南黄海和东海北部陆架重矿物组合分区及来源

利用大洋-50型海底取样器,在南黄海和东海北部陆架(125°E以西)海上调查获取了海底表层沉积物样品,其中包括1998年以来"黄东海地质地球物理补充调查"和"中韩黄海沉积动力学与古环境演变"2项研究所获得的样品共380个,选取0.063～0.125mm粒级的沉积物,进行碎屑矿物分析,最后选出9个代表性的优势重矿物种的数据为变量,利用Q型聚类(分层聚类)的数学方法,进行聚类组合,在数学统计的基础上,将研究区划分出4个重矿物组合区。客观地反映出黄河物质、长江物质和原地物质的影响范围,同时也体现出物质来源和水动力以及海底风化作用对重矿物分布的影响程度和范围,因而可以得出,在一定的范围内陆架表层沉积物中的重矿物具有趋同的演化效应。     

西江河口重金属迁移扩散数值模拟的研究

本文以水体中重金属(包括溶解态和颗粒态)的物理迁移过程为基础,建立重金属迁移扩散的数学模式。模式中考虑悬浮物沉降和再悬浮对水体中重金属浓度的影响,并考虑咸潮活动引起悬浮物的絮凝沉淀作用。计算结果表明,这种潮汐河口区重金属迁移扩散模式基本上是成功的。并以镉为例,说明重金属在西江河口区迁移扩散的特点。     

海洋沉积物重金属生态风险评价方法比较及实例验证——以莱州湾为例

利用2016年8月份莱州湾沉积物中Hg、Cd、Pb、Cu、As、Cr、Zn监测数据,分别利用单因子污染指数法、潜在生态风险指数法、地积累指数法、沉积物质量基准法、尼梅罗综合指数法、污染负荷指数法等6种沉积物重金属风险评价方法进行评价,以比较沉积物重金属生态风险评估方法的适用性与局限性。结果表明,莱州湾表层沉积物中,重金属Hg、Cd、Pb、Cu、As、Cr和Zn含量分别为0.077 4 mg/kg、0.169 mg/kg、12.1 mg/kg、11.9 mg/kg、11.6 mg/kg、31.1 mg/kg、45.3 mg/kg。不同方法在莱州湾沉积物风险评价结果上存在差异。单因素评价方法中,单因子污染指数法、潜在生态危害指数法、尼梅罗综合指数法的评价结果适中,地累积指数法评价结果偏轻,沉积物质量基准法评价结果偏重。Hg、As、Cd元素的污染评价结果均较大,为主要的污染元素;综合因素评价方法中,污染负荷指数法评价结果风险偏轻,潜在生态危害指数法评价结果适中,内梅罗综合指数法评价结果则倾向偏重。沉积物重金属含量与底栖生物的丰度、生物量的pearson相关系数表明,Hg与底栖生物的生物量呈现显著负相关。6种方法都有自身优缺点和适用范围,但潜在生态危害指数法更适合莱州湾沉积物重金属风险评价。     

Environmental impact of fluidized solidified silt casting on surrounding water bodies

Abstract

With the growing demand for underwater refill engineering, the construction technology of implementing fluidized solidification in underwater pouring has recently received increased attention. However, the environmental impact of underwater casting on surrounding water bodies, especially when the silt is polluted, is still unclear. In this study, a simulated underwater pouring test and a static immersion release test were conducted separately to study the quality of the surrounding water during and after pouring. The results showed that fluidized-solidified silt casting could increase the pH of the surrounding water, even after the pouring had stopped, by approximately 1.0 and the turbidity could reach 200 NTU. No diffusion of Zn and Cu into the surrounding water was observed and while Ni and Cr exhibited slight diffusion, this was at a level well below international water quality standard. During construction, reducing the distance from the seafloor to the bottom of the pouring catheter could reduce the level of pollution. After construction, the use of neutral solidified materials can effectively reduce the pH of the surrounding water and the potential risk of heavy metal dissolution.     

灌河口潮滩重金属累积特征及污染评价

河口地区潮滩是重金属重要的"汇"。测定了灌河口(燕尾港)潮滩高中低滩的33个表面样粒度、重金属数据,研究了4根柱状样的重金属和粒度特征,利用地累积指数法、潜在生态危害指数法及富集指数法等评价指标,对灌河口重金属的污染状况进行了评价,并对其结果进行了相互比较和印证。分析结果显示,灌河口潮滩重金属的分布主要受水动力影响,特别是受粘土分布的控制。Cd与粒径Ф值相关性不显著,相关系数只有0.099,而与粘土含量呈明显正相关关系,Hg的变化趋势恰恰相反,其含量随着距离河口距离的加大反而有增加的趋势;其他元素的变化趋势不明显。重金属元素Zn、Pb、Cu、Hg含量变化走势基本相同,用Li作归一化标准元素归一化后,所有重金属元素的归一化值变化波动范围均比重金属含量值明显收窄,波峰和波谷有后延的趋势。灌河口滩涂总体重金属环境尚可,但存在一定程度的Hg、Cu污染富集。柱状样Hg、Cu的地累积污染指数总体上均呈现随深度增加而降低的趋势。     

土壤剖面的磁学特征及其对交通污染的指示意义——以北京首都机场高速公路为例

对北京首都机场高速公路旁采集的土壤柱状T01剖面的磁学参数和金属元素分析,探讨了研究区内现代交通导致的土壤磁学性质的变化及其对环境污染的响应.结果表明,磁参数(χ,ARM和SIRM)与重金属含量呈同步垂向变化趋势.来源于交通运输排放的污染物是土壤剖面上部(0～8 cm)磁性和金属含量增强的主要原因,8cm以下,土壤基本未受到污染,磁性矿物和重金属含量较低,磁性颗粒变化稳定,基本代表了该地区土壤的自然背景.尽管土壤岩石磁学分析表明剖面上下部受污染和未受污染样品的磁载体均是粒度较粗的多畴磁铁矿,但是结合磁参数比值曲线,说明底部样品的磁颗粒的粒度较顶部偏细.磁性矿物的含量变化没有影响磁颗粒的粒度特征.指标聚类等相关分析表明,土壤磁参数(χ,ARM和SIRM)与重金属元素(Pb,Zn和Cu)含量显著相关;结合模糊聚类分析,磁参数可用于追踪、识别交通污染物质在土壤剖面中的富集、迁移状态,揭示不同深度土壤的污染程度.     

Conversion of kinetic energy from synoptic scale disturbance to low-frequency fluctuation over the Yangtze River valley in the summers of 1997 and 1999

In order to investigate the conversion of kinetic energy from a synoptic scale disturbance （SSD; period≤seven days） to a low-frequency fluctuation （LFF; period〉seven days）, the budget equation of the LFF kinetic energy is derived. The energy conversion is then calculated and analyzed for the summers of 1997 and 1999. The results show that the energy conversion from the SSD to the LFF is obviously enhanced in the middle and lower troposphere during the heavy rainfall, suggesting this to be one of mechanisms inducing the heavy rainfall, although the local LFF kinetic energy may not be enhanced.     

Impact of 4DVAR assimilation of rainfall data on the simulation of mesoscale precipitation systems in a mei-yu heavy rainfall event

The multi-scale weather systems associated with a mei-yu front and the corresponding heavy precipitation during a particular heavy rainfall event that occurred on 4 5 July 2003 in east China were successfully simulated through rainfall assimilation using the PSU/NCAR non-hydrostatic, mesoscale, numerical model （MM5） and its four-dimensional, variational, data assimilation （4DVAR） system. For this case, the improvement of the process via the 4DVAR rainfall assimilation into the simulation of mesoscale precipitation systems is investigated. With the rainfall assimilation, the convection is triggered at the right location and time, and the evolution and spatial distribution of the mesoscale convective systems （MCSs） are also more correctly simulated. Through the interactions between MCSs and the weather systems at different scales, including the low-level jet and mei-yu front, the simulation of the entire mei-yu weather system is significantly improved, both during the data assimilation window and the subsequent 12-h period. The results suggest that the rainfall assimilation first provides positive impact at the convective scale and the influences are then propagated upscale to the meso- and sub-synoptic scales.
Through a set of sensitive experiments designed to evaluate the impact of different initial variables on the simulation of mei-yu heavy rainfall, it was found that the moisture field and meridional wind had the strongest effect during the convection initialization stage, however, after the convection was fully triggered, all of the variables at the initial condition seemed to have comparable importance.     

珠穆朗玛峰地区雪冰中重金属浓度与季节变化

对2005 年9 月采自珠穆朗玛峰北坡海拔6523 m 的东绒布冰川积累区一批雪坑样品中重金属Ba, Co, Cu, Zn 和Pb 的浓度利用电感耦合等离子体质谱仪进行了测试, 重金属浓度范围分别为(pg/ml); Ba2~227、Co2.8~15.7、Cu 10~120、Zn29~4948、Pb14~142。并利用气体稳 定同位素质谱仪MAT-252 对样品稳定氧同位素比率(δ¹⁸O) 进行了测试, 雪坑样品对应的时间为2004 年夏到2005 年秋, δ¹⁸O和重金属元素的浓度都存在着季节变化特征。在夏季风期间δ¹⁸O 值和重金属元素的浓度都很低,而在非夏季风期间δ¹⁸O值和重金属元素浓度升高,反映了不同的水汽来源对重金属浓度季节变化的影响及其环境意义。Co, Cu, Pb, Zn 的地壳富集系数(EF_c) 分别为: 3.6、27、33、180, 表明该地区Pb, Cu, Zn 已经受到了人类活动的污染, 其中Zn 受到的污染最大。     

东海陆扰海域铜、铅、锌、镉重金属排海通量及海洋环境容量估算

汇总并分析了20世纪80年代初以来东海陆扰海域重金属排海通量年变化规律及主要来源,应用多介质海洋环境中重金属迁移-转化模型,估算了东海陆扰海域重金属海洋环境容量。20世纪80年代初以来,东海陆扰海域铜、铅、锌、镉排海总量整体上呈不对称的倒"U"形变化趋势,基本符合"环境库兹涅茨曲线",20世纪90年代达到最大值,当前排海总量仍高于20世纪80年代初期的水平。东海陆扰海域铜、铅、锌、镉污染物主要来源于以河流为主的陆源排放,其中88.0%左右来源于河流排放,7.5%左右来源于排污口,只有4.5%左右来源于大气沉降。长江流域排海通量占东海陆扰海域排海总量的比例最大,平均为92.4%左右,钱塘江流域平均只有3.9%左右,闽江流域平均只有3.7%左右。东海陆扰海域铜、铅、锌、镉污染物海洋环境容量分别约为17.0,4.7,113.1,0.71 kt/a。当前铅、锌、镉污染物排海总量没有超过东海陆扰海域海洋环境容量,但铜的排海总量超过其海洋环境容量大约8%。