200 a after the freshwater pulse, hints at an overshoot in the recovery from the freshwater perturbation. The South Atlantic and the Southern Ocean show a warm response reflecting the bipolar seesaw effect. The duration of the simulated event varies for different areas, and the highest probability of recording the event in proxy archives is in the North Atlantic Ocean area north of 40° N. Our results may facilitate the interpretation of proxy archives recording the 8.2 ka event, as they show that timing and duration cannot be assumed to correspond with the timing and duration of the event as recorded in Greenland ice cores. Copyright © 2011 John Wiley & Sons, Ltd.     

Severe soil erosion during a 3‐day exceptional rainfall event: combining modelling and field data for a fallow cereal field

Exceptional rainfall events cause significant losses of soil, although few studies have addressed the validation of model predictions at field scale during severe erosive episodes. In this study, we evaluate the predictive ability of the enhanced Soil Erosion and Redistribution Tool (SERT‐2014) model for mapping and quantifying soil erosion during the exceptional rainfall event (~235 mm) that affected the Central Spanish Pyrenees in October 2012. The capacity of the simulation model is evaluated in a fallow cereal field (1.9 ha) at a high spatial scale (1 × 1 m). Validation was performed with field‐quantified rates of soil loss in the rills and ephemeral gullies and also with a detailed map of soil redistribution. The SERT‐2014 model was run for the six rainfall sub‐events that made up the exceptional event, simulating the different hydrological responses of soils with maximum runoff depths ranging between 40 and 1017 mm. Predicted average and maximum soil erosion was 11 and 117 Mg ha^?1 event^?1, respectively. Total soil loss and sediment yield to the La Reina gully amounted to 16.3 and 9.0 Mg event^?1. These rates are in agreement with field estimations of soil loss of 20.0 Mg event^?1. Most soil loss (86%) occurred during the first sub‐event. Although soil accumulation was overestimated in the first sub‐event because of the large amount of detached soil, the enhanced SERT‐2014 model successfully predicted the different spatial patterns and values of soil redistribution for each sub‐event. Further research should focus on stream transport capacity. Copyright © 2014 John Wiley & Sons, Ltd.     

Stormflow concentration–discharge dynamics of suspended sediment and dissolved phosphorus in an agricultural watershed

Concentration–discharge (C-Q) relationships are an effective tool for identifying watershed biogeochemical source and transport dynamics over short and long timescales. We examined stormflow C-Q, hysteresis, and flushing patterns of total suspended sediment (TSS) and soluble reactive phosphorus (SRP) in two stream reaches of a severely impaired agricultural watershed in northeastern Wisconsin, USA. The upper watershed reach—draining a relatively flat, row crop-dominated contributing area—showed predominantly anti-clockwise TSS hysteresis during storms, suggesting that particulate materials were mobilized more from distal upland sources than near- and in-channel areas. In contrast, the incised lower watershed reach produced strong TSS flushing responses on the rising limb of storm hydrographs and clockwise hysteresis, signalling rapid mobilization of near- and in-channel materials with increasing event flows. C-Q relationships for SRP showed complex patterns in both the upper and lower reaches, demonstrating largely non-linear chemodynamic C-Q behaviour during events. As with TSS, anti-clockwise SRP hysteresis in the upper reach suggested a delay in the hydrologic connectivity between SRP sources and the stream, with highly variable SRP concentrations during some events. A broad range of clockwise, anti-clockwise, and complex SRP hysteresis patterns occurred in the lower watershed, possibly influenced by in-channel legacy P stores and connection to tile drainage networks in the lower watershed area. Total suspended sediment and SRP responses were also strongly related to precipitation event characteristics including antecedent precipitation, recovery period, and precipitation intensity, highlighting the complexity of stormflow sediment and phosphorus responses in this severely impaired agricultural stream.     

The Upstream “Strong Signals” of the Water Vapor Transport over the Tibetan Plateau during a Heavy Rainfall Event in the Yangtze River Basin

A heavy rainfall event that occurred over the middle and lower reaches of the Yangtze River Basin(YRB) during July11–13 2000 is explored in this study. The potential/stream function is used to analyze the upstream "strong signals" of the water vapor transport in the Tibetan Plateau(TP). The studied time period covers from 2000 LST 5 July to 2000 LST 15 July(temporal resolution: 6 hours). By analyzing the three-dimensional structure of the water vapor flux, vorticity and divergence prior to and during the heavy rainfall event, the upstream "strong signals" related to this heavy rainfall event are revealed. A strong correlation exists between the heavy rainfall event in the YRB and the convective clouds over the TP. The "convergence zone" of the water vapor transport is also identified, based on correlation analysis of the water vapor flux two days and one day prior to, and on the day of, the heavy rainfall. And this "convergence zone" coincides with the migration of the maximum rainfall over the YRB. This specific coupled structure actually plays a key role in generating heavy rainfall over the YRB. The eastward movement of the coupled system with a divergence/convergence center of the potential function at the upper/lower level resembles the spatiotemporal evolution of the heavy rainfall event over the YRB. These upstream "strong signals" are clearly traced in this study through analyzing the three-dimensional structure of the potential/stream function of upstream water vapor transport.     

5—6月东北冷涡持续活动及强度特征

利用1960—2012年5—6月NCEP/NCAR逐日再分析资料,基于冷涡经典定义,采取客观识别方法检索东北冷涡活动过程,根据东北冷涡活动时空变化特征给出东北冷涡持续活动过程标准, 通过冷涡强度指数进行定量化分析,该指数对冷涡持续活动过程具有较好表征意义。冷涡活动强对应5月乌拉尔山阻塞高压、贝加尔湖阻塞高压和6月鄂霍次克海阻塞高压活动频繁。通过强弱指数年合成,得到6月强指数年冷涡系统较深厚,集中于对流层中高层,冷心结构明显,具有一定大气斜压特征; 高层存在冷中心,低层有冷空气活动,中高层西风带呈明显的上游分流和下游汇合特征,分汇流之间呈东北高、西南低的偶极子阻塞形势;弱指数年冷涡系统较浅薄,主要集中在对流层中低层,冷心结构不明显,不存在阻塞形势。     

1999年北京持续高温天气过程的诊断分析

利用北京观象台观测资料和NCEP/NCAR再分析数据,对1999年6月24日至7月2日北京一次持续性高温天气的演变和发展过程及非绝热加热作用对系统的影响进行诊断分析,结果表明：在此次高温天气发生前,欧亚大陆中高纬度环流经向度很大,欧洲北部和贝加尔湖以南为高压脊控制,中亚和我国东北地区则处于低压槽内。贝加尔湖南部的高压脊纬向延伸范围较广,在东移过程中长时间影响北京。随着贝加尔湖以南的高压脊逐渐东移,北京上空下沉增温与非绝热加热作用有所增强,北京逐渐受到高温天气影响。在高温天气发生的后半阶段,我国东北的低压槽入海后在120130°E附近维持并发展,槽前非绝热加热率很大。从垂直方向来看,加热率在500 hPa以下随高度迅速增加,根据全型涡度方程,强烈的非绝热加热率垂直分布不均作为一个明显的涡度源区,对入海低压槽的稳定维持有显著的作用。而入海低压槽的稳定维持,又阻碍了华北高压脊的东移,使其在北京地区长时间稳定少动,为北京带来多日的持续性高温天气。