鄂东丰山矿田花岗闪长斑岩体锆石SHRIMP U－Pb定年及其意义

鄂东丰山矿田是长江中下游多金属成矿带的重要组成部分,由鸡笼山、丰山和李家湾等大－中型铜金多金属矿床组成。矿体产于燕山期花岗闪长斑岩体与三叠系碳酸盐岩接触带中,成矿作用与燕山期花岗闪长斑岩密切相关。作者采用锆石SHRIMP U－Pb定年方法对鸡笼山和丰山矿区成矿斑岩体进行了年代学研究,获得鸡笼山和丰山花岗闪长斑岩的锆石微区原位SHRIMP U－Pb年龄分别为138±2Ma（95%可信度,MSWD=5.1）和137±2Ma（95%可信度,MSWD=1.4）,与前人已报道的鄂东南矿集区内典型铜－金－钼－（钨）矿床中辉钼矿Re－Os等时线年龄（140Ma±）吻合,表明丰山矿田成岩成矿事件均发生于早白垩世。本次研究还在鸡笼山花岗闪长斑岩体中发现了新太古代锆石年龄信息,证实了扬子陆块北缘可能存在新太古－古元古代结晶基底。     

Google地图应用之广东省地区JOPENS地震速报系统

利用Google公司提供的电子地图服务,以B/S结构(即浏览器和服务器结构)作为系统设计架构,监听JOPENS实时系统发送的地震触发消息,访问JOPENS数据库,根据广东省地区的监测要求,制定检索、筛选策略,获取地震详细信息,显示在浏览器网页上.采用Google地图的JOPENS地震速报系统可以使地震信息发布的显示内容...     

西安市地震应急指挥技术系统设计与实现

本文从系统总体架构设计、系统功能设计与应用成果、系统特色4个方面简要介绍了西安市地震应急指挥技术系统设计与实现情况.本系统是首个应用于省会城市地震应急工作,并基于国产Server GIS软件平台研制开发出的地震应急指挥技术系统,可为大城市地震应急指挥技术系统的建设与发展提供可借鉴的经验.     

对照组和雌核发育牙鲆血清中睾酮与雌二醇水平的比较

采用放射性免疫方法测定和比较了人工诱导的雌核发育牙鲆（Paralichthys olivaceus）与对照组牙鲆血清中睾酮（T）和雌二醇（E2）水平。研究发现, 雌核发育牙鲆个体中的T 含量显著高于对照组牙鲆个体（P〈0.05）, 而其E2 含量则略低于对照组个体; 在雌核发育牙鲆中, 卵巢发育不正常的个体比发育正常的...     

Extraction and PTP1B inhibitory activity of bromophenols from the marine red alga Symphyocladia latiuscula

Previously, we had characterized several structurally interesting brominated phenols from the marine red alga Symphyocladia latiuscula collected from various sites. However, Phytochemical investigations on this species collected from the Weihai coastline of Shandong Province remains blank. Therefore, we characterized the chemical constituents of individuals of this species collected from the region. Eight bromophenols were isolated and identified. Using detailed spectroscopic techniques and comparisons with published data, these compounds were identified as 2,3-dibromo-4,5-dihydroxybenzyl methyl ether (1), 3,5-dibromo-4-hydroxybenzoic acid (2), 2,3,6-tribromo-4,5-dihydroxymethylbenzene (3), 2,3,6-tribromo-4,5-dihydroxybenzaldehyde (4), 2,3,6-tribromo-4,5-dihydroxybenzyl methyl ether (5), bis(2,3,6-tribromo-4,5-dihydroxyphenyl)methane (6), 1,2-bis(2,3,6-tribromo-4,5-dihydroxyphenyl)-ethane (7), and 1-(2,3,6-tribromo-4,5-dihydroxybenzyl)-pyrrolidin-2-one (8). Among these compounds, 1 and 2 were isolated for the first time from S. latiuscula. Each compound was evaluated on the ability to inhibit protein tyrosine phosphatase 1B (PTP1B), which is a potential therapeutic target in the treatment of type 2 diabetes. Bromophenols 5, 6, and 7 showed strong activities with IC50 values of 3.9, 4.3, and 3.5 μmol/L, respectively. This study provides further evidence that bromophenols are predominant among the chemical constituents of Symphyocladia, and that some of these compounds may be candidates for the development of anti-diabetes drugs.     

Molecular identification based on ITS sequences for Kappaphycus and Eucheuma cultivated in China

The systematic classification of the Eucheumatoideae is difficult because of their variable morphology and interpretation of reproductive structures. Kappaphycus and Eucheuma specimens cultivated on the Hainan and Fujian coast of China were introduced from Vietnam, the Philippines and Indonesia. Combined with morphological characteristics, all Kappaphycus and Eucheuma cultivated strains were identified by internal transcribed spacer (ITS) sequences. The phylogenetic tree was constructed using neighbor-joining and maximum likelihood methods. The results indicate that different ITS sequence lengths occurred in the different genera and species. An obvious difference in morphology could be found in the protuberance shape between Kappaphycus and Eucheuma. The protuberance in Eucheuma was thorn-like and in Kappaphycus was wartlike or papillate. Their ITS sequence lengths differed significantly in nucleotide variation rates up to 58.55%-63.90%. All nucleotide variations occurred in the ITS1 and ITS2 regions except for five nucleotide transversions in the 5.8S rDNA region. In addition, the difference was at the branches among congeneric species. Kappaphycus sp. had branches with small buds, while K. alvarezii did not have such a feature. The nucleotide variation rates varied from 7.02% to 7.48% among species; within the same species of the clades it was <1.20%. Eucheumatoideae algae cultivated in China consisted of three clades, K. alvarezii, Kappaphycus sp., and E. denticulatum. The results indicate that ITS sequence analysis was an effective way for identification of interspecies and intraspecies phylogenetic relationships and might provide a clue for molecular identification of algal Eucheumatoideae.     

Synthesis and protein tyrosine phosphatase 1B inhibition activities of two new synthetic bromophenols and their methoxy derivatives

3-bromo-4,5-bis(2,3-dibromo-4,5-dihydroxybenzyl)-1,2-benzenediol (1) is a natural bromophenol isolated from the red algae Rhodomela confervoides that exhibits significant inhibition against protein tyrosine phosphatase 1B (PTP1B). Based on its activity, we synthesized two new synthetic bromophenols and their methoxy derivatives from vanillin using the structure of natural bromophenol 1 as a scaffold. The structures of these bromophenols were elucidated from 1H NMR, 13C NMR, and high resolution electron ionization mass spectrometry as 2,3-dibromo-1-(2p-bromo-6p-(3q,4q-dimethoxybenzyl)- 3p,4p-dimethoxybenzyl)-4,5-dimethoxybenzene(2),2,3-dibromo-1-(2p-bromo-6p-(2q-bromo-4q,5q-dimethoxy-benzyl)-3p,4p-dimethoxybenzyl)-4,5-dimethoxybenzene(3),3,4-dibromo-5-(2p-bromo-6p-(2q-bromo-4q,5q-dihydroxybenzyl)-3p,4p-dihydroxybenzyl)pyrocatechol(4)and 3,4-dibromo-5-(2p-bromo-6p-(3q,4q-dihydroxybenzyl)-3p,4p-dihydroxybenzyl)pyrocatechol (5).PTP1B inhibition activities of these compounds were evaluated using a colorimetric assay,and compounds 3 and 4 demonstrated interesting activity against PTP1B.     

基于HJ-1B/IRS的重庆市热岛效应监测应用

本文利用MODIS数据反演大气透射率,利用HJ-1B/CCD进行分类,并反演地表比辐射率.在此基础上,借鉴单窗算法,利用HJ-1B/IRS数据反演得到地表温度,并利用MODIS温度产品对反演结果进行了初步验证.最后利用热场变异指数进一步分析重庆的热岛空间分布特征,并对NDVI与NDBI对热岛效应的影响进行了分析.其结论...     

GPS资料同化中一种快速优化算法

GPS资料同化最终归结为一个大规模的无约束优化问题。由于问题的维数很高，使得寻找到一种快速且节约存储的优化算法成为GPS资料同化能否满足在业务数值天气预报上的要求的关键。提出了一种新的优化算法。该方法把L-BFGS和HFN两种方法动态的结合起来，同时利用有限差分技术和截去技术，使算法在存储和计算量适合当前设备的前提下，较大的提高了算法的收敛速度。数值试验表明，该方法的计算效率与L-BFGS方法相比有十分明显的改善。     

气温变化对冬小麦生育的影响

利用驻马店市1961年10月—2002年5月冬小麦生长季内平均气温资料以及气温5年滑动平均变化曲线图，采用相关分析法，分析了驻马店市冬小麦生长季内气温变化特征，并利用1981年以后的冬小麦作物观测资料，经过对比分析，揭示了冬小麦生长发育过程中因暖温而产生的一系列变化。