黄土台缘滑坡地表水入渗问题分析

黄土塬区提灌工程保证了农业生产,却造成了地下水位大幅抬升,使得近年来黄土台缘滑坡不断发生。黄土滑坡一个普遍特征就是后缘发育地裂缝以及落水洞,使地表水（灌溉水以及降雨）直接灌入坡体,诱发了大量黄土滑坡。因此,地表水入渗对于黄土滑坡机理研究以及滑坡防治具有重要意义。文章基于对陕西泾阳南塬黄土滑坡的现场调查,对黄土台缘滑坡地表水入渗工程地质问题进行了初步分析,包括：①地表水入渗与落水洞形成机制;②地表水入渗途径及其与黄土滑坡发育过程的关系;③降雨因素对于黄土滑坡的影响程度。     

基坑潜水疏干的简化计算在昊华水泥厂中的应用

以流线、流面、汇点的概念为基础,对稳定流双井干扰和直线隔水边界附近涌水量理论公式进行对比分析,提出了二个虚拟界面,其中虚拟界面Ⅰ,运用流线、流面的性质,流线方程等给出证明;虚拟界面Ⅱ则通过半无限条形降落漏斗的分析,应用元流和总流的能量方程得到流量为零,流线为零的平面。在同样条件下,条形无限涌水量是半无限潜含水层涌水量的二倍。应用总流能量方程对三种情况水头损失的分析,解释了这种关系存在的合理性,得出虚拟界面Ⅱ,并以此得出该界面内的最大残余水头计算公式。将基坑降水运用虚拟界面简化为扇形,条形半无限含水层,从而实现单井预测,该方法应用到昊华水泥厂基坑降水中,预测效果理想。     

Molecular and bulk isotopic analyses of organic matter in marls of the Mulhouse Basin (Tertiary, Alsace, France)

Contents of 13C in kerogens and carbonates in 21 samples from a core of the MAX borehole, Mulhouse Evaporite Basin, range from -27.3 to -23.5 and -3.7 to -1.8% vs PDB, respectively. Organic nitrogen in the same samples is enriched in 15N relative to atmospheric N2 by 12.2-15.7%. Hydrogen indices and delta values for kerogens vary systematically with facies, averaging 493 mg HC/g Corg and -25.7% in the most saline facies (dominated by inputs from aquatic sources) and 267 mg HC/g Corg and -23.7% in the least saline facies (50/50 aquatic/terrigenous). Values of delta were measured for individual aliphatic hydrocarbons from three samples representing three different organic facies. For all samples, terrigenous inputs were unusually rich in 13C, the estimated delta value for bulk terrigenous debris, apparently derived partly from CAM plants, being -22.5%. In the most saline facies, isotopic evidence indicates the mixing of 13C-depleted products of photosynthetic bacteria with 13C-enriched products of halotolerant eukaryotic algae. At lower salinities, a change in the producer community is marked by a decrease in the 13C content of algal lipids. The content of 13C in algal lipids increases in the least saline facies, due either to succession of different organisms or to decreased concentrations of dissolved CO2.     

The hydrogeochemistry of methane: Evidence from English groundwaters

The presence of methane (CH₄) in groundwater is usually only noticed when it rises to high concentrations; to date rather little is known about its production or natural ‘baseline’ conditions. Evidence from a range of non-polluted groundwater environments in England, including water supply aquifers, aquicludes and thermal waters, reveals that CH₄ is almost always detectable, even in aerobic conditions. Measurements of potable waters from Cretaceous, Jurassic and Triassic carbonate and sandstone aquifers reveal CH₄ concentrations of up to 500 μg/l, but a mean value of < 10 μg/l. However, aquiclude and thermal waters from the Carboniferous and Triassic typically contain in excess of 1500 μg/l. Such high concentrations have so far only been found at redox (Eh) potentials below 0 mV, but in general CH₄ concentration and Eh value are poorly correlated. This suggests a lack of thermodynamic equilibrium, which is confirmed by comparing pe values calculated from the redox couple C(4)/C(− 4) with those derived from Eh. Genesis of CH₄ appears to occur on two timescales: a rapid if low rate of production from labile carbon in anaerobic microsites in the soil, and a much longer, millennium scale of production from more refractory carbon. Methane is rarely measured in groundwater; there is no single ionic determinand which acts universally as a proxy, but a combination of high HCO₃ and low SO₄ concentrations, or the reverse, is an indication that high amounts of CH₄ may be present.     

Carbon, sulfur and O2 across the Permian–Triassic boundary

A model for the carbon and sulfur cycles across the Permian–Triassic boundary has been constructed from carbon and sulfur isotopic data. Results indicate a drop in global organic matter burial, the formation of an anoxic deep ocean, and a large drop in atmospheric oxygen over the time span 270 to 240 Ma. Much of these changes were probably due to a drop in terrestrial productivity and preservation and an increase in global aridity.     

Can stable isotopes be used to monitor landfill leachate impact on surface waters?

Bacterially mediated methanogenesis in municipal solid waste landfills has been shown to cause an enrichment of carbon stable isotope ratios of dissolved inorganic carbon and hydrogen stable isotope ratios of water in landfill leachate. In the present study, we investigate the universality of this enrichment in leachate obtained from four diverse landfill sites in New Zealand. At each site, surface water samples upstream and downstream of landfills were analysed to examine the applicability of stable isotope ratios as a tool for monitoring leachate contamination in landfill-associated streams. The design of leachate collection systems, operational history, and landfill location appeared to strongly influence leachate isotopic values and the effectiveness of isotope ratios as an environmental monitoring tool for surface water.     

库车坳陷侏罗系煤成气动力学模拟研究

应用黄金管—高压釜封闭体系热模拟实验与GC、GC-IRMS分析技术,结合KINETICS专用软件,对库车坳陷侏罗系煤成气进行了动力学模拟研究。库车坳陷侏罗系煤具有高的产气性,在高演化阶段主要产甲烷气;侏罗系煤热解气甲烷碳同位素为-36‰～-25‰,乙烷碳同位素为-28‰～-16‰;甲烷、C2-C5气态烃的生成活化能分别为(47～64k)calm/ol、(55～72k)calm/ol,频率因子各为5.265×1013s-1、5.388×1018s-1。在此基础上,进一步探讨了克拉2气田天然气的成因。研究认为,克拉2气田天然气属阶段捕获的煤成气,主要聚集了5～1Ma时期的天然气,其成熟度Ro分布范围为1.3%～2.5%。     

近20年海南岛森林生态系统碳储量变化

热带森林在碳循环研究中有重要作用。根据目前森林碳储量的计算方法和海南森林资源二类调查数据 ,估算了不同时段的碳储量 ,并分析其动态变化特点。结果表明 :海南森林碳储量从 1979年的 30 4 5TgC增加到 1998年的 37 74TgC ,年均增加 0 36 4 5TgC ,增长率为1 19% ,是全国平均增长率的 2 5倍 ;海南森林在碳循环中起不断增强的碳汇作用 ;森林碳密度呈加速减少趋势 ,储碳潜力将很大 ;随着海南全面禁止采伐和封育等林业措施的实施 ,森林面积扩大 ,林龄结构改善 ,储碳能力将进一步提高 ,海南森林在全国或全球碳循环中的作用和社会价值与意义将日渐突出。通过对碳储量计算不确定性的分析和讨论 ,提出应加强对森林群落各层次生物量的实测与实地监测研究 ,统一计算方法 ,以提高碳储量计算的精度     

灌溉对甘肃中部黄土台塬区地面塌陷及生态环境影响研究

甘肃中部黄土台塬地面塌陷实质上是由水利灌溉引起的新的生态环境问题。文章在深入调查、勘测和试验研究的基础上，综合分析了地面塌陷变形的成因机制，认为黄土台塬地面塌陷变形除了黄土母质理化性质和人类活动等因素外，主要是不合理灌溉引起的。过量大水漫灌使大量渗入的水体将土壤中起固结作用的盐分和粘粒矿物淋溶殆尽，使原始结构破坏，进而崩解、湿陷。随下渗水量的增加，犁底层及以下隔水层孔洞进一步发展为洞穴和陷缝，大面积塌陷变形随之出现，同时也成为台塬滑坡的诱导因素。研究为黄土台塬灌区突出的水利环境问题治理和生态重建方案提供了基础依据。     

dC Variations in Late Jurassic Carbonates, Jaisalmer Formation, Western India

The carbon isotope measurements, carried out on subsurface carbonate samples from Oxfordian Jaisalmer Formation, western India, yield positive d¹³C values up to +3.17%. The most positive Oxfordian C-isotope value corresponds to the carbon isotope excursion measured in samples from from other late Jurassic basins of world. The latest Oxfordian C-isotope values of Jaisalmer Basin fluctuate around 2% while the C-isotope values of 1.50% mark the base of Kimmeridgian. The Oxfordian C-isotope excursion appears to correspond to a time of overall increased organic carbon burial triggered by increased nutrient transfer from continents to oceans during a time of rising global sea level.