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81.
This article summarizes work on multiple scattering based on models of media with randomly distributed scatterers. The scatterers are isotropic and statistically uniform. Measuring distance in terms of mean-free pathL
s and time in terms of the mean-free timesL
s/V, whereV is the velocity of scattered waves, we have more convenient dimensionless distance and time. It can be shown that after the dimensionless time equals 0.65 energy contributed from multiple scattering becomes predominant. Thus the later coda reflects the effect of multiple scattering rather than single scattering. Treating the seismic record, including starting and tail parts, as a whole, the diffusion theory predicts that at a dense distribution of scatterers and a small distance between source and receiver, codas reflect mainly intrinsicQ
i. Of course, this conclusion is coincident with the presumption of the diffusion theory,Q
s>Q
i. However, from a new integral equation of multiple scattering, which deals with the scattered waves and primary waves separately, the conclusion is similar but clearer. This article quotes the new expression for coda energy in two-dimensional space. It shows that if the receiver is close to the source, the coda decay reflects only intrinsicQ
i, then as the distance increases, effects of scatteringQ
s, are involved in the decay feature. The theoretical plots of coda decay show that it seems in most cases in the earthQ
i should not be smaller than one tenth ofQ
s.Project Sponsored by the Joint Earthquake Science Foundation of China. 相似文献
82.
叶蜡石、高岭石和迪开石的吸收光谱研究 总被引:3,自引:0,他引:3
对不同地区叶蜡石、高岭石、迪开石的吸收光谱测量及其高斯谱拟合说明,三各矿物的吸收光谱均由一个吸收边和三个吸收峰叠加而成。主吸收峰在562nm左右,峰高以迪开石为最大,高岭石次之,叶蜡石最低。同一地区不同颜色的叶蜡石,其主吸收峰位置随铁含量的增加向短波方向移动,相对峰高也随之增大。叶蜡石的颜色主要取决于主吸收峰的位置、高度和吸收边位置。可以认为,此吸收边为Fe^3 →O^2-荷移谱的低能拖尾部分,吸收峰则为铁离子的晶场谱带或晶场谱与Fe^2 →Fe^3 荷移的叠加。 相似文献
83.
新疆绿柱石宝石辐照致色机制的吸收光谱研究 总被引:1,自引:0,他引:1
本文对新疆阿尔泰天然淡蓝、浅蓝宝石级绿柱石辐照前后及退火处理伴随着颜色改变的吸收光谱等进行了分析讨论,认为天然淡蓝、浅蓝色绿柱石经~(60)Co-γ辐照变成黄绿色,其原因主要归因于遂道中Fe~(2-)向Fe~(3+)的转变和八面体中Fe~(3+)和配位体O~(2-)的电荷转移。 相似文献
84.
A. Waltrop S. K. Mitra A. I. Flossmann H. R. Pruppacher 《Journal of Atmospheric Chemistry》1991,12(1):1-17
An experimental study involving the Mainz vertical wind tunnel is described where the rate of SO2 removed from the air by freely suspended water drops was measured for SO2 concentrations in the gas phase ranging between 50 and 500 ppb, and for various H2O2 concentrations in the liquid phase. In a first set of experiments, the pH inside the SO2 absorbing drops was monitored by means of colour pH indicators added to the drops. In a second set of experiments, the amount of SO2 scavenged by the drops was determined as sulfate by an ionchromatograph after the drops had been removed from the vertical air stream of the wind tunnel after various times of exposure to SO2. The results of our experimental study were compared with the theoretical gas diffusion model of Walcek and Pruppacher which was reformulated for the case of SO2 concentrations in the ppbv(v) range for which the main resistance to diffusion lies in the gas phase surrounding the drop. Excellent agreement between experiment and theory was obtained. Encouraged by this agreement, the theory was used to investigate the rate of sulfate production inside a drop as a function of pH. The sulfate production rate, which includes transport and oxidation, was compared with the production rate based on bulk equilibrium, as cited in the literature. 相似文献
85.
86.
87.
88.
D. Perner U. Platt M. Trainer G. Hübler J. Drummond W. Junkermann J. Rudolph B. Schubert A. Volz D. H. Ehhalt K. J. Rumpel G. Helas 《Journal of Atmospheric Chemistry》1987,5(2):185-216
Using long path UV absorption spectroscopy we have measured OH concentrations close to the earth's surface. The OH values observed at two locations in Germany during 1980 through 1983 range from 0.7×106 to 3.2×106 cm-3. Simultaneously we measured the concentrations of O3, H2O, NO, NO2, CH4, CO, and the light non methane hydrocarbons. We also determined the photolysis rates of O3 and NO2. This allows calculations of OH using a zero dimensional time depdendent model. The modelled OH concentrations significantly exceed the measured values for low NO
x
concentrations. It is argued that additional, so far unidentified. HO
x
loss reactions must be responsible for that discrepancy. 相似文献
89.
90.
The ultraviolet absorption cross sections were measured for CF3Br, CF2ClBr, CF2Br-CF2Br, CF2Br2, CHF2Br, CHFBr-CF3, CH2Br-CF3, CHClBr-CF3 in the wavelength range 190–320 nm at 295 K. The photolysis is concluded to be the minor atmospheric sink for CHF2Br, CHFBr-CF3, CH2Br-CF3, CHClBr-CF3. 相似文献