鄂尔多斯盆地中西部深部流体活动及其对奥陶系天然气形成的热作用

鄂尔多斯是一个非常稳定的克拉通盆地,深部流体一直被认为是禁区。通过构造学、火成岩岩石学、矿物学、同位素以及热史分析等方法,首次系统证实了鄂尔多斯盆地中西部发生过强烈的深部流体活动,并分析了其形成机制和对奥陶系天然气形成的热演化作用。在中生代晚期,祁连构造域的挤压作用导致盆地西缘发生强烈逆冲推覆、断裂活动及三次大规模的深部流体上涌。这些流体在构造应力作用下主要沿J/T、O/C不整合面运移至盆地中部。流体携带了大量深部热能,使奥陶系上部古地温升高约50℃,并将其中的碳酸盐岩生烃速度提高了至少32倍。最终,深部流体一方面导致奥陶系生烃量显著增加,另一方面也降低了天然气的散失,有助于其聚集成藏。深部流体使鄂尔多斯盆地中西部奥陶系天然气成因复杂化,另外它对深入探索铀和其它金属矿床的形成及盆地演化也具有重要意义。     

青藏高原地面加热场强度变化及其与太阳活动的关系

利用1958—2006年日喀则和玉树观测的历年各月平均地面(0 cm)温度和气温(百叶箱)资料,采用新量纲重新计算并续补了48年的青藏高原地面加热场强度距平指数。结果表明,青藏高原地面加热场强度存在后延1~2个月的显著相关,干季具有较好的持续性。除存在明显的年际和年代际变化特征外,总体表现出春、夏季由弱变强,秋、冬季由强变弱,且具有稳定而显著的准11年和17年周期。持续的太阳黑子数偏少对青藏高原地面加热场强度的增强具有明显的指示性;太阳黑子周期长度(SCL)变长(太阳活动减弱)时,青藏高原地面加热场强度减弱。通过初步分析认为,太阳活动是引起青藏高原地面加热场强度变化的重要原因之一。     

微波照射下火成岩升温特性和升温预测模型研究

微波辅助破岩可有效降低刀具磨损,提高破岩效率,具有广阔的发展前景.文章选取了10种火成岩进行微波加热试验,发现岩石的升温速率主要与岩石所含矿物的种类、含量,及岩石中的Fe元素含量有关.岩石所含矿物越敏感、含量越多,岩石中的Fe元素含量越大时,其升温速率越高.整体而言,火成岩中基性岩的升温速率最高、中性岩次之、酸性岩最低...     

秦岭—淮河南北供暖格局变化及其影响因素

基于秦岭—淮河南北及其周边196个气象站点观测资料,构建实际和动态供暖指数,对中国南北过渡带供暖格局变化进行分析,并探讨冬季北极涛动（AO）异常与供暖效率的响应关系。结果表明：① 固定供暖策略下,1960-2016年秦岭—淮河南北实际供暖能耗偏高,呈现“南多北少,西低东高”的变化特征,且低纬度地区供暖需求下降信号早于高纬度;② 对比区域变暖前后,秦岭—淮河南北冬季供暖能耗1960-1990年和1990-2016年两阶段空间特征,发现“整体南高北低,北部东高西低”的格局并未发生变化,供暖南北波动界线依然维持在秦岭山脉—淮河平原中部;③ AO强弱波动与区域冬季供暖能耗具有明显的时空响应关系,是影响中国南北过渡带供暖格局变化的重要因素。当AO负相位时,除四川盆地和巫山山区之外,秦岭—淮河南北其他区域实际供暖能耗明显下降,特别是淮河平原和长江下游的过渡地带响应尤为明显,未来应该有针对性制定气候适应对策。     

Pricing Weather Derivatives Index based on Temperature: The Case of Bahir Dar,Ethiopia

In this paper we present a stochastic model for daily average temperature to calculate the temperature indices upon which temperature-based derivatives are written. We propose a seasonal mean and volatility model that describes the daily average temperature behavior using the mean-reverting Ornstein-Uhlenbeck process. We also use higher order continuous-time autoregressive process with lag 3 for modeling the time evolution of the temperatures after removing trend and seasonality. Our model is fitted to 11 years of data recorded, in the period 1 January 2005 to 31 December 2015, Bahir Dar, Ethiopia, obtained from Ethiopia National Meteorological Services Agency. The analytical approximation formulas are used to price heating degree days (HDD) and cooling degree days (CDD) futures. The suggested model is analytically tractable for derivation of explicit prices for CDD and HDD futures and option. The price of the CDD future is calculated, using analytical approximation formulas. Numerical examples are presented to indicate the accuracy of the method. The results show that our model performs better to predict CDD indices.     

臭氧及臭氧类高级氧化技术降解甲基对硫磷的效能

文章研究了臭氧及臭氧类高级氧化技术(AOPs-O3)在不同pH条件下降解甲基对硫磷(MP)的效能。结果表明,在pH 3~10的条件下(反应过程控制pH),单独臭氧化5min即可完全降解MP,但不同pH下化学耗氧量(COD)和有机磷的释放率差异明显。在pH为3.3,7.5和9.4的条件下单独臭氧30min后COD的去除率分别为55.17%,89.64%和93.10%,有机磷的释放率分别为16.33%,95.00%和99.99%。考虑酸性条件下可以规避碳酸盐的负面影响(特别是高浓度废水),利用O3/H2O2/Ti(IV)在pH 3.3条件下处理MP溶液,COD去除率和有机磷释放率分别达到89.64%和81.57%。相对法计算求得MP与O3和羟基自由基(·OH)的速率常数分别为31.98L·(mol·s)-1和7.488×109 L·(mol·s)-1。活性污泥法的测试结果表明,MP经O3/Ti(IV)/H2O2(pH=3.3)和O3(pH=9.4)可提升含MP废水的可生化性,但与培养液体系相比仍具有一定的毒性。     

Effects of the seasonal variation in chlorophyll concentration on sea surface temperature in the global ocean

The effects of biological heating on the upper-ocean temperature of the global ocean are investigated using two ocean-only experiments forced by prescribed atmospheric fields during 1990–2007, on with fixed constant chlorophyll concentration, and the other with seasonally varying chlorophyll concentration. Although the existence of high chlorophyll concentrations can trap solar radiation in the upper layer and warm the surface, cooling sea surface temperature (SST) can be seen in some regions and seasons. Seventeen regions are selected and classified according to their dynamic processes, and the cooling mechanisms are investigated through heat budget analysis. The chlorophyll-induced SST variation is dependent on the variation in chlorophyll concentration and net surface heat flux and on such dynamic ocean processes as mixing, upwelling and advection. The mixed layer depth is also an important factor determining the effect. The chlorophyll-induced SST warming appears in most regions during the local spring to autumn when the mixed layer is shallow, e.g., low latitudes without upwelling and the mid-latitudes. Chlorophyll-induced SST cooling appears in regions experiencing strong upwelling, e.g., the western Arabian Sea, west coast of North Africa, South Africa and South America, the eastern tropical Pacific Ocean and the Atlantic Ocean, and strong mixing (with deep mixed layer depth), e.g., the mid-latitudes in winter.     

Finite element modeling of heating phenomena of cracks excited by high-intensity ultrasonic pulses

A three-dimensional thermo-mechanical coupled finite element model is built up to simulate the phenomena of dynamical contact and frictional heating of crack faces when the plate containing the crack is excited by high-intensity ultrasonic pulses. In the finite element model, the high-power ultrasonic transducer is modeled by using a piezoelectric thermal-analogy method, and the dynamical interaction between both crack faces is modeled using a contact-impact theory. In the simulations, the frictional heating taking place at the crack faces is quantitatively calculated by using finite element thermal-structural coupling analysis, especially, the influences of acoustic chaos to plate vibration and crack heating are calculated and analysed in detail. Meanwhile, the related ultrasonic infrared images are also obtained experimentally, and the theoretical simulation results are in agreement with that of the experiments. The results show that, by using the theoretical method, a good simulation of dynamic interaction and friction heating process of the crack faces under non-chaotic or chaotic sound excitation can be obtained.     

那曲高寒草地总体输送系数及地面热源特征

利用中国科学院那曲高寒气候环境观测研究站那曲/BJ观测点的野外观测数据,估算了青藏高原那曲地区典型高寒草地下垫面的热量和水汽总体输送系数以及地表大气相对湿度因子,在此基础上利用中国气象局那曲气象站1980-2016年的常规业务观测数据,采用总体输送法计算并分析了那曲高寒草地地表通量特征。研究结果表明:(1)那曲/BJ观测点地表大气相对湿度因子γ的数值在33%~62%,9月最大,2月最小,热量和水汽输送系数CH和Cλ的季节变化范围分别在1.6×10^-3~2.7×10^-3和1.0×10^-3~2.0×10^-3,两者存在较大的差异。(2)1980-2016年那曲高寒草地感热通量总体呈现减弱趋势,而潜热通量呈现增强趋势,导致地面热源变化趋势不明显;分阶段来看,感热通量的变化在2004年前后发生转折,转折点前后的趋势为先减弱后增加,潜热通量在1994-2005年下降趋势明显,这也导致地面热源在1995-2005年有一个明显的减少。(3)年内季节变化上潜热通量相较于感热通量更明显,地面热源的季节变化更依赖于潜热通量的季节变化。     

Chromium(VI) reduction by sulphur(IV) in aqueous solutions

The rates of the reduction of Cr(VI) with S(IV) were measured in deaerated NaCl solution as a function of pH, temperature and ionic strength. The rates of the reaction were found to be first order with respect to Cr(VI) and second order with respect to S(IV), in agreement with previous results obtained at concentrations two order higher than the present study. The reaction also showed a first-order dependence of the rates on the concentration of the proton and a small influence of temperature with an apparent energy of activation ΔH_app of 22.8 ± 3.4 kJ/mol. The rates were independent of ionic strength from 0.01 to 1 M. The rate of Cr(VI) reduction is described by the general expression

−d[Cr(VI)]/dt=k[Cr(VI)][S(IV)]²