南平市公路运输危险化学品污染事件的研究

对2004-2007年在福建省南平市行政区域内发生的公路运输危险品污染事件进行统计分析,研究结果表明：南平市4年间共发生26起公路运输危险化学品事故,每年平均6．5起．其中夜间发生事故的比率为57．7％,夏季发生事故的比率为34．6％,35～45岁驾驶员年龄段事故发生率高达59．1％,驾龄在11～15年的为事故多发驾龄段,其发生率为45．5％,发生在弯道的事故占61．5％,超载发生事故的可能性为44．0％,占总数65．4％的事故对环境产生污染．205国道南平段发生危险化学品运输事故的概率为0．0124次／（a·km）,发生危险化学品泄漏事件的可能性为0．0142次／（a·km）,发生危险化学品1t以上大规模连续泄漏事件的概率为0．0098次／（a·km）．     

Deriving hillslope sediment budgets in wildfire-affected forests using fallout radionuclide tracers

Information on post-fire sediment and nutrient redistribution is required to underpin post-fire catchment management decisions. Fallout radionuclide budgets (²¹⁰Pb_xs, ¹³⁷Cs and ⁷Be) were derived to quantify soil redistribution and sediment yield in forested terrain following a moderately severe wildfire in a small (89 ha) water supply catchment in SE Australia. Application of these techniques in burnt terrain requires careful consideration of the partitioning of radionuclides between organic and mineral soil components. Beryllium-7 and ²¹⁰Pb_xs were shown to be closely associated with ash, litter and soil organic matter whereas ¹³⁷Cs was more closely associated with subsurface coarse mineral soil. Comparison of the three tracer budgets indicated that the dominant sediment source areas were ridgetops and steep valley sideslopes, from which burnt surface material was conveyed to the stream network via pre-existing gullies. Erosion was predominantly driven by sheetwash, enhanced by soil water repellency, and modified by bioturbation which both supplies subsurface sediment and provides sinks for erosive overland flow. Footslope and riparian zones were not important sediment source areas. The estimated event-based (wildfire and subsequent rainfall) sediment yield is 58 ± 25 t km^− 2, based on fallout ⁷Be measurements. The upper estimate of total particulate phosphorus yield (0.70 kg ha^− 1) is more than 10 times that at equivalent unburnt sites. This illustrates that, soon after fire, burnt eucalypt forest can produce nutrient loads similar to those of agricultural catchments. The tracer budgets indicate that wildfire is an important control on sediment and phosphorus inputs to the stream network over the decadal timeframe and the pulsed nature of this release is an important concern for water quality management.     

湖泊自生碳酸盐碳同位素在环境变化中的应用

湖泊自生碳酸盐碳同位素组成(δ13Cc)在区域气候与环境变化方面的应用研究近年来进展迅速,成果显著,保存在各类湖泊沉积物柱芯中的δ13Cc记录揭示了湖表水体与大气CO2的交换程度、暖季降水量的多少、流域C3和C4植被变化情况、水生生物光合作用或呼吸作用强弱、湖泊生产力大小、湖泊水体化学特征、湖水不同深度层的有机质变化过程等重要的气候和环境信息;对此进行归纳和述评。     

The Kwinana Coastal Fumigation Study: III – Meteorological and Turbulence Modelling on Selected Days

The Kwinana Coastal Fumigation Study took place inearly 1995 at Kwinana near Perth in Western Australia.The study involved surface and elevated meteorologicaland plume fumigation measurements in sea-breeze flowsnear the coast, and has yielded a comprehensive dataset that is suitable for assessing meteorological andplume dispersion models. In this paper, wesimulate the meteorology and turbulence on four casestudy days, and compare model results with thedetailed surface and aircraft measurements takenduring the study. These days had surface synopticwinds ranging from southerly to northeasterly, witheither stable or near-neutral temperature profilesover the sea.The model used was based on that developed by Hurley(Boundary-Layer Meteorol. 83, 43–73, 1997), but extended here to allow domain nesting,optional non-hydrostatic simulations, and a vegetativecanopy at the surface. The model was forced bystandard weather service synoptic data, and thesimulations have captured the essential features ofthe strong sea-breeze circulation observed on thesedays. The boundary-layer structure over the sea waspredicted to be near-neutral or stable in agreementwith the observations on the particular day. The windspeed and direction in the sea-breeze flow weregenerally predicted well, although the predictedmaximum inflow speed over the land was a little toohigh. The potential temperature was generallyover-predicted, but temperature gradients agreed well.Predicted turbulence levels in the bottom-half of thethermal internal boundary layer compared well to theobservations, but under-estimated the observations inthe in the upper half of this layer. Near-surfacemeasurements of meteorological variables werepredicted well over the entire diurnal cycle, althoughthe predicted sea-breeze onset was generally tooearly. A quantitative model evaluation for thenear-surface sites showed the model performance to bebetter than that from other studies, with Index ofAgreement (IOA) values of 0.8 (wind speed) and 0.96(temperature), compared with values of 0.5–0.6 (windspeed) and 0.33 (temperature) obtained from otherstudies.The availability of new higher resolution synopticanalyses should obviate the lack of spatial andtemporal resolution in synoptic inputs. Theincorporation of these higher resolution synopticinputs and new parameterisation schemes should improvefuture model performance.     

哈拉湖岩芯XRF扫描元素统计分析及其环境意义

青藏高原东北缘高山湖泊哈拉湖是位于季风与西风影响的交汇带的封闭深水湖泊,是区域环境和气候变化的良好记录载体。目前对该湖的研究还较少,缺乏对沉积物中元素环境意义的系统认识。通过高分辨率XRF岩芯扫描,用相关、聚类和因子分析的方法对哈拉湖沉积岩芯地球化学元素进行分析。结果显示Ti、K、Si、Al、Fe、Mn等元素变化一致,相关性高,归为同一类,即径流输入的陆源碎屑组分,反映了流域水文状况如径流量的变化。Sr、Zr元素相关性高,为赋存在粗颗粒沉积物中的元素,根据哈拉湖实际,应为冬季湖泊冰面风力搬运,反映了湖区冬季风力强度的变化。Ca元素既与径流输入元素总体变化一致,也与Sr、Zr元素显著相关,且在第一和第二主成分(径流和风力)上的载荷相当,表明哈拉湖沉积物中的碳酸盐既有粗颗粒的外源碎屑,也有湖泊自生的组分,这在利用碳酸盐进行地球化学研究时应重视,注意去除外源碎屑碳酸盐的影响。可溶元素S和Cl可能反映了入湖水量与蒸发对比情况,与湖泊盐度有关。     

国家湿地公园旅游环境容量问题与调控——以杭州西溪湿地为例

国家湿地公园的旅游环境容量问题多来源于园区内部属性和游客行为之间的差异,国家湿地公园面积大、生态系统独特,园区空间布局、管理制度、主题商品与设施建设、服务方面的不合理、不完善导致了局部时段性的超载现象,宜采取以游客行为为导向的容量调控模式(TBCC),从加强园区自身建设和管理入手调控游客空间流动,从内部提升视角解决容量超载问题,实现游客体验、环境保护、科普教育等多功能为一体的湿地公园建设目标。     

上海旱地农田氮磷随地表径流流失研究

选择上海宝山罗店镇具有代表性的旱地蔬菜农田生态系统，从2004年3月到8月的近半年时间里，通过对径流及径流中侵蚀泥沙的氮磷流失情况的连续监测，研究了旱地农田施肥与氮磷流失污染之间的关系，探讨了农田氮磷的迁移特征及环境效应，主要结果表明：当季施用化肥的地表径流总流失量，总氮为32．77kg/hm^2，总磷为8．1kg／hm^2，随径流排出农田的氮素中有37．7％是当季施用的氮素化肥，磷素中有26．9％是当季施用的磷素化肥；从过量施肥与环境污染之间的“因”与“果”来看，减量15％施肥区相比常规施肥区的茄子的产量减少2．7％，但是其污染负荷却减少了13．4％，表明在化肥利用的有效性上或增施化肥与控制环境污染之间，应该寻找一个最佳的平衡点。     

环境库兹涅茨曲线在文山县城的应用

环境库兹涅茨曲线认为随着经济发展，环境质量先下降后改善，环境质量与收入之间表现为倒U形曲线，这意味着经济发展最终会解决环境问题。应用这一思想，根据1991～2000年文山县城区大气污染指数及1998～2002年盘龙河水污染物浓度与同期人均居民收入进行了回归分析，发现对多数污染物而言，表现为N形的高次曲线能很好的拟合两者之间的关系，据此提出一种简单但普遍的机理来解释EKC曲线，即经济发展对环境质量的正负反馈作用决定其在涨落中演变。     

武汉市科教区冬春季气溶胶的元素组成特征及来源分析

2006-2007年冬春季在武汉市湖北大学校区连续采集气溶胶样品,测定气溶胶元素组成,分析气溶胶样品总悬浮颗粒物（TSP）质量浓度,再结合污染源的特征元素组成来确定污染物的来源构成。结果表明：湖北大学校区大气气溶胶污染程度较轻,气溶胶元素以地壳元素为主,其次是具有代表性的人为污染物元素,再次是盐类元素。通过因子载荷分析和相关性分析显示,湖北大学周边地区的建筑源、交通源和餐饮源是湖北大学校区大气的主要污染源。