合兴场地震资料吸收油气预测研究

在地震勘探中快速有效地进行油气预测的方法研究已成为我们目前十分重要的研究课题。我们研究了对地震资料利用吸收衰减理论对油气进行预测的油气预测实用技术。     

青海湖的地质构造背景及形成演化

青海湖地区位于 3个构造单元及多条深断裂的交汇部位 ,结构复杂 ,强度较弱。上新世出现断陷 ,中更新世成湖。湖盆可划分为 3个地垒和 3个次级断陷盆地。其形成和演化受中祁连南缘大断裂带、宗务隆山 -青海南山大断裂带和黑马河 -达日大断裂带重新活动及其它NWW ,NW ,NNW ,SN ,NE向断裂的活动及伴随的差异隆升所控制 ,与青藏高原的隆升演化有密切关系 ,尤其是可能与青藏高原发生后造山伸展作用有关的应力场转变造成的负反转构造有重要关系。中中新世夷平面形成以来的新构造活动和青海湖的形成演化具明显的脉动性。中中新世以来的新构造活动可分为 5个阶段 ,青海湖形成演化过程可大致分为 9期     

The effects of phase fractionation on the composition of oils, condensates and gases

The effects of phase fractionation on the composition of oils, condensates and gases have been studied in the laboratory by a differential evaporation experiment. The experiment was designed to simulate the behaviour of a single-charge petroleum during (upward) migration or in a reservoir undergoing uplift, scenarios thought to be typical for the Norwegian continental shelf. After each pressure reduction step, samples from all phases (oil, condensate, free and associated gas) were collected and analysed. The results show that, in general, small molecules are preferentially enriched in the gas phase, both at elevated pressure and temperature and under standard conditions (15°C, 1 bar). The solvent power of the gas phase for large molecules is drastically reduced at lower pressures (here below approx. 300 bar). Carbon isotope ratios of individual compound are not affected, while variations in isotope ratios of fractions can be explained by changes in the fraction compositions. Individual geochemical parameters behave as can be expected based on the molecular size and structure of the compounds involved. However, a generally valid, quantitative prediction of how geochemical parameters vary as a result of phase fractionation is very difficult, as this will depend not only on the pressure and temperature of fractionation, but also on the composition and amounts of the oil and gas that are involved. The observations from this study confirm the importance of phase fractionation as an important process to consider when interpreting geochemical data for both condensates and oils.     

人体泌尿系统结石及人发成分分析的意义

利用红外光谱分析法对尿路结石进行了物相分析,并用原子吸收分光光度法测定了结石和发样的微量元素,根据结石的物相特征、微量元素含量以及与人体发样微量元素含量进行对比分析,探讨了尿路结石的成因、影响因素及预防措施。     

纳米碳纤维红外消光数值计算

为探讨纳米碳纤维作为烟幕粒子的红外消光特性,基于电磁场理论建立了细直的纳米碳纤维感应电流积分方程,并利用矩量法进行了求解,导出了纳米碳纤维散射场及吸收、散射和消光截面的计算式.通过与变分法的计算结果相比较,表明了该方法的有效性.利用该方法数值分析了纳米碳纤维红外消光截面与入射场波长、入射角、纤维长度和半径的关系,计算结果为纳米碳纤维用于红外烟幕干扰提供了理论依据.     

NaAlH4 表面Ti催化空间构型和X射线吸收光谱:Car-Parrinello分子动力学和密度泛函理论研究

通过采用Car-Parrinello分子动力学方法对掺杂Ti前后的NaAlH₄(001)2×2×1超晶胞表面晶体在333 K(60 ℃)温度条件催化脱氢的空间构型做了理论研究,发现掺杂Ti的合金中AlH₄团的其中两个Al—H键长分别从约1.64 (1 =0.1 nm)增大至1.74和1.93 ,而未掺杂合金表面中AlH₄团的4个Al—H键长基本不变,这意味着掺杂Ti相对未掺杂的合金更易于放氢.但在模拟温度条件下并未发现Ti-Al成键趋     

Tunable surface-plasmon-resonance wavelength of silver island films

This paper experimentally and theoretically investigates the effect of the underlayer medium on tuning of the surface plasmon resonance (SPR) wavelength of silver island films, and the effect of substrate temperature on the morphologies and optical properties of the films. From the absorption spectra of single Ag with various thickness and overcoated (Ag/TiO₂) films deposited on glass substrates at various substrate temperatures by RF magnetron sputtering, we demonstrate that the surface plasmon resonance wavelength can be made tunable by changing the underlayer medium, the thickness of metal layer and the substrate temperature. By varying substrate temperatures, the interparticle coupling effects on plasmon resonances of nanosilver particles enhance as the spacing between the particles reduces. When the substrate temperature is up to 500 ℃, the absorption peak decreases sharply and shifts to shorter wavelength side due to the severe coalescence between silver islands in the film.     

基于两种半分析算法的水体吸收系数反演

本文基于42组不同年份不同季节获得的遥感反射率、水体各组分吸收系数的实测数据,对QAA（Quasi-Analytical Algorithm）和GSM（Garver-Siegel-Maritorena）算法在寡营养的南海和富营养的福建沿岸两种不同类型水体的吸收系数反演进行了检验。以水样测量值为参考,两种算法在本研究水体中的反演成效与他人在其它水域的研究结果相当。QAA算法在南海的反演成效高于福建沿岸水体。对于443 nm的总吸收系数（a443 ）,南海的对数均方根误差（RMSE ）为0.046,平均相对误差为7.9%,对数平均偏差为0;福建沿岸水体的对数均方根误差（RMSE ）为0.194,平均相对误差为30.6%,对数平均偏差为-0.167 。GSM算法在两类水体的反演成效类似,A443 之RMSE和平均相对误差,南海分别为0.161和27.7%,福建沿岸分别为0.149和32.1%,但从A443的对数平均偏差值看,其在南海反演值低于实测值（对数平均偏差为-0.142 ）,在福建沿岸则略呈高于实测值（对数平均偏差为0.016）。两种算法中的部分经验参数与实测值之间的差异是产生反演误差的主要原因,为了提高反演精度,对算法中经验参数的更进一步区域化调整可能是必要的。     

燃烧氧化-非色散红外吸收法测定海水中溶解有机碳

采用燃烧氧化-非色散红外吸收法测定了海水中的溶解有机碳.结果表明,标准曲线的线性较好,精密度较高,方法检出限为0.024 mg/L;所测海水样DOC质量浓度的最高值为3.95 mg·L-1,最小值为1.47 mg·L-1;采样点距离海岸越远,DOC质量浓度越低.海水样品置于4 ℃下冷藏保存,滴加饱和HgCl2溶液的水样,其保存效果要好于不加饱和HgCl2溶液的水样,且在55 d内,其DOC质量浓度基本上没有发生变化.