Speciation and potential remobilization of heavy metals in sediments of the Taihu Lake, China

The species of Cu, Pb, Zn, Cd and Cr in sediments of the Taihu Lake, China, have been analyzed using the sequential chemical extraction method. Variations in the chemical fractions of these metals and their geographic distributions have also been studied. For all five metals, the residual fraction is highest but the exchangeable fraction is lowest among all the fractions. Compared to other metals, Cd has the highest percentage in the exchangeable fraction, and Cr is associated mainly with the residual fraction. Cu in the organic fraction and Pb in the Fe-Mn fraction are the important species, whereas the lowest percentages are found for Cd in the organic fraction, Cu in the Fe-Mn oxide fraction and Pb in the carbonate fraction. With respect to spatial differences, the total contents in the non-residual fractions of the metals in bay sediments are found to be higher than those in other sediments. The fractions of Cd, Cu and Cr showed significant variations in different regions. The fractions of Pb and Zn, however, did not show significant variations in spatial distribution, suggesting different amounts and different paths of anthropogenic input for the metals. Comparisons of the metal speciation indicated that Cd might be the most bioavailable metal, followed by Pb.     

土壤-水稻系统中重金属元素与其他元素之间的相互作用

通过相关关系的统计分析,探讨了四川省61件水稻籽实及其根系土中重金属元素与其他元素间的相互关系。研究结果表明:①水稻籽实对重金属元素、微量元素、大量元素的富集系数差异很大,元素富集系数之间具有显著的相关性;②水稻籽实中重金属元素的含量与土壤中部分元素的含量之间存在着显著的相关关系;③水稻籽实重金属元素的含量与籽实中其他元素含量之间的相关关系显著。结合元素之间的相互作用对元素地球化学行为的影响,评价了作物籽实中重金属元素的危害程度,为土壤修复提供了新思路。     

强夯引起的振动规律及环境效应分析

强夯法是地基处理的一种常用方法,而强夯施工振动往往是制约强夯法应用的关键。综合国内外的研究成果,重点分析强夯引起的振动规律及振动对环境的影响,并结合某沿海地基处理中的强夯振动工程实例,根据实测结果,分析振动速度随距离的衰减规律及强夯安全距离的确定。     

土壤—农产品系统中重金属含量关系的影响因素分析

针对浙江省主要粮食、油料大宗作物以及蔬菜、茶叶等各类典型经济作物,选择典型种植区开展了农产品及根系土壤调查,根系土壤样测定了土壤有机质、酸碱度及十多种重金属元素含量,农产品样测定了十多种重金属元素含量。采用分类统计、相关分析、含量分布散点图等方法,研究了农产品与土壤中重金属含量关系。结果表明,作物种类是决定农产品重金属含量的最主要因素;农产品与土壤中重金属含量总体上具有共消长的趋势;土壤有机质、pH值是影响作物对土壤重金属吸收累积的重要环境因素;作物样品采集、加工和分析过程中沾污问题可能会对土壤-农产品重金属含量的相关性产生较大影响。     

辽河流域人发中重金属元素分布特征

对辽河流域人发中重金属元素含量分布、分配规律研究结果表明：重金属元素尤其是铅、镉、汞、砷、铬元素，分布规律有很大相同之处，高含量数据点均围绕沈阳、锦州等重工业城市及阜新、柴河铅矿及其下游等地区分布，且城市居民平均含量明显高于乡村居民平均水平。通过进一步对典型污染区的研究发现：人发分布特征与背景环境有很大相关性，即土壤、浅层地下水、作物中重金属含量高的地区，人发中重金属含量亦较高。     

重金属离子在胡敏酸-高岭石复合体上的吸附

本文研究了胡敏酸存在下高岭石对重金属离子的吸附行为。实验结果表明:①胡敏酸和Cu2 溶液按先后顺序或同时加入高岭石中反应,在Cu2 平衡浓度<10mg/L时,3种加入顺序对Cu2 的吸附量基本相同,当Cu2 平衡浓度>10mg/L时,(K Cu) HA和(K Cu HA)两种加入顺序对Cu2 的吸附量比(K HA) Cu的略大。②在pH=5时,胡敏酸-高岭石复合体对Cu2 的吸附量明显大于纯高岭石。这是由于胡敏酸含有大量的羧基和酚羟基等活性基团,吸附在高岭石上的胡敏酸增加了其表面吸附位,在复合体表面形成了S—HA—Cu三元配合物,且Cu2 的吸附量与复合体中胡敏酸的含量在一定范围内成正相关;③溶液pH值在4～7之间变化可调控复合体对Cu2 的吸附机制。④在Cu2 和Cd2 共存时,随着金属离子初始浓度的增大,Cu2 的吸附量呈直线上升,而Cd2 的吸附量增加缓慢,表明复合体对Cu2 的吸附能力比对Cd2 强。     

A coupling of mixed and continuous Galerkin finite element methods for poroelasticity II: the discrete-in-time case

In this paper, we formulate a finite element procedure for approximating the coupled fluid and mechanics in Biot’s consolidation model of poroelasticity. Here, we approximate the pressure by a mixed finite element method and the displacements by a Galerkin method. Theoretical convergence error estimates are derived in a discrete-in-time setting. Of particular interest is the case when the lowest-order Raviart–Thomas approximating space or cell-centered finite differences are used in the mixed formulation and continuous piecewise linear approximations are used for displacements. This approach appears to be the one most frequently applied to existing reservoir engineering simulators.     

A coupling of mixed and continuous Galerkin finite element methods for poroelasticity I: the continuous in time case

In this paper, we formulate a finite element procedure for approximating the coupled fluid and mechanics in Biot’s consolidation model of poroelasticity. Here, we approximate the pressure by a mixed finite element method and the displacements by a Galerkin method. Theoretical convergence error estimates are derived in a continuous in-time setting for a strictly positive constrained specific storage coefficient. Of particular interest is the case when the lowest-order Raviart–Thomas approximating space or cell-centered finite differences are used in the mixed formulation, and continuous piecewise linear approximations are used for displacements. This approach appears to be the one most frequently applied to existing reservoir engineering simulators.     

Heavy clastic minerals from the Far East island-arc complexes

The results of the study of heavy clastic minerals from the Cretaceous-Paleogene terrigenous complexes of Sikhote-Alin and Kamchatka, as well as from the Cenozoic sediments of the deepwater Vanuatu Trench, are summarized. The data obtained have been interpreted on the basis of their comparison with heavy mineral assemblages of recent sediments deposited in known geodynamic settings. It is shown that the heavy clastic minerals of sedimentary rocks, their relative quantities, and chemical compositions may serve as reliable indicators of different island-arc settings and magmatic processes; these indicators may also be used for identification of such settings in paleobasins of orogenic regions.     

非均匀饱和广义湿位涡在暴雨分析与预测中的应用

考虑实际大气非均匀饱和特性, 通过引入广义位温及广义湿位涡方程, 对华北暴雨和江淮梅雨锋暴雨的发生及落区进行了广义湿位涡异常的诊断分析, 表明暴雨形成时大气低层有广义湿位涡的异常出现。对广义湿位涡倾向的计算表明:它对暴雨的发生有一定指示作用, 因而可利用广义湿位涡的异常来识别暴雨的出现。