Lower to Middle Devonian carbonates of the Prague Syncline, the Carnic Alps, the Montagne Noire, and the Cantabrian Mountains were investigated for δ13Ccarb and δ13Corg. These values were measured on bulk rocks, selected components and cements. Many carbonates exhibit primary marine values, but some are altered by diagenesis. A δ13C curve can be presented for the latest Pridolian to Emsian time interval. Several sharp or broad positive excursions are obvious in the woschmidti-postwoschmidti, sulcatus, kitabicus, Late serotinus, and kockelianus conodont zones. The excursion at the Silurian–Devonian boundary is known worldwide and therefore considered global in nature. Some of the others are described for the first time from central and southern Europe, and their global nature has to be verified by further investigations in other regions. Most excursions relate to and/or started during major regressions whereas sea-level highstands correspond to minimal δ13C values. Similar relationships between sea-level changes and δ13C have been observed from other early Palaeozoic intervals. The transgressive Chote? (?) and Ka?ák events are marked by positive isotope excursions, this type of combination is usually observed in late Palaeozoic to Cenozoic black shale events. 相似文献
Omphacite and garnet coronas around amphibole occur in amphibolites in the Hong'an area, western Dabie Mountains, China. These amphibolites consist of an epidote–amphibolite facies assemblage of amphibole, garnet, albite, clinozoisite, paragonite, ilmenite and quartz, which is incompletely overprinted by an eclogite facies assemblage of garnet, omphacite and rutile. Coronas around amphibole can be divided into three types: an omphacite corona; a garnet–omphacite–rutile corona; and, a garnet–omphacite corona with less rutile. Chemographic analysis for local reaction domains in combination with petrographical observations show that reactions Amp + Ab + Pg = Omp +Czo + Qtz + H2O, and Amp + Ab = Omp ± Czo + Qtz + H2O may lead to the development of omphacite coronas. The garnet–omphacite–rutile corona was formed from the reaction Amp + Ab + Czo + Ilm ± Qtz = Omp + Grt + Rt + H2O. In garnet–omphacite coronas, the garnet corona grew during an early stage of epidote amphibolite facies metamorphism, whereas omphacite probably formed by the reactions forming the omphacite corona during the eclogite facies stage. It is estimated that these reactions occurred at 0.8–1.4 GPa and 480–610 °C using the garnet–clinopyroxene thermometer and omphacite barometer in the presence of albite. 相似文献