分光光度法测定水系沉积物中硼

本文介绍了分光光度法测定硼的分析方法,盐酸介质中,硼与甲亚胺-H生成可溶性黄色络合物,用饱和Ba CO3溶液沉淀去除其干扰,于420.0 nm进行比色。方法的检出限为29μg/g,结果满足国家标准物质和实际样品分析测试要求,达到了国家标准。     

Parallel finite element algorithm with domain decomposition for three-dimensional magnetotelluric modelling

We present a new finite element (FE) method for magnetotelluric modelling of three-dimensional conductivity structures. Maxwell's equations are treated as a system of first-order partial differential equations for the secondary fields. Absorbing boundary conditions are introduced, minimizing undesired boundary effects and allowing the use of small computational domains. The numerical algorithm presented here is an iterative, domain decomposition procedure employing a nonconforming FE space. It does not use global matrices, therefore allowing the modellization of large and complicated structures. The algorithm is naturally parallellizable, and we show results obtained in the IBM SP2 parallel supercomputer at Purdue University. The accuracy of the numerical method is verified by checking the computed solutions with the results of COMMEMI, the international project on the comparison of modelling methods for electromagnetic induction.     

Effects of Interference and Oxidation on the UV/Visible Rejection Properties of Filters for Soft X-ray Detectors

We report on UV/Visible transmission measurements of aluminum coated Lexan filters designed as UV blocking filters for soft x-ray detectors. Transmission of the filters in the 2300-8000 Å wavelength range is significantly higher than expected. It cannot be accounted for applying a simple slab model of the transmission and adopting material properties reported in the literature. We show that this is due to interference effects which are strongly dependent on the filter geometry, and to oxidation of exposed aluminum surfaces and/or chemical interaction with the plastic support. The results of this work have led to the redesign of the Advanced X-ray Astrophysics Facility High Resolution Camera UV blocking filters.     

用线性规划法求解瞬变电磁场反射系数

讨论了在水平层状介质中的反射系数的物理意义 ,推出时间域含有以反射系数序列为未知项的欠定方程组 ,提出用线性规划法求解瞬变电磁场反射系数序列 ,并给出求解思路和程序框图。对两个理论模型进行了处理 ,计算出了其反射系数。算例分析结果表明 ,算法可靠 ,程序可行。这一方法可用于瞬变电磁成像数值计算中。     

乾陵地震台钻孔体应变观测资料分析

选取乾陵地震台2018—2020年钻孔体应变观测资料,进行完整性、年零漂和观测资料精度分析,通过采样调和分析,评价观测数据质量,并对自然环境变化、仪器系统故障和人为干扰对观测数据的影响进行分析,探讨该台钻孔体应变观测映震能力,认为： ①乾陵地震台体应变测项运行良好,观测数据质量较高; ②降雨、气压是影响体应变观测数据的主要干扰因素; ③体应变对全球7级以上、中国6级以上地震同震响应较明显,震级越大,同震响应持续时间越长。     

E5000型全谱直读型电弧发射光谱仪研制及其在地球化学样品分析中应用

在地球化学样品检测工作中,Ag、B、Sn等难分析元素通常采用传统的交流电弧发射光谱法(摄谱仪),随着地球化学样品数量的增加以及对检测结果质量要求的提高,该方法操作复杂、分析过程繁琐的问题与日常大量样品分析的矛盾日益突出,多道式电弧直读发射光谱也开始在行业内应用。本文基于先进的数字光源技术和CCD全谱型光谱仪技术,改进了电弧发生系统、分光系统和检测系统,将电弧激发光源与Paschen-Runge型全谱CCD光谱仪结合,研制了一款新型的台式全谱直读型电弧发射光谱仪E5000。E5000型电弧发射光谱仪通过激光定位结合程控电极技术,自动调整电极位置,提高了采谱过程的精度控制;利用CCD全谱技术获得了激发样品的全谱信息,可轻易实现光谱信号的背景扣除和干扰校正;且无需再次测定黑度,直接获得分析结果;同时结合内标法和标准加入法,可以进一步提高复杂基体样品的分析精准度。应用研制的光谱仪对水系沉积物和土壤样品进行检测,Ag、B、Sn元素的检出限分别达到了0.01μg/g、0.65μg/g、0.16μg/g,在分析水系沉积物、土壤时检测精密度基本小于10%,优于当前的摄谱法和多道电弧直读光谱法,满足了地球化学样品检测质量要求。     

φ71 mm绳索取心铝合金钻杆的研制

介绍了国内外铝合金钻杆的研制现状,分析了绳索取心铝合金钻杆在地质钻探中的优势。对φ71 mm×5.5 mm绳索取心铝合金钻杆体与钢接头连接结构进行了详细设计。通过对试验钻杆进行静拉力、扭矩试验,得出了铝合金钻杆体与钢接头主要技术参数。     

盒子波调查技术在六盘山黄土塬区的应用分析

六盘山盆地被巨厚的黄土所覆盖,是表层和深层双复杂区域。巨厚的黄土和复杂的地形条件使该区干扰波非常发育,严重影响了地震资料的信噪比。为了有效调查该区干扰波发育特征,并进行针对性地压制,通过盒子波调查技术在该区的应用分析,提出了和生产结合进行盒子波调查的有效方式,克服了静校正问题对盒子波调查数据的影响。针对两种地形条件下的盒子波资料,分析了在不同地形和表层条件下干扰波场的变化,认为影响浅层和中深层信噪比的干扰波特征存在差异;并通过组合压噪效果分析,提出对不同深度勘探目标进行针对性压噪的组合接收方式,提高了六盘山地区巨厚黄土塬勘探区目标层采集资料的信噪比。     

ALOS PALSAR全极化图像分类研究

极化干涉相干矩阵服从复Wishart分布,通过对相关系数的分析可以获得不同的地物类别。在总结极化干涉非监督Wishart ML分类流程的基础上,基于该方法对塔河地区全极化PALSAR数据进行了分类,研究结果表明:基于极化干涉的分类方法能够有效区分不同散射机制对应的地物,该分类方法具有较强的适应性,并且类间边界比较明显,这些分类信息为森林资源的开发和利用提供了参考。     

Ground-based electromagnetic studies combined with remote sensing based on Demeter mission: A way to monitor active faults and volcanoes

The identification of magnetic, electric and electromagnetic (EM) precursory signals related to volcanic activities and earthquakes is still a matter of debate. Some examples are now well established, but they are often based on a few parameters recorded on sparse equipments and with no multi-disciplinary approach. Demeter program takes into account a more complete approach of EM phenomena related to volcanic eruptions and earthquakes, by combining both ground-based and satellite EM monitoring, from direct current to several kilohertz, i.e. from ULF, ELF to VLF frequency domains.The research program stands in two parts: one is the identification of EM signals at the satellite altitude and the other consists in detailed studies in a few pilot sites on the ground. Two main test sites have been considered: La Fournaise volcano in Réunion Island and the seismogenic Corinth rift in Greece. Both sites allow for performing EM studies in a multi-disciplinary environment.La Fournaise volcano erupts on average two times a year. The self-recording Demeter EM station is composed of three modules measuring the components of the magnetic and electric fields in three different frequency domains: DC to 0.5 Hz, 0.0033-160 Hz and 8-10 kHz. Preliminary observations made during the May 2003 eruption show that electric and magnetic signals appeared before the eruption. Some signals present sharp step-like variations, with amplitudes up to several hundreds mV per km and a few hour duration, followed by periods with a higher spectral frequency content. The frequency of these signals can be of several tens of Hz.The Corinth rift is a highly seismic area, frequently affected by seismic swarms. In 2004 the region has experienced tens of earthquakes of magnitude less than 4.6. A Demeter station has been set up on the Trizonia Island along the northern mainland coast, where a 30 km long seismic gap has been identified. The station is composed of two modules recording the three components of the magnetic field and the two horizontal components of the electric field in the ULF and ELF-VLF frequency bands. The audiomagnetotelluric soundings show that the station is close to a regional conductive fault connected to the sea. The first 4 months of observation clearly show that 29 earthquakes, even of low magnitude (M?2.8), occurring at less than 140 km of distance of the station, have generated electric signals when the seismic waves have passed the EM station. For a given magnitude of the earthquake, the energy of the electric signal is independent of the distance between the focal source and the EM station, which points out local electric source mechanisms. The greater the magnitude of the earthquake, the greater is the energy of the electric signal is. The co-seismic electric signals have the same morphology as that of the passing seismic wave, and there is no noticeable time delay between the electric and the seismic signals. This simultaneity between the seismic and the electric signal is best explained by the generation of an electrokinetic effect due to the passage of the seismic wave through the seawater-saturated ground.