特征变量选择结合SVM的耕地土壤Hg含量高光谱反演

为探讨应用高光谱数据反演耕地土壤重金属汞(Hg)含量,对原始光谱进行10 nm重采样和SG平滑处理,用不同光谱变换数据与土壤重金属Hg含量进行相关性分析,采用IRIV、Random Frog和PCC提取光谱特征波段,分别建立SVM与GWO-SVM土壤Hg含量高光谱反演模型,获取Hg含量最优反演路径。研究表明,一阶微分变换光谱后土壤光谱特征更明显;上述特征提取方法在不同程度上减少光谱数据冗余,保留有效变量信息;经灰狼算法优化后支持向量机模型反演精度提高,IRIV结合GWO-SVM预测精度更高,其验证集R²为0.894,RMSE为0.082,MAE为0.016。研究成果可为类似土壤重金属含量的反演提供借鉴。     

Mass transport triggered by heavy rainfall: the role of endorheic basins and epikarst in a regional karst aquifer

This study aims at recognizing the mechanisms of mass transport between the karst surface and the saturated zone in a morphostructural relief of the Mesozoic karst carbonate platform of Murgia (Puglia, Southern Italy). The large dimension of the karst aquifer, the regional scale of the flow system, the boundary condition constituted by the sea, and the lack of freshwater springs constrain to the use of wells as monitoring points and limit the study area to the recharge area comprising 986 endorheic basins. The concentrations of non‐reactive tracers (nitrates) in the waters of autogenic recharge (from endorheic basins) have been modeled through the evaluation of effective infiltration, land use, and nitrogen surplus, with reference to a time window, which includes a low precipitation period followed by significant rainfall events. The comparison between the modeled nitrate concentrations and the nitrate concentrations measured in ground waters, coupled with the analysis of groundwater chemograms and records of hydraulic heads (all referred to the same time window), allows inferring the mechanism of mass transport between the karst surface and the groundwater table. The mass transport conceptual model requires the presence of the epikarst. The infiltration of significant rainfall in the endorheic basins after a low precipitation period displaces waters stored in the epikarst toward the saturated zone. Ground waters in the post‐event period show higher concentrations of nitrates, lower concentrations of total organic carbon, and higher Mg/Ca ratios than both those of the pre‐event period and the autumn‐winter recharge period. The post‐event recharge from epikarst storage determines a transient hazard of groundwater pollution with a time lag from the occurrence of the heavy rainfall.     

Origin of sandplains in Western Australia: A review of the debate and some recent findings

Views on the origin of sandplains in Western Australia remain controversial with debate focusing around three different models of formation. These are in situ, aeolian and in situ formation with local remobilisation by wind or colluvial transport. The only recent work on the subject to date espouses a dominantly aeolian origin. New work from a detailed study on the Victoria Plateau is described and demonstrates the applicability of utilising a range of evidence in understanding the origin of sandplains in Western Australia. Field investigations show a strong association of sandplain with sandstone and an absence of sand on non‐arenaceous geology in similar and adjacent topographic settings. Grainsize, mineral magnetic analysis and heavy‐mineral spectra show the Victoria Plateau to be a heterogeneous body of sand. These findings coupled with a lack of internal sedimentary structures are not consistent with an aeolian origin for the sandplain. Furthermore, scanning electron microscopy, grainsize and heavy minerals also demonstrate a clear link between bedrock and overlying sandplain. These data support the hypothesis that Western Australian sandplains are mostly the product of in situ weathering. Such findings question whether the origin of sandplains can be satisfactorily deduced without such a range of data.     

Investigation into the daily precipitation variability in the Yangtze River Delta,China

In this article, by using the daily precipitation data measured at 58 meteorological stations, spatial and temporal variability of daily precipitation including zero rainfall values (called “precipitation”) and without zero rainfall values (called “rain”) and four precipitation extrema (P₀, P₂₀, P₅₀, and P₁₀₀ representing the daily precipitation with the magnitude smaller than 0.1 mm, bigger than 20 mm, 50 mm, and 100 mm per day, respectively) in the Yangtze River Delta (YRD) during 1958–2007 were analyzed, and the effects of urbanization were further investigated. Results indicate that (i) differing from the downward trends in 1958–1985, daily precipitation and rain in 1986–2007 show slowly downward trends in the mid YRD but show upward trends in the northern and southern YRD. (ii) Spatial and temporal variability of the rain is more complex than daily precipitation. Both of them become smaller but show more obvious fluctuations in 1986–2007. (iii) Urbanizations cause not only the urban rainfall island problem but also more obvious fluctuations of rain intensity in the mid YRD, reflecting more uncertainty of daily precipitation variability. (iv) Urbanizations have little effects on the variability of P₀ and P₁₀₀ but cause notable increases of P₂₀ and P₅₀. (v) The spatial variability of daily precipitation and precipitation extrema in 1958–1985 clearly shows a breakpoint at 30°20′N latitude, but the breakpoint disappears afterward because of the effects of urbanization. Copyright © 2012 John Wiley & Sons, Ltd.     

Application of FY-2C Cloud Drift Winds in a Mesoscale Numerical Model

Statistical tests and error analysis of cloud drift winds(CDWs) from the FY-2C satellite were made by using radiosonde observations.According to the error characteristics of the CDW,a bias correction using the thermal wind theory was applied in the data quality control.The CDW data were then assimilated into the GRAPES-meso model via the GRAPES-3DVar.A torrential rain event that occurred in northwestern China during 1-2 July 2005 was simulated.The results indicate that the CDW data were mainly distribute...     

H~+对Cu~(2+)—Me~(2+)二元体系吸附的影响规律研究

土壤对重金属离子的吸附容量严格受H~+浓度的控制。本文通过试验探讨了H~+ 对Cu~(2+)——Pb~(2+),Cn~(2+)——Zu~(2+),Cu~(2+)——Hg~(2+)系统中Cu~(2+)吸附量的影响规律。当pHpH时,Cu~(2+)吸附量随pH值增大而减小。对于酸性土,pH=6.5(初始值)或7.0(平衡值),对碱性土,pH=5.5(初始值)或7.8(平衡值)。在pHpH_(ZPC)时,吸附模式具有完全不同的形式。     

广东省海岸表层沉积物的重矿物特征及其与沉积环境的关系

广东省海岸表层沉积物中的重矿物近40种。含量较高的有钛铁矿、赤矿铁、磁铁矿、话石、电气石、黑云母和普通角闪石等。自生矿物主要为硬石膏、自然铜、黄铁矿及菱铁矿。这些矿物来自附近的母岩。根据物源性质不同,可将不同岸段重矿物区分为陆源矿物组合、近源-自生矿物组合和近源矿物组合三种:除物源控制外,重矿物含量、种类、形态特征及其在平面上的分布主要受沉积环境影响。据此,可将重矿物分布类型划分为河口型、海湾型和海岛型三类,且与上述不同矿物组合性质相对应。     

Wet deposition of excess sulfate at Macquarie Island, 54° S

Annual wet deposition of excess sulfate at Macquarie Island has been estimated from 5 months of rainwater composition data covering the Austral summer of 1985/86. The resulting figure of 2.1±0.6 mmol/m²/yr is at the low end of previous estimates of maritime excess sulfate deposition by precipitation. Within estimated uncertainty limits this figure is consistent with the DMS emission flux which would be predicted for latitude 50°–60° S, based solely on available Northern Hemispheric DMS measurements.Temporarily at the International Meteorological Institute, Stockholm University, S-106 91, Stockholm, Sweden.     

四川省宁南县城后山泥石流激发雨强

根据宁南县城后山垂直剖面观测资料，对本区降雨的垂直变化及泥石流激发雨强作了探讨。当地暴雨泥石流发生所需的１０分钟雨强ｉ＿（１０ｍｉｎ）和前期降水量Ｐａ组合为：：ｉ＿（１０ｍｉｎ）≥１５ｍｍ∩Ｐａ≥５０ｍｍ，或ｉ＿（ｍｉｎ）≥１０ｍｍ∩Ｐａ≥６５ｍｍ，或ｉ＿（１０ｍｉｎ）≥５ｍｍ∩Ｐａ≥９０ｍｍ。超过上述各组合值就有可能暴发泥石流。     

多沙河流造床流量研究

在综述和分析前人有关造床流量研究成果的基础上,根据多沙河流的特点,提出了一种适用于多沙河流造床流量计算的水沙综合频率法.通过黄河、永定河水沙资料的分析,结果比较合理.