The effects of carbon dioxide leakage on fractures, and water quality of potable aquifers during geological sequestration of CO2

Since industrial revolution, the ＂greenhouse effect＂ is one of the most important global environmental issues. Of all the greenhouse gases, CO2 is responsible for about 64% of the enhanced ＂greenhouse effect＂, making it the target for mitigation, so reducing anthropogenic discharge of carbon dioxide attracts more and more attention. Geological sequestration of CO2 in deep saline aquifers is one of the most promising options. But because unknown fractures and faults may exist in the caprock layers which can prevent the leakage of CO2, CO2 will leak upward into upper potable aquifers, and lead to adverse impacts on the shallow potable aquifers. In order to assess the potential effect of CO2 leakage from underground storage reservoirs on fractures and water quality of potable aquifers, this study used the non-isothermal reactive geochemical transport code TOUGHREACT developed by Xu et al to establish a simplified 2-D model of CO2 underground sequestration system, which includes deep saline aquifers, caprock layers, and shallow potable aquifers, and study and analyze the changes of mineral and aqueous components. The simulation results indicated that the minerals of deep saline aquifers and fractures should be mainly composed of aluminosilicate and silicate minerals, which not only enhance the mass of CO2 sequestrated by mineral trapping, but also decrease the porosity and permeability of caprock layers and fractures to prevent and reduce CO2 leakage. The results from deep saline aquifers showed that the mass of carbon dioxide trapped by minerals and solution phases is limited, the rest remained as a supercritical phase, and so once the caprock aquifers have some unknown fractures, the free carbon dioxide phase may leak from CO2 geologic sequestration reservoirs by buoyancy.     

Geochemistry of soils derived from black shale, central Hunan, China

The black shale formed under anoxic conditions usually contains high concentrations of many metals. Weathering of such black shale might cause the emission of many metals. Moreover, soils derived from black shale （SBS） are believed to be affected by black shale weathering. In recent years, many studies such as Lee et al. （2002）, Woo et al. （2002）, Fang et al. （2002）, Pasava et al. （2003）, and Peng et al. （2004） have approached the heavy metal contaminations of SBS, but systematical geochemical study is rare. Presently, the SBS and its corresponding black shales （CBS） were both sampled from central Hunan （China）, and analyzed for a large number of elements, using an Elan6000 ICP-MS/AES machine at Guangzhou Institute of Geochemistry, CAS. In this paper, some preliminary results are reported. The analytical results show that the SBS in central Hunan contains very high concentrations of heavy metals such as Co, Cu, Hg, Mo, Pb, Zn, U, Th, Sb, T1, Cd, Cr, Sc, V, Sn, As, Se, and Ni.     

Heavy metal contamination in the sediment of the Second Songhua River

The Second Songhua River was subjected to a large amount of untreated effluent from petrochemical industries in Jilin City in the 1960s to the 1970s. The objectives of this study were to investigate the mercury and other heavy metal contamination in the sediment of the river. The river bottom sediment was sampled from the river segment between Jilin City to Haerbin City in 2005. Total concentrations of Hg, Cd, Cu, Cr, Pb, Zn, Ni, As, Sc, and major cations （A1, Fe, Mg, Ca, K, Na） in the sediment were measured by atomic fluorescence spectrometer, ICP-MS, and ICP-OES, respectively, following digestion with various acids. We found the concentrations of most elements in the uncontaminated sediment were significantly correlated to those of Sc.     

Influence of humic acid on bioavailability of heavy metals in sediments

The mimetic ocean environment and chemical method were used to research the bioavailability effect of humic acid on five heavy metals in sediment, including Cd, Cu, Zn, Pb and Ni. The sediment was separated into four containers with artificial seawater, and each of them had different concentrations of humic acid. The values of concentrations covered the whole range found in natural sediment （0.1%-10%）. According to the 48 hours LC50 of clam and distribution coefficient, metals were added in artificial seawater, and their speciation was determined at first and then after two days＇ incubation. It was found the bioavailability of heavy metals was reduced in the presence of humic acid. The obvious negative effect on Zn was observed, but the influence on Cd was not remarkable. In addition, the contents of Pb and Ni increased obviously in organic phase, and they are correlative with the concentrations of humic acid.     

长江下游一次大暴雨的中尺度模拟分析

运用中尺度数值模式（MM5V3.6）对2004年6月25日长江下游地区一次大暴雨天气过程进行了数值模拟,结合天气形势和卫星云图对此次过程进行了分析.结果表明：在东北冷涡和西太平洋副热带高压两大天气尺度系统的作用下,西南低空急流的再次加强和中低层切变线共同作用是此次大暴雨过程的主要原因.螺旋度分析表明,在不均匀的强上升气流的作用下,涡旋的水平分量向垂直分量转化是此次强降水的可能机制之一.     

非地转强迫对Fitow(0114)暴雨的影响

利用非静力中尺度模式MM5对 0 114号台风Fitow从 2 0 0 1年 8月 31日 0 0时～ 9月 2日 0 0时 (UTC ,下同 )的降水过程进行了模拟研究。结果表明 ,MM5对Fitow登陆过程中暴雨落区和强度的模拟与实况比较一致。模拟结果较好地再现了暴雨的中尺度特征。正是维持少动的台风倒槽和嵌入其中的中小尺度系统相互作用造成了暴雨的发生、发展 ,而高、低空中尺度散度场的配置对暴雨有很好的指示意义。在华南台风暴雨区无论是高层还是低层 ,都存在很强的非地转作用 ,非地转涡度项对散度倾向项是重要的强迫因素 ;但非地转作用的实现与中高纬度地区有本质的区别 ,在低层非地转作用是由于强的位势场气旋涡度 (- 2  <0 )与弱的流场气旋涡度 (fζ >0 )不平衡产生的 ;而高层非地转作用是由于强的位势场反气旋涡度 (- 2  >0 )与弱的流场反气旋涡度 (fζ <0 )不平衡产生的。非地转作用是暴雨中尺度系统上升运动发展的触发机制。从动力学角度解释了用非地转 Q矢量散度场来判断暴雨落区要比用准地转 Q矢量散度场好的原因。     

上海“8.5”特大暴雨的成因和特点

利用WSR－88D多普勒雷达资料，通过分析2001年8月5日到8月6日产生于上海地区的特大暴雨过程的雷达回波特征，研究探讨这次过程的降水成因和降水特点。发现副热带高压边缘偏南气流的风速辐合、螺旋雨带中强回波短带的合并加强、风的垂直切变产生的辐合以及热带系统的高效率降水作用是这次暴雨过程的降水成因和降水特点。并提出了预报这类暴雨系统需要注意的要点：强降水回波的发生和发展加强往往和风场中的局地强辐合区相联系，利用多普勒雷达连续演变的风场资料，可及时了解辐合区的形成和演变过程，提前作出强降水可能性的预测。     

初夏一次特大暴雨的诊断分析

对新疆1996年5月28－30日一次特大暴雨过程的诊断分析，给出了暴雨产生的原因。