陕西渭北东部岩溶水环境同位素

陕西渭北东部岩溶水系统是一个复杂的地下水系统，碳酸盐岩大面积隐伏与深埋。使用传统手段和方法勘查岩溶地下水和研究可持续开发利用方案遇到诸多困难，不仅费时，而且耗资大。本文通过系统分析研究陕西渭北东部地区岩溶地下水T、D、^180、^14C环境同位素特征，揭示岩溶水的补给迳流排泄条件、岩溶水系统边界性质以及岩溶水与黄河洛河地表水、黄河岩溶泉与洛河岩溶泉之间的补排关系。结果显示环境同位素方法简便有效，能够达到预期目的。     

干旱区内陆河流域水文与水资源问题

阐述了我国水文水资源研究的发展阶段,面临的主要问题,以及当前研究中的热点问题。以新疆地区为例,对干旱区内陆河流域的水文水资源研究方向作了初步探讨。     

高效液相色谱-离子阱质谱法测定海洋微藻藻粉中的8种脂溶性毒素

建立了利用高效液相色谱-电喷雾离子阱质谱(HPLC-ESI-IT-MS)测定海洋微藻藻粉中8种典型脂溶性毒素的分析方法。藻粉样品经超声细胞破碎后,采用超声波辅助提取法对藻毒素进行提取,用HPLC-ESI-IT-MS多反应离子监测(MRM)模式对各种毒素(包括大田软海绵酸(OA)、鳍藻毒素1(DTX-1)、扇贝毒素2(PTX-2)、虾夷扇贝毒素(YTX)、原多甲藻酸1(AZA1)原多甲藻酸2(AZA2)、罗环内酯毒素(SPX),米氏裸甲藻毒素(GYM))进行测定。8种脂溶性藻毒素均在线性范围内线性关系良好(R2均在0.991以上),检出限均介于0.085～1.315 pg之间,加标回收率在88.5%～111.4%之间,方法重复性相对标准偏差(RSD)在4.82%～10.17%范围。应用该方法对利玛原甲藻干藻粉中的毒素进行了测定,分析结果良好,说明本方法是海洋微藻藻粉中脂溶性藻毒素测定的有效方法。     

黄河流域水循环演变若干问题的研究

从若干方面的研究结果揭示了黄河流域水循环发生的巨大变化.水循环是水资源科学评价与合理开发利用的基本依据.水循环主要要素的变化取决于气候条件的变化与人类活动的影响.对前者宜采用适应性对策,在研究气候变化的基础上,分析水循环变动的规律并预测其趋势,制定相应的适应性措施;对于后者则应加强水资源开发利用的科学管理,以维持流域天然水资源的可更新(可再生)性.     

Water and nutrient fluxes in a cool temperate rainforest at the Cordillera de la Costa in southern Chile

Water and nutrient fluxes were studied during a 12-month period in an alerce (Fitzroya cupressoides) forest, located in a remote site at the Cordillera de la Costa (40°05′S) in southern Chile. Measurements of precipitation, throughfall, stemflow, effective precipitation, soil infiltration and stream flow were carried out in an experimental, small watershed. Simultaneously, monthly water samples were collected to determine the concentrations and transport of organic-N, NO₃-N, total-P, K⁺, Ca²⁺, Na⁺ and Mg²⁺ in all levels of forest. Concentration of organic-N, NO₃-N, total-P and K⁺ showed a clear pattern of enrichment in the throughfall, stemflow, effective precipitation and soil infiltration. For Ca²⁺ and Mg²⁺, enrichment was observed in the effective precipitation, soil infiltration and stream flow. Annual transport of K⁺, Na⁺, Ca²⁺ and Mg²⁺ showed that the amounts exported from the forest via stream flow (K⁺=0·95, Na⁺=32·44, Ca²⁺=8·76 and Mg²⁺=7·16 kg ha⁻¹ yr⁻¹) are less than the inputs via precipitation (K⁺=6·39, Na⁺=40·99, Ca²⁺=15·13 and Mg²⁺=7·61 kg ha⁻¹ yr⁻¹). The amounts of organic-N and NO₃-N exported via stream flow (organic-N=1·04 and No₃-N=3·06 kg ha⁻¹ yr⁻¹) were relatively small; however, they represented greater amounts than the inputs via precipitation (organic-N=0·74 and NO₃-N=0·97 kg ha⁻¹ yr⁻¹), because of the great contribution of this element in the superficial soil horizon, where the processes of decomposition of organic material, mineralization and immobilization of the nutrients occurs. © 1998 John Wiley & Sons, Ltd.     

张掖市水资源实物型投入产出表的编制应用

实物型投入产出模型更适合用于核算与量化分析经济系统与资源环境间直接及间接的耦合关联。采用Helga Weisz的方法,通过价值型向实物型表转换,编制完成张掖市实物型投入产出表。基于实物型投入产出模型,对张掖市各部门水资源利用在社会经济系统中迁移特点和部门关联程度及乘数进行分析。结果表明：实物表为我们提供了新的分析视角,此方法的应用在资源环境领域的应用具有相当的适用价值。间接需求对水资源影响不容忽视,每个部门的乘数作用很大程度影响该部门在虚拟水战略中的地位和作用。畜牧业、制造业、建筑业在张掖市水资源利用部门关联中作用突出,应作为水资源的社会化管理重点关注的部门。     

上杭县铁东水库铁锰超标的地球化学作用机理及防治建议

在野外调查及采样分析的基础上,通过综合研究已有资料,对上杭县旧县镇铁东水库中的铁锰质超标原因进行了分析,认为水库中由于残留的有机质与库区内软锰矿层、黄铁矿化岩石在水介质的参与下,发生氧化-还原反应和酸碱反应等一系列现代地球化学作用,形成了一个酸性递增、铁锰离子加快析出的递进的地球化学过程,从而导致水库水中铁锰质超标。     

节水钻探系统井下工况判断水力模型

节水钻探是基于解决干旱地区和漏失地层钻探严重缺水问题而发展起来的一项最新技术,其通过实现钻井液的孔底局部循环,使钻进过程中的用水量降为原来的5%～20%。节水钻探系统在使用过程中,由于孔内不返水,在地表只能通过观察压力表的变化量来判断孔内工况,精度不高。通过研究,最终解决通过地表压力变化值来判断孔内工作情况的量化问题,建立初步理论模型,从而更加准确地判断孔内的工况,使这套钻具更快地应用到实际工程中。     

The Role of Seal and Source Rocks in Fluid-rock Interactions and their Reservoir Effects within the Carbonate Deep Burial Realm

Discoveries of deep high-quality carbonate reservoirs challenged the general understanding on the evolution of porosity decreasing with depth. New mechanisms of pore generation and preservation in the deep realm require to be proposed. Dolostones in the Feixianguan and Dengying Formations experienced maximum depths in excess of 8000 m, but still retained high porosity. Petrographic observation and homogenization temperatures help to identify products of deep fluid-rock interactions, visual and experimental porosity were used to quantify reservoir effects, the distribution of products finally being plotted to unravel the mechanisms. Th data reveal that thermochemical sulfate reduction (TSR), burial dissolution and quartz cementation are typical deep fluid-rock interactions. The SO42? of residual porewater sourced from the evaporative dolomitizing fluid was supplied for TSR in the hydrocarbon column, the TSR-inducing calcite cements were homogeneously dispersed in the hydrocarbon column. Quartz cementation was caused by the increasing acidity and Si-rich residual porewater in the oil column. Burial dissolution is forced by organic acid and limited in oil–water contact. This study suggests that seal and source rocks not only play important roles in hydrocarbon accumulation, but also have a general control on the deep fluid-rock interactions and porosity evolution in the deep burial realm.     

高密度电阻率法在咸水入侵监测中的应用

应用高密度电阻率法测量手段,结合水质调查取样,对山东寿光市咸水入侵过渡带的基本特征进行了研究。通过对典型高密度电阻率法测量剖面的视电阻率进行分析,初步确定10 Ω;m作为该区域咸淡水分界线的视电阻率指示值,并初步推断了咸淡水过渡带的咸水区、咸淡水过渡区及淡水区的位置。结果表明高密度电阻率法具有高效、省时、成本低等优点,可以配合其他方法,作为大范围咸水入侵监测的有效手段。