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41.
碱消解-高效液相色谱-电感耦合等离子体质谱法测定生物样品中的甲基汞和乙基汞 总被引:7,自引:2,他引:5
建立了碱消解-高效液相色谱-电感耦合等离子体质谱联用系统测定生物样品中甲基汞(MeHg)与乙基汞(EtHg)的分析方法。为提高灵敏度,选用微流量的PFA雾化器,在优化的检测条件下,MeHg及EtHg检出限可达到0.036μg/L和0.03μg/L;线性范围达到4个数量级,两条工作曲线线性相关系数为1。对1.78μg/L MeHg、1.65μg/L EtHg的混合标准溶液重复测定7次,色谱峰面积的相对标准偏差(RSD)分别为1.79%和1.44%。对标准物质BCR 464(金枪鱼)的分析结果表明,测定值与标准值基本吻合,但略低于标准值;甲基汞和乙基汞的加标回收率分别为85.9%和84.5%。高效液相色谱与质谱联用技术的高灵敏度和低检出限能够满足生物样品中汞形态定量分析的要求。 相似文献
42.
Response of groundwater chemistry to water deliveries in the lower reaches of Tarim River,Northwest China 总被引:2,自引:0,他引:2
Yongjin Chen Kefa Zhou Yaning Chen Weihong Li Jiazhen Liu Tao Wang 《Environmental Geology》2008,53(6):1365-1373
In this paper, we analysed the monitored data from nine groundwater-monitoring transects in the lower reaches of Tarim River
during the five times of stream water deliveries to the river transect where the stream flow ceased. The results showed that
the groundwater depth in the lower reaches of Tarim River rose from −9.30 m before the conveyances to −8.17 and −6.50 m after
the first and second conveyances, −5.81 and −6.00 m after the third and fourth the conveyance, and −4.73 m after the fifth.
The horizontal extent of groundwater recharge was gradually enlarged along both sides of the channel of conveyance, i.e.,
from 250 m in width after the first conveyance to 1,050 m away from the channel after the fourth delivery. With the rising
groundwater level, the concentrations of major anions Cl−, SO42− and cations Ca2+, Mg2+, Na+, as well as total dissolved solids (TDS) in groundwater underwent a significant change. The spatial variations in groundwater
chemistry indicated that the groundwater chemistry at the transect near Daxihaizi Reservoir changed earlier than that farther
from it. In the same transect, the chemical variations were earlier in the monitoring well close to watercourse than that
farther away from the stream. In general, the concentration of the major ions and TDS at each monitoring well increased remarkably
when the water delivery started, and decreased with the continued water delivery, and then increased once again at the end
of the study period. Hence, the whole study period may be divided into three stages: the initial stage, the intermediate stage
and the later stage. According to the three stages of groundwater chemistry reaction to water delivery and the relationships
between groundwater chemical properties and groundwater depths, we educe that under the situation of water delivery, the optimum
groundwater depth in the lower reaches of the Tarim River should be −5 m. 相似文献
43.
A modified DRASTIC model for Siting Confined Animal Feeding Operations in Williams County,Ohio, USA 总被引:1,自引:0,他引:1
Three of DRASTIC’s parameters (Depth to Water, Soil Media, and Topography) were modified and another parameter was added (land
use/land cover) to the model to determine the potential impact on groundwater from Confined Animal Feeding Operations (CAFO)
manure lagoon settings and manure application as fertilizer. Williams County is a mostly agricultural county located in northwest
Ohio, USA. It currently has three CAFOs, all dairy, with the possibility of the construction of a multi-million chicken egg
CAFO in the near future. A Geographic Information System (GIS) was utilized to modify the Ohio Department of Natural Resources
(ODNR) DRASTIC map for the county to fully assess the county-wide pollution potential of CAFOs. The CAFO DRASTIC map indicates
that almost half of Williams County has elevated groundwater pollution potential. The rest of the county, primarily the southeast
corner, has lower CAFO groundwater pollution potential. Future CAFO development within the county should focus on the southeastern
portion of the county where the groundwater table is deeper, and the aquifer is composed of shale substrate with low hydraulic
conductivity. The CAFO DRASTIC results are intended to be used as a screening tool and are not to replace site-specific hydrogeologic
investigations. 相似文献
44.
Thomas B. Boving Mark H. Stolt Janelle Augenstern Brian Brosnan 《Environmental Geology》2008,55(3):571-582
The control of polluted surface runoff and the assessment of possible impacts on groundwater is a concern at the local and
regional scale. On this background, a study investigates possible impacts of organic and inorganic pollutants (including bacteria)
originating from a permeable asphalt parking lot on the water quality immediately beneath it. The functioning of the permeable
pavement, including clogging and restricted vertical percolation, was also evaluated. Four nested sample ports (shallow and
deep) were installed below low- and high-traffic areas, including one port outside the parking lot. At least initially there
was a good hydraulic connection between the parking surface and the shallow sample ports. The presence of a geotextile layer
at the base of the parking lot structure, however, was identified in lab tests as one factor restricting vertical percolation
to the deeper ports. Clogging of the permeable surface was most pronounced in heavy traffic areas and below snow pile storage
areas. Corroborated by high electric conductivity and chloride measurements, sand brought in by cars during winter was the
principal cause for clogging. No bacteria or BOD were found in percolating water. Polycyclic aromatic hydrocarbons (PAH) were
present at concentrations near minimum detection limit. Nutrients (nitrate and phosphate) were being leached into the ground
via the permeable parking lot surface at annual flux rates of 0.45–0.84 g/m2/year. A multi-species tracer test demonstrated a retention capacity of the permeable parking lot structure of >90% for metals
and 27% for nutrients, respectively. 相似文献
45.
Concentrations of trace elements and heavy metals (Al, As, Ba, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sb, Se, Sr, V and Zn) in
the Danjiangkou Reservoir, the water source area of the Middle Route of China’s interbasin South to North Water Transfer Project,
were analyzed using an Inductively Coupled Plasma Atomic Emission Spectrometer (ICP-AES) and compared with the national and
international standards for drinking water. The results indicated that concentrations of As, Pb, Sb and Se in the Reservoir
exceeded the standards and they would pose health risk for residents in the region and the water receiving areas of the interbasin
water transfer project. Spatial and temporal variability of the trace elements and heavy metals in the Reservoir implies their
mixed sources of natural processing and anthropogenic activities in the upper drainage of the Reservoir. The research results
would help develop water resource management and conservation strategy for the interbasin water transfer project. 相似文献
46.
M. I. Holloway F. Bussy T. W. Vennemann 《Contributions to Mineralogy and Petrology》2008,155(1):111-121
Migmatites produced by low-pressure anatexis of basic dykes are found in a contact metamorphic aureole around a pyroxenite–gabbro
intrusion (PX2), on Fuerteventura. Dykes outside and inside the aureole record interaction with meteoric water, with low or
negative δ18O whole-rock values (+0.2 to −3.4‰), decreasing towards the contact. Recrystallised plagioclase, diopside, biotite and oxides,
from within the aureole, show a similar evolution with lowest δ18O values (−2.8, −4.2, −4.4 and −7.6‰, respectively) in the migmatite zone, close to the intrusion. Relict clinopyroxene phenocrysts
preserved in all dykes, retain typically magmatic δ18O values up to the anatectic zone, where the values are lower and more heterogeneous. Low δ18O values, decreasing towards the intrusion, can be ascribed to the advection of meteoric water during magma emplacement, with
increasing fluid/rock ratios (higher dyke intensities towards the intrusion acting as fluid-pathways) and higher temperatures
promoting increasing exchange during recrystallisation.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
47.
Almeev Renat; Holtz Francois; Koepke Jurgen; Haase Karsten; Devey Colin 《Journal of Petrology》2008,49(1):25-45
Phase equilibria simulations were performed on naturally quenchedbasaltic glasses to determine crystallization conditions priorto eruption of magmas at the Mid-Atlantic Ridge (MAR) east ofAscension Island (7–11°S). The results indicate thatmid-ocean ridge basalt (MORB) magmas beneath different segmentsof the MAR have crystallized over a wide range of pressures(100–900 MPa). However, each segment seems to have a specificcrystallization history. Nearly isobaric crystallization conditions(100–300 MPa) were obtained for the geochemically enrichedMORB magmas of the central segments, whereas normal (N)-MORBmagmas of the bounding segments are characterized by polybariccrystallization conditions (200–900 MPa). In addition,our results demonstrate close to anhydrous crystallization conditionsof N-MORBs, whereas geochemically enriched MORBs were successfullymodeled in the presence of 0·4–1 wt% H2O in theparental melts. These estimates are in agreement with direct(Fourier transform IR) measurements of H2O abundances in basalticglasses and melt inclusions for selected samples. Water contentsdetermined in the parental melts are in the range 0·04–0·09and 0·30–0·55 wt% H2O for depleted and enrichedMORBs, respectively. Our results are in general agreement (within±200 MPa) with previous approaches used to evaluate pressureestimates in MORB. However, the determination of pre-eruptiveconditions of MORBs, including temperature and water contentin addition to pressure, requires the improvement of magma crystallizationmodels to simulate liquid lines of descent in the presence ofsmall amounts of water. KEY WORDS: MORB; Mid-Atlantic Ridge; depth of crystallization; water abundances; phase equilibria calculations; cotectic crystallization; pressure estimates; polybaric fractionation 相似文献
48.
Experimental phase equilibrium and trace element partitioningdata are reported for H2O-saturated mid-ocean ridge basalt at2·5 GPa, 750–900°C and oxygen fugacities atthe nickel–nickel oxide buffer. Garnet, omphacite andrutile are present at all temperatures. Amphibole and epidotedisappear as residual phases above 800°C; allanite appearsabove 750°C. The Na–Al-rich silicate glass presentin all run products is likely to have quenched from a supercriticalliquid. Trace element analyses of glasses demonstrate the importantcontrol exerted by residual minerals on liquid chemistry. Inaddition to garnet, which controls heavy rare earth elements(HREE) and Sc, and rutile, which controls Ti, Nb and Ta, allanitebuffers the light REE (LREE; La–Sm) contents of liquidsto relatively low levels and preferentially holds back Th relativeto U. In agreement with previous experimental and metamorphicstudies we propose that residual allanite plays a key role inselectively retaining trace elements in the slab during subduction.Experimental data and analyses of allanite-bearing volcanicrocks are used to derive a model for allanite solubility inliquids as a function of pressure, temperature, anhydrous liquidcomposition and LREE content. The large temperature dependenceof allanite solubility is very similar to that previously determinedfor monazite. Our model, fitted to 48 datapoints, retrievesLREE solubility (in ppm) to within a factor of 1· 40over a pressure range of 0–4 GPa, temperature range of700–1200°C and for liquids with anhydrous SiO2 contentsof 50–84 wt %. This uncertainty in LREE content is equivalentto a temperature uncertainty of only ± 27°C at 1000K, indicating the potential of allanite as a geothermometer.Silicic liquids from either basaltic or sedimentary protolithswill be saturated in allanite except for Ca-poor protolithsor at very high temperatures. For conventional subduction geothermsthe low solubility of LREE (+ Th) in liquids raises questionsabout the mechanism of LREE + Th transport from slab to wedge.It is suggested either that, locally, temperatures experiencedby the slab are high enough to eliminate allanite in the residueor that substantial volumes of H2O-rich fluids must pass throughthe mantle wedge prior to melting. The solubility of accessoryphases in fluids derived from subducted rocks can provide importantconstraints on subduction zone thermal structure. KEY WORDS: subduction; experimental petrology; allanite; solubility; supercritical liquid; eclogite 相似文献
49.
实验研究不同盐离子对水分子拉曼效应的影响 总被引:3,自引:0,他引:3
对流体包裹体中常见的几种盐水溶液进行了拉曼光谱分析.采用了频移参数描述水分子拉曼峰的形变强度,并讨论了频移参数与盐度之间的关系.实验分析结果表明,盐度越大,频移参数越大,水分子拉曼峰形变越大.对频移参数曲线斜率分析显示,盐类对水分子拉曼峰偏移程度影响的强弱顺序为NaCl>Na2SO4>NaHCO3>Na2CO3.讨论了不同阳离子和阴离子对水伸缩振动拉曼峰的影响,结果表明,高价阳离子的影响明显高于低价阳离子;而阴离子对水拉曼峰影响的强弱顺序初步确定为Cl-≈SO2-4->HCO-3>CO2-3≈NO-3. 相似文献
50.