Magnetotelluric characterization through the Ambargasta-Sumampa Range: The connection between the northern and southern trace of the Río de La Plata Craton – Pampean Terrane tectonic boundary

The South American Platform was part of the Western Gondwana, a collage of plates of different ages assembled in late Neoproterozoic to Cambrian times. The Transbrasiliano Lineament, a continental shear belt that transversely intersects this platform from NE to SW, has its southern expression in the tectonic boundary between the Río de La Plata Craton and the Pampean Terrane. Magnetotelluric long-period data in a W–E profile (29°30′ S) that crosses the Ambargasta-Sumampa Range and the Chaco-Pampean Plain were obtained to connect information of this mostly inferred tectonic boundary. A 2-D inversion model shows the Chacoparanense basin, Río Dulce lineament, Ambargasta-Sumampa Range and Salina de Ambargasta in the upper crust. At mid-to-lower crust and 40 km to the east of the Ambargasta-Sumampa Range, a discontinuity (500–2000 Ω m) of 20-km-wide separates two highly resistive blocks, the Río de La Plata Craton (6000–20,000 Ω m) in the east, and the Pampean Terrane (5000–20,000 Ω m) in the west. This discontinuity represents the tectonic boundary between both cratons and could be explained by the presence of graphite. The geometry of the Pampean Terrane suggests an east-dipping paleo-subduction. Our results are consistent with gravimetric and seismicity data of the study area. A more conductive feature beneath the range and the tectonic boundary was associated with the NE–SW dextral transpressive system evidenced by the mylonitic belts exposed in the Eastern Pampean Ranges. This belt represents a conjugate of the mega-shear Transbrasiliano Lineament and could be explained by fluid–rock interaction by shearing during hundreds of years. The eastern border of the Ambargasta-Sumampa Range extends the trace of the Transbrasiliano Lineament. The electrical Moho depth (40 km to the west and 35 km to the east) was identified by a high electrical contrast between the crust and upper mantle. The upper mantle shows a resistive structure beneath the Río de La Plata Craton that could have been originated by stationary delamination by the presence of hydrated lithosphere.     

Orosirian (ca. 1.96 Ga) mafic crust of the northwestern São Francisco Craton margin: Petrography,geochemistry and geochronology of amphibolites from the Rio Preto fold belt basement,NE Brazil

The bulk of the Atlantic shield basement in the eastern South American platform is made of Rhyacian calc-alkaline magmatic rocks (∼2.2–2.15 Ga) affected by granulite-facies metamorphism at around 2.06 Ga, as part of a Paleoproterozoic orogenic system which joined Archean crustal fragments together. Orosirian (2050–1800 Ma) rocks, on the other hand, are scarce in all four major provinces of eastern South America (the Borborema, São Francisco, Tocantins and Mantiqueira provinces). Recently, however, sparse occurrences of Orosirian-aged rocks have been described, particularly in the northern São Francisco Craton margin and adjoining fold belts that compose the Borborema Province further north. In this paper, we present new geochemical, geochronological and isotopic data of amphibolites which compose the basement of the Rio Preto fold belt, in the northwestern São Francisco Craton margin. Geochemical data suggest tholeiitic gabbro protoliths intruded in a subduction-related setting, as suggested by tectonic discrimination diagrams and differentiation trends. U–Pb analyses of magmatic zircon crystals yielded a 1958.3 ± 16 Ma Concordia age. Slightly negative to positive εNd_(1.96) = (−0.3 to +1.0) and εHf_(1.96) from −0.76 to −4.55 suggest variable mixing of a depleted mantle source and older continental crust. We interpret the amphibolite body as a remnant of a subduction-related crustal fragment developed in the Orosirian, around 1.96 Ga ago, possibly in a continental back-arc setting. This crustal fragment was further reworked as part of the basement of the Rio Preto fold belt during the Brasiliano Orogeny (∼600–550 Ma). The Cristalândia do Piauí Complex gneisses further north might represent fragments of a coeval continental magmatic arc. These rocks could be the first well documented representatives of an Orosirian tectono-magmatic event which has been, up to now, broadly ignored within this portion of West Gondwana, and thus present major implications for the Proterozoic crustal evolution of South America and for Paleoproterozic supercontinent reconstructions in general.     

A late eocene-early Oligocene transgressive event in the Golfo San Jorge basin: Palynological results and stratigraphic implications

A new Cenozoic dataset in the subsurface of the South Flank of the Golfo San Jorge Basin (Santa Cruz province) allowed to identify a non-previously recognized transgressive event of late Eocene to early Oligocene age. Below of a marine succession containing a dinoflagellate cyst assemblage that characterizes the C/G palynological zone of the Chenque Formation (early Miocene), a 80–110 m thick marine succession contains a palynological assemblage integrated by Gelatia inflata, Diphyes colligerum and Reticulatosphaera actinocoronata supporting the occurrence of a marine incursion in the basin during the Eocene–Oligocene transition (EOT). The new lithostratigraphic unit - here defined as El Huemul Formation – covers in sharp contact to the Sarmiento Formation, and become thinner from East to West; the unit has been identified in about 1800 well logs covering up to 3500 km², and its subsurface distribution exceed the boundaries of the study area. The El Huemul Formation consists of a thin lag of glauconitic sandstones with fining-upward log motif, followed by a mudstone-dominated succession that coarsening-upward to sandstones, evidencing a full T-R cycle. Preservation of the El Huemul Formation in the subsurface of the South Flank has been favored by the reactivation of WNW-ESE late Cretaceous normal faults, and by the generation of N–S striking normal faults of Paleocene-Eocene age. Flexural loading associated to igneous intrusions of Paleocene?- middle Eocene age also promoted the increase of subsidence in the South Flank of the basin prior to the transgression.     

Provenance and sedimentary environments of the Proterozoic São Roque Group,SE-Brazil: Contributions from petrography,geochemistry and Sm–Nd isotopic systematics of metasedimentary rocks

The Proterozoic metasedimentary sequences exposed in the São Roque Domain (Apiaí Terrane, Ribeira Belt, southeast Brazil) consist of metasandstones and meta-felspathic wackes with some volcanic layers of within-plate geochemical signature (Boturuna Formation), a passive margin turbidite sequence of metawackes and metamudstones (Piragibu Formation), and volcano-sedimentary sequences with MORB-like basalts (Serra do Itaberaba Group; Pirapora do Bom Jesus Formation). A combination of zircon provenance studies in metasandstones, whole-rock geochemistry and Sm–Nd isotopic systematics in metamudstones was used to understand the provenance and tectonic significance of these sequences, and their implications to the evolution of the Precambrian crust in the region.Whole-rock geochemistry of metamudstones, dominantly from the Piragibu Formation, points to largely granitic sources (as indicated for instance by LREE-rich moderately fractionated REE patterns and subtle negative Eu anomalies) with some mafic contribution (responding for higher contents of Fe₂O₃, MgO, V, and Cr) and were subject to moderate weathering (CIA – 51 to 85). Sm–Nd isotope data show three main peaks of Nd T_DM ages at ca. 1.9, 2.1 and 2.4 Ga; the younger ages define an upper limit for the deposition of the unit, and reflect greater contributions from sources younger than the >2.1 Ga basement.The coincident age peaks of Nd TDM and U–Pb detrital zircons at 2.1–2.2 Ga and 2.4–2.5 Ga, combined with the possible presence of a small amount of zircons derived from mafic (gabbroid) sources with the same ages, as indicated by a parallel LA-ICPMS U–Pb dating study in metapsammites, are suggestive that these were major periods of crustal growth in the sources involving not only crust recycling but also some juvenile addition.A derivation from similar older Proterozoic sources deposited in a passive margin basin is consistent with the main sedimentary sequences in the São Roque Domain being broadly coeval and in part laterally continuous. The coincident age, Sm–Nd isotope signature and geographic proximity make the exposures of basement orthogneisses in the Apiaí Terrane candidates for source material to the São Roque Domain. Additional sources with younger Nd T_DM could be juvenile 2.2 Ga basement from the southern portion of the São Francisco Craton and its marginal belts (e.g., Mineiro Belt and Juiz de Fora Complex).     

Countering Inequality: Brazil's Movimento Sem‐Terra

Data from a national survey of formerly landless peasants residing in federal land‐reform settlements in Brazil (Pesquisa Nacional de Educação na Reforma Agrária—PNERA) confirm that the Landless Rural Workers Movement (Movimento dos Trabalhadores Rurais Sem‐Terra—MST) has been far more successful than other settlement movements in assuring a better quality of life for its members. This superior performance is attributed to an organizational structure that demands and assures membership involvement, and a commitment to participatory education in an environment that fosters and supports MST's goals and objectives. MST's members have higher self‐perceived social status than members of non‐MST movements, have better residential environments and more material possessions, and experience an education that emphasizes the movement's principles of social justice, radical democracy, and humanist and socialist values.     

Zoophycos and related trace fossils from the Chefar El Ahmar Formation,Upper Emsian-Frasnian Ia-Ib (Ougarta,SW Algeria)

The Upper Emsian to Frasnian Ia-Ib strata of the Marhouma area (or “km 30” outcrop), exposed in the Ougarta Range (SW Algeria) belong to the Chefar El Ahmar Formation. On the basis of distinct lithological and palaeontological features, this formation is subdivided into three members (Lower Marly Limestones Member, Middle Marly Limestones Member, and Upper Marly Limestones Member). The studied beds show low to moderate diversity of trace fossil assemblage which contains thirteen ichnotaxa: Chondrites intricatus, Chondrites isp., Chondrites cf. targionii, Circulichnis cf. montanus, Cochlichnus isp., Neonereites biserialis, Neonereites multiserialis, Nereites isp., Palaeophycus isp., Planolites isp., Thalassinoides isp., Zoophycos aff. cauda-galli, and Zoophycos isp. A. The two latter ichnotaxa are the most common trace fossils in the assemblage and occur at three different levels showing different bioturbation intensities. The first Zoophycos-bearing level (Zl 1) is characterised by an overall high bioturbation intensity reflecting a very high oxygenation rate and nutrient supply, allowing the development of large and dense Zoophycos specimens. The second Zoophycos-bearing level (Zl 2) has a considerable reduction of bioturbation intensity as compared to the previous level, with an abundance of Chondrites, which is probably due to radical palaeoecological changes that suggests dysoxic and stressful conditions. The third Zoophycos-bearing level (Zl 3) is characterised by an overall moderate bioturbation intensity. The distribution of trace fossils was influenced by lithology, sedimentation rate, energy level (storm events), bottom oxygenation, and nutrient supply. The lithofacies and trace fossils of the Chefar El Ahmar Formation both indicate a depositional environment fluctuating from the lower shoreface to lower offshore zone.     

膨润土负载纳米铁镍同步修复地下水中三氯乙烯和六价铬复合污染

纳米零价铁原位注射修复地下水污染是近年发展的新技术,以往研究多侧重于单一目标污染物的去除效果及作用机理,但是地下水多种污染物共存问题不容忽视。本文针对典型污染物三氯乙烯TCE和六价铬Cr(Ⅵ),运用合成的活性高、稳定性强的膨润土负载纳米铁镍(B-Fe/Ni)开展修复实验,研究B-Fe/Ni对TCE和Cr(Ⅵ)共存复合污染的修复效果及其作用机制。通过一步法合成B-Fe/Ni,对TCE和不同浓度Cr(Ⅵ)混合污染的去除进行试验研究,对反应前后的样品B-Fe/Ni进行表征,并跟踪反应过程中TCE和Cr(Ⅵ)的浓度变化。结果表明:B-Fe/Ni同步去除水中TCE和Cr(Ⅵ)快速高效,50 mg/L Cr(Ⅵ)在2 h内能被B-Fe/Ni (1 g/L)完全去除而不受共存TCE(0. 1 mmol/L)的影响,然而TCE降解速率会随共存Cr(Ⅵ)的浓度(0、10、30、50 mg/L)增大而降低。经透射电镜-电子能谱及X射线光电子能谱表征验证,这是由于B-Fe/Ni与Cr(Ⅵ)快速反应,生成部分Fe-Cr共沉淀会覆盖B-Fe/Ni表面的活性位点,抑制了TCE的降解,但通过分析TCE降解产物可知,B-Fe/Ni同样能对TCE完全脱氯。因此,B-Fe/Ni适用于地下水复合污染修复,实际应用时需考虑多种污染物共存的相互影响,选择适宜试剂用量和注射方式,这对纳米零价铁修复技术的发展具有重要理论意义和应用参考价值。     

The Predictability of Ocean Environments that Contributed to the 2020/21 Extreme Cold Events in China:2020/21 La Niña and 2020 Arctic Sea Ice Loss

Several consecutive extreme cold events impacted China during the first half of winter 2020/21,breaking the low-temperature records in many cities.How to make accurate climate predictions of extreme cold events is still an urgent issue.The synergistic effect of the warm Arctic and cold tropical Pacific has been demonstrated to intensify the intrusions of cold air from polar regions into middle-high latitudes,further influencing the cold conditions in China.However,climate models failed to predict these two ocean environments at expected lead times.Most seasonal climate forecasts only predicted the 2020/21 La Ni?a after the signal had already become apparent and significantly underestimated the observed Arctic sea ice loss in autumn 2020 with a 1-2 month advancement.In this work,the corresponding physical factors that may help improve the accuracy of seasonal climate predictions are further explored.For the 2020/21 La Ni?a prediction,through sensitivity experiments involving different atmospheric-oceanic initial conditions,the predominant southeasterly wind anomalies over the equatorial Pacific in spring of 2020 are diagnosed to play an irreplaceable role in triggering this cold event.A reasonable inclusion of atmospheric surface winds into the initialization will help the model predict La Ni?a development from the early spring of 2020.For predicting the Arctic sea ice loss in autumn 2020,an anomalously cyclonic circulation from the central Arctic Ocean predicted by the model,which swept abnormally hot air over Siberia into the Arctic Ocean,is recognized as an important contributor to successfully predicting the minimum Arctic sea ice extent.     

Approaches to equilibrium in the distribution of trace elements among the principal minerals in a high-grade metamorphic terrane

X-ray fluorescence, instrumental neutron activation, and particle-induced X-ray emission methods were used to determine the distribution of numerous trace elements among garnet (Grt), Ca-pyroxene (Cpx), hornblende (Hbl), biotite (Bt), plagioclase (Pl) and K-feldspar (Kf) in a high-grade metamorphic terrane within the Grenville Province of the Canadian Shield. Results are presented as distribution formulae, e.g. Sr: Kf 1.1 Pl 16 Hbl 2.2 Cpx 1.0 Bt 1.2 Grt Sc: Hbl 1.1 Cpx 1.0 Grt 7.8 Bt 22 Pl 2.6 Kf V: Hbl 1.15 Bt 2.07 Cpx 6.0 Grt (1.4% CaO)>1 (Pl, Kf) Zn: Bt 1.6 Hbl 1.62 Cpx 2.9 Grt 10 Pl Ga: Bt 1.2 Hbl 1.2 Pl 2.5 Cpx 1.3 Grt where numbers are distribution ratios, e.g. ppm Sr in Hbl/ppm Sr in Cpx=2.2. Examples of inter-element similarities and differences are (a) both Rb and Cs are concentrated in biotite relative to K-feldspar, but for Rb the ratio is 2.3 and for Cs it is 16, (b) the distribution formulae for seven lanthanides are similar except for the position of garnet, e.g. Ce: Hbl 2.7 Cpx 2.8 Pl 1.1 Bt 11 Kf 16 Grt Yb: Grt 2.8 Hbl 2.7 Cpx 9 Pl 1.0 Bt 7 Kf and (c) all of Sr, eight lanthanides, Zr, V and Cr are concentrated in hornblende relative to Ca-pyroxene by a factor that lies in the narrow range of 2.2–3.1. There is a larger variation (departure from the mean) in some distribution ratios than in others. Thus the mean ratios (Hbl/Cpx) for each of six elements and in parentheses the percentage relative standard deviation are Zn 1.62 (8.6), V 2.38 (12), Cr 2.42 (18), Sr 2.7 (28), Ba 2.9 (36) and Ni 1.66 (38). We suggest that variation of this kind is the result of differences from place to place in the magnitude of deformation and recrystallization (which facilitated the rearrangement of atoms), combined with rates of lattice and crystal-boundary diffusion that are unique for the various elements, thus permitting some trace elements to approach equilibrium more closely than others.     

REVISITING RIO DE JANEIRO AND SÃO PAULO*

ABSTRACT. Contrasting models of urban development characterize the historical-geographical evolution of Brazil's two leading cities, viewed in an updating of the seminal 1933 article by Preston James. Native to Rio de Janeiro is a distinctive Luso-Brazilian style of irregular coastal urbanization, whereas SÃo Paulo displays a more uniform, modern type of inland commercial-industrial expansion. Even as Rio de Janeiro and SÃo Paulo sprawl today to form a virtual megalopolis in southeastern Brazil, they retain distinguishing roles in the national city system. Both metropolises are experiencing increasing functional decentralization and socioeconomic polarization, but in their own characteristic fashions. Generalized models of “Latin American city structure” are of limited value, unless they take into account such significant historical-geographical variations in urban form.