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31.
M. Koch-Müller P. Dera Y. Fei H. Hellwig Z. Liu J. Van Orman R. Wirth 《Physics and Chemistry of Minerals》2005,32(5-6):349-361
We synthesized superhydrous phase B (shy-B) at 22 GPa and two different temperatures: 1200°C (LT) and 1400°C (HT) using a
multi-anvil apparatus. The samples were investigated by transmission electron microscopy (TEM), single crystal X-ray diffraction,
Raman and IR spectroscopy. The IR spectra were collected on polycrystalline thin-films and single crystals using synchrotron
radiation, as well as a conventional IR source at ambient conditions and in situ at various pressures (up to 15 GPa) and temperatures
(down to −180°C). Our studies show that shy-B exists in two polymorphic forms. As expected from crystal chemistry, the LT
polymorph crystallizes in a lower symmetry space group (Pnn2), whereas the HT polymorph assumes a higher symmetry space group (Pnnm). TEM shows that both modifications consist of nearly perfect crystals with almost no lattice defects or inclusions of additional
phases. IR spectra taken on polycrystalline thin films exhibit just one symmetric OH band and 29 lattice modes for the HT
polymorph in contrast to two intense but asymmetric OH stretching bands and at least 48 lattice modes for the LT sample. The
IR spectra differ not only in the number of bands, but also in the response of the bands to changes in pressure. The pressure
derivatives for the IR bands are higher for the HT polymorph indicating that the high symmetry form is more compressible than
the low symmetry form. Polarized, low-temperature single-crystal IR spectra indicate that in the LT-polymorph extensive ordering
occurs not only at the Mg sites but also at the hydrogen sites. 相似文献
32.
The strain developed due to creep is mainly proportional to the logarithm of the time under load, and is mostly proportional
to the stress and temperature. At higher temperature the creep rate falls slowly with respect to time, and the creep strain
is proportional to a fractional power of time, with the exponent increasing as the temperature increases and reaching a value
approximately one-third at temperatures of about 0.5°C. At these temperatures, the creep increases with stress according to
a power greater than unity and possibly exponentially. It increases with temperature as (−U/kT), where U is an activation energy and k is Boltzman’s constant. There are different methods to determine the creep strain and the energy of Jog (B) including experimental
methods, multivariate regression analysis, and by numerical simulation. These methods are less cumbersome and time consuming.
In the present investigation, artificial neural network technique has been used for prediction of the creep strain and energy
of Jog (B). Two different networks have been tested and validated. Both the networks have four input neurons and one hidden
layer with five neurons, and one output neuron. The data for different rocks at temperatures up to 750°C under conditions
of compressive or tortional stress are taken from the literatures. The training and testing data sets used were 163 and 14,
respectively. To deal with the problem of overfitting of data, Bayesian regulation has been used and network is trained with
suitable training epochs. The coefficients of correlation among the predicted and observed values are found high and they
improve the confidence of the users. The mean absolute percentage error obtained are also very low. 相似文献
33.
GRAPES(Globe and Regional Assimilation and Prediction System)变分系统能够同化常规资料和非常规卫星资料,这些被同化的资料究竟对同化系统得到的分析场有何影响,目前国内外尚未见相关的研究文献。为此,首次采用基于信息熵信号自由度思想,诊断风云三号B星(FY3B)红外分光计(Infrared Atmospheric Sounder,IRAS)资料对GRAPES分析场的影响。诊断过程中,采用数值逼近方法,统计2012年12月24日18时到2013年1月22日00时共114个时次IRAS资料对GRAPES分析场影响,结果表明,IRAS中高层通道亮温资料对GRAPES分析场影响比地表通道20观测亮温的影响大,地表通道8和9观测亮温对分析场影响较大。前24个GRAPES变分同化时次每个时次IRAS通道亮温对分析场影响的贡献率分析结果显示,高层通道和H_2O通道贡献率较大。个例分析结果表明,在同化探空资料基础上加入IRAS资料后,温度和湿度增量场变化幅度较大,表明IRAS资料对分析场有降温和增湿作用。 相似文献
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自2007年以来, 黄海海域每年的5月初~8月中下旬浒苔(Ulva prolifera)会周期性地暴发与消亡,导致海洋生态环境被破坏以及经济损失。利用2014 年的HJ-1A/1B遥感影像, 利用神经网络监督分类及RULE规则影像重分类动态阈值法, 对2014年的浒苔的漂移路径、各时期影响的海域面积、分布面积以及暴发高峰期的最大面积进行了动态监测。结果表明, 2014年浒苔持续时间为101 d, 5月中旬开始在江苏省盐城市近海出现零星斑点, 分布面积为2.299 km2, 影响面积为1 744.799 km2; 6月初到6月中旬浒苔广泛分布于黄海海域, 分布面积扩大至1 367.145 km2, 达到当年的峰值; 从6月下旬开始, 浒苔进入衰退期, 浒苔分布面积、相对聚集密度均急剧缩小, 但影响面积的峰值出现在该时期; 8月初消亡于青岛附近海岸, 8月20日遥感影像已难以监测到浒苔的存在。2014年黄海海域浒苔经过了“出现—发展—暴发—衰退—消亡”5个发展阶段。 相似文献
36.
Generalised observations of wave characteristics on near‐horizontal shore platforms: Synthesis of six case studies from the North Island,New Zealand
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Most field studies of wave processes on shore platforms in front of eroding cliffs focus on a single site, revealing aspects of wave dynamics at that location. Here, we analyse data from six platforms around northeastern New Zealand and describe the fundamental control of shore platform width, gradient and elevation on wave processes, including greater attenuation of short‐period waves at lower tidal stages and increases in longer period wave energy towards the cliff toe. These data suggest that empirical formulae developed from coral‐reef environments provide better predictions of wave height on platforms than formulae currently used in shore platform models. 相似文献
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基于历史文献、古地图和现代遥感数据,引入历史学古代城镇形态复原方法,复原(提取)明代以来长江三角洲地区113座城镇7个时间断面(1461年、1820年、1930年、1970年、1980年、2000年和2010年)下的城镇边界,采用扩张速率、扩张效率、首位度指数和位序-规模法则,分析了近六百年来区域城镇空间与城镇体系等级规模演变格局。取得以下研究结果: 研究时段内,区内城镇用地总规模由205.98 km2增加到6442.19 km2,扩大了31.27倍;城镇扩张经历了萌芽阶段(明清时期)、起步阶段(民国至改革开放前夕)、成长阶段(改革开放至2000年)和加速阶段(2000—2010年),城镇扩张速率不断加快,但扩张效率有待提升; 在城镇等级规模空间格局上,明清时期南京与苏州为区内的一级城镇,民国后,上海逐渐取代其地位,从五级城镇发展成为区域核心城镇,四级以上城镇主要集中在长江干流沿岸和太湖流域,五级以下城镇大多集中在安徽;城镇体系呈首位型分布,城镇首位度较高,且改革开放后的城镇首位度较明清与民国时期要高,不同等级规模城镇之间差距扩大,大城镇优势较强。近30年,长江沿岸城镇发展加速,苏锡常都市圈、南京都市圈等逐渐形成并快速发展。 相似文献
40.