Carbonaceous aerosol transport from the Indo-Gangetic Plain to the Himalayas: Carbon isotope evidence and light absorption characteristics

The Indo-Gangetic Plain (IGP) is a major regional and global emitter of atmospheric pollutants, which adversely affect surrounding areas such as the Himalayas. We present a comprehensive dataset on carbonaceous aerosol (CA) composition, radiocarbon (Δ¹⁴C) -based source apportionment, and light absorption of total suspended particle (TSP) samples collected over a 3-year period from high-altitude Jomsom in the central Himalayas. The 3-year mean TSP, organic carbon (OC), and elemental carbon (EC) concentrations were 92.0 ± 28.6, 9.74 ± 6.31, and 2.02 ± 1.35 μg m^?3, respectively, with the highest concentrations observed during the pre-monsoon season, followed by the post-monsoon, winter, and monsoon seasons. The Δ¹⁴C analysis revealed that the contribution of fossil fuel combustion (f_fossil) to EC was 47.9% ± 11.5%, which is consistent with observations in urban and remote regions in South Asia and attests that EC likely arrives in Jomsom from upwind IGP sources via long-range transport. In addition, the lowest f_fossil (38.7% ± 13.3%) was observed in winter, indicating large contributions in this season from local biomass burning. The mass absorption cross-section of EC (MAC_EC: 8.27 ± 1.76 m²/g) and water-soluble organic carbon (MAC_WSOC: 0.98 ± 0.45 m²/g) were slightly higher and lower than those reported in urban regions, respectively, indicating that CA undergo an aging process. Organic aerosol coating during transport and variation of biomass burning probably led to the seasonal variation in MAC of two components. Overall, WSOC contributed considerably to the light absorption (11.1% ± 4.23%) of EC. The findings suggest that to protect glaciers of the Himalayas from pollution-related melting, it is essential to mitigate emissions from the IGP.     

What future for the voluntary carbon offset market after Paris? An explorative study based on the Discursive Agency Approach

The Paris Agreement heralds a new era in international climate governance. Yet, the Agreement's implementation rulebook is still under negotiation. During this transition, from the Kyoto Protocol to the new regime under the Paris Agreement, many non-state actors are facing a high level of uncertainty. In particular, actors in the voluntary carbon market are struggling to define their new role. The business model of producing carbon credits in developing countries and selling them elsewhere is threatened. Although its financial significance and achieved emission reductions are limited, the voluntary market's role as an incubator for innovation has made it a prominent representative of non-state mitigation mechanisms. Therefore, we ask: What effects will the regime change to the Paris Agreement have on the voluntary carbon offset market (VCM) and how does it react to these effects?

This study analyses perceptions of, and reactions to, the new regulatory environment within the VCM. We apply the Discursive Agency Approach to scrutinize the institutions, discourses and influential agents involved in the VCM, and the strategic practices they apply to manage the transition towards the Paris regime. We find two dominant coping strategies: to align the voluntary offsetting mechanism with the Paris Agreement, and to re-invent its overall purpose as a tool to deliver sustainable development rather than solely emission reductions. Based on these results, we outline ‘thought spaces’ for a future VCM: (1) voluntary and non-party offsetting beyond nationally determined contributions (NDCs), (2) results-based financing for emission reductions and sustainable development, and (3) private climate action under international oversight.

Key policy insights

• The Paris Agreement threatens the VCM's business model, prompting market agents to frame and legitimize their work in new ways.

• The voluntary market's viability depends on the future accounting rules for emission reductions under Paris Agreement Article 6. Discursive struggles surround the risks of double counting and NDC ambitions.

• Based on an understanding of the past, we can draw lessons from agents’ attempts to re-legitimize their role under the new Paris Agreement; their future visions will shape the debates about this nascent regime.

     

The differentiated impact of emissions trading system based on company size

Most countries implementing an emissions trading system (ETS), such as EU member states, California in the US, or South Korea, are generally targeting large sized companies, which consume energy above a specific threshold. However, previous studies using computable general equilibrium (CGE) models have analyzed climate policies without considering company size. This may have led to inaccurate results because the impacts of climate policy would differ depending on the coverage of regulated companies. Accordingly, this study examines the environmental and economic impacts of greenhouse gas emission reduction policies, assuming policy results vary by firm size, as covered by the Korean emission trading system. To this end, a CGE model with a separate social accounting matrix based on company size is used to compare three scenarios that reflect different types of carbon pricing methods. The results show that greenhouse gases will be reduced to a lower extent and utility will decrease more if mitigation policies are only imposed to large companies.

Key policy insights

• Carbon pricing policies should consider the different impacts on companies of different sizes and industry sectors.

• Without considering the different sizes of companies covered by an ETS, the expected carbon price and its economic impact will be underestimated.

• Small and medium-sized companies will face more negative impacts than large companies in some industry sectors under an ETS, even if the mitigation burden is only faced by large companies.

     

Aligning climate action with the self-interest and short-term dominated priorities of decision-makers

The global and long-term nature of climate change conflicts with the self-interest and short-term dominated priorities of decision-makers. Climate change mitigation makes sense at the global level, but not at the level of the individual decision-maker. This conflict has been and remains the main obstacle to effective global cooperation and mitigation. This paper proposes a framework that aligns climate action with short-term self-interest through results-based payments to governments. Its key components are: determining an emission benchmark for each country as well as a price for carbon saving; paying countries annually for reducing emissions below their respective benchmark; a new international fund to finance these annual payments by borrowing capital from private investors; and repaying borrowings in the long-term through payments made by countries to the fund based on a pre-determined allocation mechanism. This framework would offer important benefits over an approach focused on allocating climate action or a carbon budget among countries. These include the improved prospect of reaching an effective climate agreement and delivering fast and dramatic mitigation thanks to stronger political commitment, the transformation of short-term self-interest from an obstacle into a driver of climate action, and the additional financing created. The paper also proposes a pilot scheme focusing on hydrofluorocarbon emissions with a considerably lower financing requirement. This offers the possibility of an alternative financing mechanism, and thus a faster and more straightforward implementation path. Short-term financial incentives offered to governments could turn policy action from a burden into an opportunity from their perspective unlocking a huge potential for timely mitigation.

Key policy insights

• A new international framework that offers short-term, results-based payments to governments to promote mitigation action could lead to much more effective global mitigation and international cooperation.

• The financing of such an approach could be solved through a novel financing structure, backed by the long-term commitments of participating countries and thus aligning the timeframe of the financial costs of mitigation with its climate benefits.

• The effectiveness of results-based payments and the concept behind this new approach could be proven through a pilot scheme focusing on hydrofluorocarbon emissions.

     

Sunlight and tidal interaction as a mechanism of carbon transport in an ice-covered region: Results of a coupled ice–ocean ecosystem model

In order to clarify the mechanism of carbon transport in an ice-covered ecosystem in Lake Saroma (44^°N${44}^{°}\mathrm{N}$, 143^°E${143}^{°}\mathrm{E}$, Hokkaido, Japan), a three-dimensional numerical calculation using a coupled ice–ocean ecosystem model was conducted. This model comprises an ocean ecosystem model, an ice ecosystem model, and equations for the coupling between ice and ocean. Comparisons of calculated results with observational data confirm that the calculation well reproduced the in situ phenomena with respect to tides, tidal currents, concentrations of POC and chlorophyll a in ice and in water, and sinking fluxes beneath the ice. The analysis of the organic carbon budget based on the calculation reveals that tide-induced transport, the enhancement of biological production in a pelagic system, and the physical release of organic matter from ice associated with ice-melting are important factors affecting the carbon transport during the ice-melting season. The carbon transport has a one-day time cycle. This is because principal driving forces are sunlight, and diurnal tides. The described mechanism of “sunlight and tidal pumping” is one of the most important features of carbon transport in a coupled ice–water ecosystem.     

Efficient trapping of organic carbon in sediments on the continental margin with high fluvial sediment input off southwestern Taiwan

Accumulation rates of marine and terrigenous organic carbon in the continental margin sediments off southwestern Taiwan were estimated from the measured concentrations and isotopic compositions of total organic carbon (TOC) and previously reported sedimentation rates. Surficial sediments were collected from the study area spanning from the narrow shelf near the Kaoping River mouth to the deep slope with depths reaching almost 3000 m. The average sediment loading of Kaoping River is 17 Mt/yr, which yields high sediment accumulation rates ranging from 0.08 to 1.44 g cm⁻² yr⁻¹ in the continental margin. About half of the discharged sediments were deposited on the margin within 120 km of the river mouth. Carbon isotopic compositions of terrestrial and marine end-members of organic matter were determined, respectively, based on suspended particulate matter (SPM) collected from three major rivers in the southwestern Taiwan and from an offshore station. All samples were analyzed for the TOC content and its isotopic composition (δ¹³C_org). The SPM samples were also analyzed for the total nitrogen (TN) content. TOC content in marine sediments ranges from 0.45% to 1.35% with the highest values on the upper slope near the Kaoping River mouth. The TOC/TN ratio of the SPM samples from the offshore station is 6.8±0.6, almost identical to the Redfield ratio, indicating their predominantly marine origin; their δ¹³C_org values are also typically marine with a mean of −21.5±0.3‰. The riverine SPM samples exhibit typical terrestrial δ¹³C_org values around −25‰. The δ¹³C_org values of surficial sediments range from −24.8‰ to −21.2‰, showing a distribution pattern influenced by inputs from the Kaoping River. The relative contributions from marine and terrestrial sources to sedimentary organic carbon were determined by the isotope mixing model with end-member compositions derived from the riverine and marine SPM. High fluvial sediment inputs lead to efficient trapping of organic carbon over a wide range of water depth in this continental margin. The marine organic accumulation rate ranges from 1.6 to 70 g C m⁻² yr⁻¹ with an area weighted mean of 4.2 g C m⁻² yr⁻¹, which is on a par with the mean terrestrial contribution and accounts for 2.3% of mean primary production. The depth-dependent accumulation rate of marine organic carbon can be simulated with a function involving primary productivity and mineral accumulation rate, which may be applicable to other continental margins with high sedimentation rates. Away from the nearshore area, the content of terrigenous organic carbon in surficial sediments decreases with distance from the river mouth, indicating its degradation in marine environments.     

On the Anomalous Behaviour of Scalar Flux–Variance Similarity Functions Within the Canopy Sub-layer of a Dense Alpine Forest

Within the canopy sub-layer (CSL), variability in scalar sources and sinks are known to affect flux–variance (FV) similarity relationships for water vapour (q) and carbon dioxide (C) concentrations, yet large-scale processes may continue to play a significant role. High frequency time series data for temperature (T), q and C, collected within the CSL of an uneven-aged mixed coniferous forest in Lavarone, Italy, are used to investigate these processes within the context of FV similarity. This dataset suggests that MOST scaling describes the FV similarity function of T even though the observations are collected in the CSL, consistent with other studies. However, the measured FV similarity functions for q and C appear to have higher values than their temperature counterpart. Two hypotheses are proposed to explain the measured anomalous behaviour in the FV similarity functions for q and C when referenced to T. Respired CO₂ from the forest floor leads to large positive excursions in the C time series at the canopy top thereby contributing significantly to both C variance increase and C vertical flux decrease—both leading to an anomalous increase in the FV similarity function. For q, transport of dry air from the outer-layer significantly increases both the variance and the water vapour flux. However, the expected flux increase is much smaller than the variance increase so that the net effect remains an increase in the measured FV similarity function for water vapour above its T counterpart. The hypothesis here is that identifying these events in the temporal and/or in the frequency domain and filtering them from the C and q time series partially recovers a scalar flow field that appears to follow FV similarity theory scaling. Methods for identifying both types of events in the time and frequency domains and their subsequent effects on the FV similarity functions and corollary flow variables, such as the relative transport efficiencies, are also explored.     

Concatenation of HRSC colour and OMEGA data for the determination and 3D-parameterization of high-altitude CO2 clouds in the Martian atmosphere

We used Mars Express HRSC and OMEGA data to investigate mesospheric cloud features observed in the equatorial belt of Mars from December 2007 until early March 2008. This period corresponds to early northern spring of Martian year 29. The reflection peak at 4.26 μm in OMEGA data identifies the clouds as CO₂ ice clouds. HRSC observed the clouds together with OMEGA in five orbits. Cloud features are most prominent in the shortwave HRSC colour channels with wavelength centers at 440 and 530 nm, but rarely visible in all other channels. In the period of Ls 0-36°, OMEGA and HRSC together detected mesospheric CO₂ ice clouds in 40 orbits. They occur in a latitude belt of ±20° around the equator and at longitudes between 240°E (Tharsis) in the West and 30°E (Sinus Meridiani) in the East. The clouds were observed between 3 and 5 p.m. local time with mainly ripple-like to filamentary cloud forms. The viewing angles of the HRSC blue and green colour channels differ by 6.6° and the resulting parallax can be used to directly measure cloud heights by means of ray intersection. 17 HRSC data takes were found to exhibit clouds with heights from 66 to 83 km with an accuracy of 1-2 km. The pushbroom imaging technique also yields a time delay for the two observations in the order of 5-15 s close to periapsis, and therefore time-related cloud movements can be detected. A method was developed to determine the across-track cloud displacements, which can directly be translated to wind velocities. Zonal cloud movements could be measured in 13 cases and were oriented from East to West. Related wind speeds range between 60 and 93 m/s with an accuracy of 10-13 m/s.     

冷泉区底栖有孔虫研究进展

海底冷泉区是海洋能源和生物资源同时富集的一类特殊区域。底栖有孔虫群落及其地球化学组成是海底冷泉区发育的重要指示标志之一。海底冷泉区的底栖有孔虫及其碳同位素研究,对于探讨冷泉演化、评估古冷泉甲烷排放对全球气候变化的影响有重要的研究意义。综述了全球一些主要冷泉区的底栖有孔虫研究方法及其进展,对比了各冷泉区底栖有孔虫群落结构的主要特征及地域差异,评述了冷泉区底栖有孔虫的碳同位素记录特征、影响因素及其对冷泉活动的潜在指示意义,最后提出了南海北部冷泉活动区底栖有孔虫方面的研究展望。     

Biostratigraphy of a Paleocene–Eocene Foreland Basin boundary in southern Tibet

This study of the Paleocene–Eocene boundary within a foreland basin of southern Tibet, which was dominated by a carbonate ramp depositional environment, documents more complex environmental conditions than can be derived from studies of the deep oceanic environment. Extinction rates for larger foraminiferal species in the Zongpu-1 Section apply to up to 46% of the larger foraminiferal taxa. The extinction rate in southern Tibet is similar to rates elsewhere in the world, but it shows that the Paleocene fauna disappeared stepwise through the Late Paleocene, with Eocene taxa appearing abruptly above the boundary. A foraminifera turnover was identified between Members 3 and 4 of the Zongpu Formation—from the Miscellanea–Daviesina assemblage to an Orbitolites–Alveolina assemblage. The Paleocene and Eocene boundary is between the SBZ 4 and SBZ 5, where it is marked by the extinction of Miscellanea miscella and the first appearance of Alveolina ellipsodalis and a large number of Orbitolites. Chemostratigraphically, the δ13C values from both the Zongpu-1 and Zongpu-2 Sections show three negative excursions in the transitional strata, one in Late Paleocene, one at the boundary, and one in the early Eocene. The second negative excursion of δ13C, which is located at the P–E boundary, coincides with larger foraminifera overturn. These faunal changes and the observed δ13C negative excursions provide new evidence on environmental changes across the Paleocene–Eocene boundary in Tibet.