电感耦合等离子体发射光谱法测试地质样品中的基体效应及校正办法

电感耦合等离子体发射光谱（ICP-AES）法分析速度快、干扰较少并能同时测定多种元素，被广泛应用于地质调查样品的分析测试中，成为通用的无机化学元素分析测试工具.在测定复杂基体样品时，由于基体效应产生的各种干扰也会影响分析测试结果，包括光谱干扰、物理干扰、化学干扰、电离干扰等.以ICAP-6000型号仪器为例，结合仪器特点及实际工作经验，对复杂基体地质样品测定中出现干扰的原因、特点进行分析，探讨基体消除的方法以保障测试结果的准确性.     

A study of transient variations in the Earth’s electromagnetic field at equatorial electrojet latitudes in western Africa (Mali and the Ivory Coast)

In the framework of the French-Ivorian participation to the IEEY, a network of 10 electromagnetic stations were installed at African longitudes. The aim of this experiment was twofold: firstly, to study the magnetic signature of the equatorial electrojet on the one hand, and secondly, to characterize the induced electric field variations on the other hand. The first results of the magnetic field investigations were presented by Doumouya and coworkers. Those of the electric field experiment will be discussed in this study. The electromagnetic experiment will be described. The analysis of the electromagnetic transient variations was conducted in accordance with the classical distinction between quiet and disturbed magnetic situations. A morphological analysis of the recordings is given, taking into consideration successively quiet and disturbed magnetic situations, with the results interpreted in terms of the characterization of external and internal sources. Particular attention was paid to the effects of the source characteristics on the induced field of internal origin, and to the bias they may consequently cause to the results of electromagnetic probing of the Earth; the source effect in electromagnetic induction studies. During quiet magnetic situations, our results demonstrated the existence of two different sources. One of these, the S_R^E source, was responsible for most of the magnetic diurnal variation and corresponded to the well-known magnetic signature of the equatorial electrojet. The other source (the S_R*^E source) was responsible for most of the electric diurnal variation, and was also likely to be an ionospheric source. Electric and magnetic diurnal variations are therefore related to different ionospheric sources, and interpreting the electric diurnal variation as induced by the magnetic field diurnal variation is not relevant. Furthermore, the magnetotelluric probing of the upper mantle at dip equator latitudes with the electromagnetic diurnal variation is consequently impossible to perform. In the case of irregular variations, the source effect related to the equatorial electrojet is also discussed. A Gaussian model of equatorial electrojet was considered, and apparent resistivities were computed for two models of stratified Earth corresponding to the average resistive structure of the two tectonic provinces crossed by the profile: a sedimentary basin and a cratonic shield. The apparent resistivity curves were found to depend significantly on both the model used and the distance to the center of the electrojet. These numerical results confirm the existence of a daytime source effect related to the equatorial electrojet. Furthermore, we show that the results account for the observed differences between daytime and night-time apparent resistivity curves. In particular, it was shown that electromagnetic probing of the Earth using the classical Cagniard-Tikhonov magnetotelluric method is impossible with daytime recordings made at dip latitude stations.     

地震前电磁辐射信息特征研究

反映电磁辐射信息的地震前异常变化很多,但都有一个震前平静－加强－平静然后发震的特征,为了更好地体现这种特征,根据十几年来河北廊坊电磁台网的观测资料,通过给不同强度段的各台日信息量赋予不同的权值,并把当日各台权值累加来反映当日内多台信息量集中的强弱,然后把上述权累加和用一种不连续积分的方法反映异常的持续时间,通过对监测范围内４次Ｍｓ≥５．０地震震例分析,发现该方法反映震前异常特征明显,短临效果很好,     

Cylindrically symmetric inhomogeneous universe with electromagnetic field in string cosmology

Cylindrically symmetric inhomogeneous string cosmological model in presence of electromagnetic field is investigated. We have assumed that F ₂₃ is the only non-vanishing component of F _ij . To get the deterministic solution, it has been assumed that the expansion (θ) in the model is proportional to the eigen value σ ¹ ₁ of the shear tensor σ ⁱ _j . The physical and geometric aspects of the model are also discussed.      

简化磁力计非线性误差模型的快速校正算法

针对传统的磁力计校正算法中存在的误差模型复杂、计算时间长、需要保持水平姿态和已知航向信息等弊端,该文从磁力计误差特性入手,推导并建立了简化的磁力计非线性等效误差模型。基于动态调整策略对传统的LM算法进行改进,并利用改进的LM算法求解误差模型,减少计算过程中的迭代次数,实现了磁力计误差的快速估计。实验表明,该方法在有效保证磁力计校正精度的前提下,迭代次数减少25%,计算速度提高了65.59%。     

Detection and Correction of AMSR-E Radio-Frequency Interference

Radio-frequency interference (RFI) affects greatly the quality of the data and retrieval products from space-borne microwave radiometry. Analysis of the Advanced Microwave Scanning Radiometer on the Earth Observing System (AMSR-E) Aqua satellite observations reveals very strong and widespread RFI contam- inations on the C- and X-band data. Fortunately, the strong and moderate RFI signals can be easily identified using an index on observed brightness temperature spectrum. It is the weak RFI that is diffi- cult to be separated from the nature surface emission. In this study, a new algorithm is proposed for RFI detection and correction. The simulated brightness temperature is used as a background signal (B) and a departure of the observation from the background (O-B) is utilized for detection of RFI. It is found that the O-B departure can result from either a natural event (e.g., precipitation or flooding) or an RFI signal. A separation between the nature event and RFI is further realized based on the scattering index (SI). A positive SI index and low brightness temperatures at high frequencies indicate precipitation. In the RFI correction, a relationship between AMSR-E measurements at 10.65 GHz and those at 18.7 or 6.925 GHz is first developed using the AMSR-E training data sets under RFI-free conditions. Contamination of AMSR-E measurements at 10.65 GHz is then predicted from the RFI-free measurements at 18.7 or 6.925 GHz using this relationship. It is shown that AMSR-E measurements with the RFI-correction algorithm have better agreement with simulations in a variety of surface conditions.     

输变电设施电磁辐射环境影响评价方法探讨

结合输变电设施周围电磁环境特点,对其电磁辐射环境影响评价方法进行探讨,提出相应的电磁辐射污染防治措施与建议,消除公众疑虑。在此基础上,总结当前电磁辐射环评工作中存在的问题,以期为后续同类问题深入研究提供思路。     

Long-Term Observations of Isotope Ratio Accuracy and Reproducibility Using Quadrupole ICP-MS

High precision isotope ratio and trace element determination can be achieved with modern quadrupole ICP-MS provided that short and long-term instrument performance is accurately monitored. Here we present results for the isotope ratios ⁶Li/⁷Li, ¹⁴⁷Sm/¹⁴⁹Sm, ¹⁶⁰Dy/¹⁶¹Dy, ²⁰⁷Pb/²⁰⁶Pb, ²⁰⁸Pb/²⁰⁶Pb, ²⁰⁶Pb/²⁰⁴Pb and ²³⁵U/²³⁸U with which we determined long-term isotope ratio stability of relevance to both trace element and isotope determination. With respect to trace element determination, we first present long-term observations regarding oxide formation rates of Ba and Nd on light REE and heavy REE, as well as Zr on Ag. These showed good correlations and could be used to correct effectively the interference. The efficacy of this correction was demonstrated with analyses of the rock reference material BHVO-2 at both low and high oxide formation rates. Next, we studied the long-term reproducibility of a Dy isotope ratio that was measured to correct for the isobaric interference on Gd. It was found that, regardless of tuning condition, the ratio reproduced very well (0.58% RSD, 1s) and that the estimate of the Gd concentration did not suffer from the large correction (> 10%) caused by the Dy isobar. Long-term reproducibilities of Li, Sm and U isotope ratios, required for accurate mass bias correction when isotopically enriched internal standards of these elements are employed, were measured in the rock reference materials AGV-2 and JA-3 over a time period of up to 3 years. As expected, the Li isotope ratio showed the largest variability (RSD = 7%), but the other two ratios had relative external reproducibilities of only 1.01% (1s, U) and 0.67% (Sm). The mass bias-induced scatter in measurements for Sm and U was so small that the internal standard correction was effective, even for samples with high concentrations of these elements. With regard to Pb-isotope ratio determination, we also present long-term reproducibility for NIST SRM 982, run as an unknown and two accuracy tests for Pb separated from granitoids and from meteorites. It is demonstrated that the obtained ratios, including those involving ²⁰⁴Pb, are accurate relative to MC-ICP-MS determinations and of comparable precision to conventional TIMS analysis. The excellent agreement between all data sets shows the potential of modern quadrupole ICP-MS instrumentation for Pb-isotope determination, particularly for samples with very low Pb content.     

孤立内波对过渡海域声场干涉结构的影响分析

南海北部陆坡海域是孤立内波的活跃区,孤立内波在该海域能够引起水体环境较强烈的水平不均匀性,从而影响声场干涉结构。将描述宽带声信号强度干涉条纹斜率的波导不变量视为一种分布,能更准确地分析声场的距离*频率干涉结构。本文研究了孤立内波环境下过渡海域声场的距离*频率干涉结构,依据实测孤立内波海洋环境,得到孤立内波环境下随距离变化的声速剖面,利用抛物方程方法仿真过渡海域声场干涉结构。在此基础上,利用拉东变换和傅里叶变换结合的谱值分离方法在低信噪比环境下提取波导不变量分布。分析表明孤立内波环境下过渡海域的声场类影区、类会聚区的波导不变量取值更丰富。     

山西阳泉矿区煤层气分层排采分析

煤层气开发过程中,由于各煤层及其顶底板之间物性特征等方面的差异,易导致层间干扰,影响煤层气产能。阳泉矿区煤层气资源储量丰富,主要可采煤层有3#、8#、9#、15#煤层,其中3#煤层为局部可采煤层。以该区YQ-191和YQ-359井为例,通过分析8#、9#、15#煤层在渗透率、储层压力、煤层厚度、含气量、埋藏深度、水文地质条件的差异,发现,YQ-191井8#、9#的各项参数较为接近,层间干扰小,适宜合层开采;YQ-359井8#、15#煤层渗透率与储层压力相差较大,层间干扰严重,合层开采严重影响15#煤层的产能,该井8#、15#煤层不适宜合层开采。