湖泊沉积有机质的地球化学记录与古气候古环境重建

与深海沉积与冰芯记录相比,湖泊沉积主要反映区域气候变迁史,可以揭示百年、甚至十年尺度的古气候事件,是高分辨率古环境、古气候重建的理想场所.传统的地质地球化学方法主要侧重于宏观物理 /化学特性描述和孢粉学的研究,近 10年来,沉积有机质分子碳、氢同位素地球化学技术的渗入,使研究工作从传统的宏观、微观层次向分子级水平发展,对诸如古生产率估算、C3/C4植被演替史、古二氧化碳分压及古温度计算等深层次问题解决提供了强有力支持.本文评述了湖泊沉积有机质分子与碳、氢同位素地球化学记录及其在区域古环境、古气候研究中的应用前景.     

Variations in silicate concentration affecting photosynthetic carbon fixation by spring phytoplankton assemblages in surface water of the Strait of Malacca

The Strait of Malacca (SoM), the world’s busiest sea-route, is increasingly polluted as the rapid development of world trades, affecting phytoplankton primary productivity therein. The variations of surface phytoplankton biomass, size-structure and carbon fixation were investigated across the SoM during the spring period (May 4 to 9, 2011). Chlorophyll a concentration increased from 0.12 μg/L at the northwest entrance of the SoM to a maximal 0.63 μg/L at narrowest section, and decreased to 0.10 μg/L at the southeast entrance. Photosynthetic carbon fixation by phytoplankton coincided well with Chl a biomass, and increased from 10.8 to 22.3 μg C/(L d), then decreased to 9.21 μg C/(L d); while the carbon fixation rate showed an inverse pattern to the changes of Chl a, and decreased from 87.1 to 35.5 μg C/(μg Chl a d) and increased thereafter to 95.3 μg C/(μg Chla·d). Picophytoplankton cells (<3 μm) contributed to more than 60% and 50% of the total Chl a and carbon fixation at both the entry waters; while the contributions of pico-cells decreased sharply to the minimum of 18.3% and 27.5% at the narrowest part of the SoM. In particular, our results showed that the silicate concentration positively regulated Chl a biomass and carbon fixation, reflecting that the higher silicate favoured the growth of phytoplankton and thus led to higher primary production in this strait.     

金刚石与深部碳循环

深部碳循环是全球碳循环研究中不可或缺的部分。较之表层碳,人类对地球深部碳储库的储量、碳的迁移方式和交换量都缺乏清晰认识。作为来自地球深部的碳单质矿物,金刚石是研究深部碳循环的绝佳样品。近年来原位微区分析技术的突飞猛进为研究金刚石及深部碳循环提供了良好条件。文中对表层与深部碳交换、深部碳储库及金刚石矿物学性质进行了介绍,并通过金刚石及其包裹体的稳定同位素组成,探讨了金刚石的形成机制及含碳流体/熔体的性质与来源问题。     

土壤碳储量计算中不同插值方法对比研究——以吉林省大安市为例

土壤碳储量问题是大气温室效应和全球变化研究的热点问题。本文采用“单位土壤碳量”方法,计算了吉林省大安市表层土壤有机碳总储量和平均土壤有机碳储量,以为全球碳循环研究提供精确的基础数据。分析和比较了反距离加权、全局多项式、局部多项式、径向基函数和普通克里格等不同插值模型对表层单位土壤有机碳储量空间插值结果的影响,结果表明全局多项式插值的均差最小,径向基函数中张力样条法的平均绝对误差最小,普通克里格法的标准差最小。综合分析来看,普通克里格的有理二次方程式模型插值精度最高。      

利用POLDER多角度偏振数据反演陆上气溶胶光学厚度的群组残差最优方法

陆上气溶胶光学厚度(AOD)反演作为气候、环境领域的一大研究方向,偏振多角度遥感在这个方向上有其特有的优势.本文使用法国POLDER(Polarization and Directionality of Earth's Reflectance)1 级偏振多角度资料,提出了一种针对气溶胶反演的群组残差最优方法,反演了气溶...     

Optical Response of the Atmosphere During the Caribbean Total Solar Eclipses of 26 February 1998 and of 3 February 1916 at Falcón state,Venezuela

An investigation of the optical response of the atmosphere before, during, and afterthe total solar eclipse of 26 February 1998 at the Caribbean Peninsula of Paraguaná (Falcón State) in Venezuela, was made by measuring photometrically the intensity of the sky brightness in three strategic directions: zenith, horizon anti-parallel or opposite the umbra path, and horizon perpendicular to this path. From these measurements, and by applying in an inverse way an empirical photometric model, very rough estimations of theextinction coefficient, and also of the average optical depth, were obtained in one of these particular directions. However based on meteorological measurements such as those of relative humidity and temperature, and applying a different model, a better estimation in the visual of the total global extinction coefficient of the sky (except the horizon), were made considering the contribution of each component: atmospheric aerosol, water vapour, ozone and Rayleigh scattering. It is shown that this global coefficient is mostly dependent upon aerosol extinction. In spite of the strong reduction of sky brightness photometrically observed during the totality, the results show that the sky was not dark. This is confirmed by the results obtained for the total global extinction coefficient. Additionally it is estimated that the total solar eclipse that took place also in Falcón State, Venezuela, at the beginning of the last century on 3 February 1916, was 30% darker that the 1998 eclipse, and that atmospheric aerosol played a relevant and similar role in the scattering of sunlight during the totality as it was for 1998's. Visual observations made during each event, which show that at length only one or two bright stars could be seen in the sky, support the results obtained for both eclipses.     

南方地区页岩气储层工业组分与有机碳测井计算方法

通过南方地区页岩气藏的储层特征和赋存方式的研究,认为页岩各组分含量的准确计算直接关系到含气量评价的精度.以南方3个工区计74块岩心样品组分分析实验为基础,提出页岩的五元工业组分体积模型和体积含量计算方法.对其中表征页岩含气性最关键组分——干酪根（有机碳）含量,分别建立与三孔隙度、电阻率、铀元素等5条测井曲线的线性关系.通过有机碳敏感性分析,引入两种多元回归计算有机碳含量方法,确定了适用于3个南方地区有机碳含量的公式.3口探井应用实例表明该方法符合页岩气藏的实际,提高了页岩气层各组分含量的计算精度,取得了预期的地质效果.     

实施低碳水泥标准的影响及协同减排效果分析

采用MAP-CGE模型,模拟了我国水泥行业实施低碳水泥标准对不同生产工艺产出、能耗及污染排放的影响,测算了对其边际减排成本和均衡价格的影响,分析了对不同污染物的协同减排效果。模拟结果表明：实施低碳水泥标准有利于水泥生产工艺的升级换代,并有助于水泥行业节能减排;在现有技术水平下,水泥行业在减排1 t CO2的同时将带来约1.17 kg的SO2减排量和4.44 kg的NOx减排量;实施低碳水泥标准对于水泥行业控制NOx排放很有利;但水泥行业也需承担减排成本并导致其均衡价格的小幅上升。     

美国碳排放权交易体系评析

通过评析当前美国最主要的两类碳排放交易体系--自愿减排和总量控制与交易体系的发展现状与前景得到,自愿减排终因需求不足而难以维系,只有建立碳排放的总量控制与交易体系,才能进行持续的碳交易,完成减碳目标。借鉴美国区域温室气体行动、西部气候倡议和加州总量控制与交易体系的经验,建议中国选择具有一定基础的省份或行业试行总量控制与交易体系,初期排放配额的分配以免费发放为主,拍卖为辅,并严格控制碳抵消的数量和范围等,然后再逐步过渡到拍卖方式。