发射光谱载体蒸馏法测定地质样品中微量硼铍锡银

选择了适合的缓冲剂,利用载体蒸馏法将被测元素与基体元素分离,使Be转变为易挥发的氟化物与B、Sn、Ag同时蒸发;降低了谱线背景及元素检出限;加入内标元素Au、Bi,提高了方法的准确度和精密度;采用普通 3mm×3mm×0.7mm杯型电极,装样量少,操作简单。方法检出限(wB/10-6)分别可达B1.5、Be0.3、Sn0.8、Ag0.02;准确度(Δlog C)基本在-0.05～0.05,精密度(RSD,n=8)为2.9%～17%。     

Comparisons on seasonal and annual variations of δ~(18)O in precipitation

interpretationofpaleoclimaticrecordsinicecore(Dansgaardetal.,1969;Rozanskietal.,1997;Yao,1999;Thompsonetal.,2000).SincethefirstdeepicecorewasdrilledinGreenlandin1966(Dansgaardetal.,1969),hundredsoficecoreswereobtainedsuccessivelyfromicesheetsinAntarcticaandArctic,andmountainglaciersatmid-highlatitudes,fundedbynumerousresearchprogramsonglobalclimateandenvironmentalchange.Theseicecoresprovideuniqueandvaluablefirst-handinformationinrecoveringglobalpaleoenvironmentalrecordsandforecastingfuturecl…     

Submillimeter-wave and observations of the event on 28 November, 2001

We present a detailed study of a 1B/M6.9 impulsive flare combining high time resolution (1 ms) and instantaneous emission source localization observations at submillimeter frequencies (212 GHz), obtained with the solar submillimeter telescope (SST), and Hα data from the Hα solar telescope for argentina (HASTA). The flare, starting at 16:34 UT, occurred in active region (AR) 9715 (NOAA number) on November 28, 2001, and was followed by an Hα surge. We complement our data with magnetograms from the Michelson Doppler Imager (SOHO/MDI). SST observed a short impulsive burst at 212 GHz, presenting a weak bulk emission (of about 90 sfu) composed of a few shorter duration structures. The integrated Hα and the 212 GHz light curves present a remarkable agreement during the impulsive phase of the event. The delay between both curves stays below 12 s (the time resolution of the Hα telescope). The flare as well as the surge are linked to new flux emergence very close to the main AR bipole. Taking into account the AR magnetic field evolution, we infer that magnetic field reconnection, occurring at low coronal levels, could have been at the origin of the flare; while in the case of surge this would happen at the chromospheric level.     

Experimental study on soil CO2 emission in the alpine grassland ecosystem on Tibetan Plateau

The Tibetan Plateau, the Roof of the World, is the highest plateau with a mean elevation of 4000 m. It is characterized by high levels of solar radiation, low air temperature and low air pressure compared to other regions around the world. The alpine grassland, a typical ecosystem in the Tibetan Plateau, is distributed across regions over the elevation of 4500 m. Few studies for carbon flux in alpine grassland on the Tibetan Plateau were conducted due to rigorous natural conditions. A study of soil respiration under alpine grassland ecosystem on the Tibetan Plateau from October 1999 to October 2001 was conducted at Pangkog County, Tibetan Plateau (31.23°N, 90.01°E, elevation 4800 m). The measurements were taken using a static closed chamber technique, usually every two weeks during the summer and at other times at monthly intervals. The obvious diurnal variation of CO2 emissions from soil with higher emission during daytime and lower emission during nighttime was discovered. Diurnal CO2 flux fluctuated from minimum at 05:00 to maximum at 14:00 in local time. Seasonal CO2 fluxes increased in summer and decreased in winter, representing a great variation of seasonal soil respiration. The mean soil CO2 fluxes in the alpine grassland ecosystem were 21.39 mgCO2 · m-2 · h-1, with an average annual amount of soil respiration of 187.46 gCO2 · m-2 · a-1. Net ecosystem productivity is also estimated, which indicated that the alpine grassland ecosystem is a carbon sink.     

Study of statistically correcting model CMAQ-MOS for forecasting regional air quality

Based on analysis of the air pollution observational data at 8 observation sites in Beijing including outer suburbs during the period from September 2004 to March 2005, this paper reveals synchronal and in-phase characteristics in the spatial and temporal variation of air pollutants on a city-proper scale at deferent sites; describes seasonal differences of the pollutant emission influence between the heating and non-heating periods, also significantly local differences of the pollutant emission influence between the urban district and outer suburbs, i.e. the spatial and temporal distribution of air pollutant is closely related with that of the pollutant emission intensity. This study shows that due to complexity of the spatial and temporal distribution of pollution emission sources, the new generation Community Multi-scale Air Quality (CMAQ) model developed by the EPA of USA produced forecasts, as other models did, with a systematic error of significantly lower than observations, albeit the model has better capability than previous models had in predicting the spatial distribution and variation tendency of multi-sort pollutants. The reason might be that the CMAQ adopts average amount of pollutant emission inventory, so that the model is difficult to objectively and finely describe the distribution and variation of pollution emission sources intensity on different spatial and temporal scales in the areas, in which the pollution is to be forecast. In order to correct the systematic prediction error resulting from the average pollutant emission inventory in CMAQ, this study proposes a new way of combining dynamics and statistics and establishes a statistically correcting model CMAQ-MOS for forecasts of regional air quality by utilizing the relationship of CMAQ outputs with corresponding observations, and tests the forecast capability. The investigation of experiments presents that CMAQ-MOS reduces the systematic errors of CMAQ because of the uncertainty of pollution emission inventory and improves the forecast level of air quality. Also this work employed a way of combining point and area forecasting, i.e. taking the products of CMAQ for a center site to forecast air pollution for other sites in vicinity with the scheme of model products "reanalysis" and average over the "area".     

Localization of mining-induced horizontal fractures along rock layer interfaces in overburden: field measurements and prediction

The locations of mining-induced horizontal fractures along rock interfaces in the overburden of Donetsk Coal Basin were identified using an original experimental device. The device traps methane from horizontal fracture zone (100–fold coal seam thickness) over an active longwall mining excavation. Presence or absence of horizontal fractures along rock layer interfaces is correlated with physical characteristics of the overburden, such as thickness, uniaxial compressive strength of overburden rock layers, location of rock layer interfaces and thickness of extracted coal seams. As a result, a combined criterion based on these physical characteristics is proposed to predict the presence of overburden horizontal fracturing in coal mine operations.     

On Tension Failure of 2-D Rock Specimens and Associated Acoustic Emission

Summary To understand the failure mechanism of quasi-brittle materials like rock under tensile stress, observations on the failure process of granite and marble plate specimens under tension are summarized and presented. Micro- and macro-failure properties of rock plates under uniaxial tension have been characterized by using an acoustic emission technique. Acoustic emission signals associated with micro-fractures are captured to locate the sources. An algorithm based on arrival time difference is developed for this purpose. The results reveal clearly the failure processes of rock which include initiation, nucleation and propagation of micro-fractures when the axial stress is close to the peak strength of rock. It is believed that the difference in heterogeneity between granite and marble specimens leads to different fracture shapes and different behaviors of associated acoustic emissions. Numerical simulation of acoustic emissions for two-dimensional tensile test is also carried out. The simulated characteristics are in good agreement with the experimental results.     

沙尘天气频率与相关气象因子的关系

基于北京及其周边14个国家基本气象站1971—2000年气象资料的相关分析,指出风速、相对湿度是影响沙尘天气的关键气象因子,用这两个气象因子构建了月沙尘气象指数。月沙尘气象指数与沙尘天气频率具有较一致的周期性,沙尘天气日的沙尘气象指数是非沙尘日指数的倍数关系。另外,根据月沙尘气象指数在不同月份的分布特征,给出了相应的季节性气象指数计算方法,对14个站计算的结果显示,季节性气象指数与沙尘天气频率有很好的线性关系,这种线性关系具有明显的区域特征。     

GRAPES千米尺度模式在西南复杂地形区降水预报偏差与成因初探

利用2019年夏季（6—8月）西南复杂地形区地面观测站逐时和逐日降水量观测数据,从降水量和降水频率入手,对同期GRAPES-Meso 3 km业务模式短期（36 h以内）降水预报性能,特别是在不同典型地貌区—四川盆地子区、云贵高原北部子区和南部子区、青藏高原东缘山地子区的预报偏差进行细致评估与分析。结果表明:（1）GRAPES-Meso 3 km模式能合理地刻画出西南复杂地形区夏季日降水和日内尺度降水的主要特征,以及小时降水频次-强度的基本关系。（2）在各子区,模式日降水量（频率）预报表现为清晰的正偏差,正偏差在盆地子区最显著,为观测值的1.1倍（0.3倍）;日降水量正偏差主要由强降水日降水量预报偏大引起,但频率正偏差在云贵高原南、北子区与其他两个子区不同,主要是中小雨日数预报偏多的贡献;强降水（中小雨）落区预报存在明显（轻微）偏大倾向,强降水预报落区偏大频率在青藏高原东缘山地子区最高,达82.8%,在云贵高原南部子区最低,为53.6%。（3）日循环上,各时次小时降水量（频率）预报整体偏大,且主要正偏差出现在观测的夜雨峰值时段,其中海拔1200 m以下区域的降水频率正偏差从夜间峰值区延续到中午,模式偏强的日降水量预报往往表现为日内偏长的降水时长或小时降水空报。（4）诊断分析显示,模式在四川盆地区突出的夏季日降水预报正偏差是模式对流层低层在云贵高原南-东南侧偏强的西南风预报与西南地区特殊地形结合的产物。      

海相碳酸盐岩层系不整合量化研究及其意义——以四川盆地北部二叠系为例

本文以四川盆地北部二叠系为例,将层序地层分析和沉积盆地波动过程分析相结合,提出了运用沉积波动过程分析研究沉积记录不完整性的量化方法,该方法可以相对准确地定量描述盆地形成演化过程中的升降运动,恢复无地层"记录"中的沉积-剥蚀过程,进而定量分析盆地的沉积-剥蚀过程、计算沉积间断(不整合)内的地层剥蚀量、认识其时空分布规律.同时,通过实际钻井及"人工井"的波动过程分析,结合地震剖面解释成果,可以作出主要不整合的空间分布图、各层位的剥蚀厚度图和原始厚度图、各期构造的剥蚀量分布图等重要基础图件,为盆地进一步系统分析及盆地模拟打好基础,结合沉积相研究及构造样式分析还可分析盆地沉积中心、生油层、盖层、储层等在时空中的变化规律.由于沉积盆地的升降波动过程直接影响着盆地的埋藏史、热史和生、排烃史,因此通过沉积波动过程的系统分析不仅能正确建立盆地演化的地质模型,还可以正确认识油气形成与分布规律,有效指导油气勘探.