中国煤中的氟

氟是煤中所含微量元素中丰度较高的少数几种元素之一。对我国581个煤样分析数据的统计表明,多数样品氟含量处于20～300mg/kg,平均40mg/kg,个别超过1000mg/kg。氟在煤中赋存状态有:①独立的氟矿物;②以类质同象存在于矿物晶格内;③被矿物吸附;④以F-离子形式溶于水中。在煤中所含微量元素中,氟是对植物、动物和人体健康的影响面最大的元素。     

DEM modeling of pullout behavior of geogrid reinforced ballast: The effect of particle shape

The performance of a geogrid reinforced system depends heavily on the properties of interface between the interacting components (i.e., backfill soil and geogrid inclusion). The comprehensive understanding of soil-geogrid interaction requires proper consideration of the true aperture geometry and the discontinuous nature of backfill soil. Based on the calibrated parameters, this paper presents a simulation procedure using PFC3D to reproduce the realistic pull-out behaviors of a triaxial geogrid embedded in various ballast aggregates with diverse particle shapes. The load transfer behaviors across the interacting components have been visualized in terms of the evolution of bond forces along the geogrid and the evolution of contact forces across the particle assembly. Meanwhile, the inherent microscopic changes accounting for the regression of macroscopic strength and the correlation between macro pull-out force and micro anisotropy parameters have been addressed. In addition, the differences in macro performance and the particle responses produced by different shapes of particles are also systematically discussed to justify the significant role of particle geometry. The findings obtained in this study are expected to provide better understanding of soil-geogrid interaction and the improved interlocking caused by irregular ballast geometry.     

Associated terrestrial and marine fossils in the late-glacial Presumpscot Formation, southern Maine, USA, and the marine reservoir effect on radiocarbon ages

Excavations in the late-glacial Presumpscot Formation at Portland, Maine, uncovered tree remains and other terrestrial organics associated with marine invertebrate shells in a landslide deposit. Buds of Populus balsamifera (balsam poplar) occurred with twigs of Picea glauca (white spruce) in the Presumpscot clay. Tree rings in Picea logs indicate that the trees all died during winter dormancy in the same year. Ring widths show patterns of variation indicating responses to environmental changes. Fossil mosses and insects represent a variety of species and wet to dry microsites. The late-glacial environment at the site was similar to that of today's Maine coast. Radiocarbon ages of 14 tree samples are 11,907 ± 31 to 11,650 ± 50 ¹⁴C yr BP. Wiggle matching of dated tree-ring segments to radiocarbon calibration data sets dates the landslide occurrence at ca. 13,520 + 95/−20 cal yr BP. Ages of shells juxtaposed with the logs are 12,850 ± 65 ¹⁴C yr BP (Mytilus edulis) and 12,800 ± 55 ¹⁴C yr BP (Balanus sp.), indicating a marine reservoir age of about 1000 yr. Using this value to correct previously published radiocarbon ages reduces the discrepancy between the Maine deglaciation chronology and the varve-based chronology elsewhere in New England.     

深层地震资料采集的若干问题

本文着重叙述检波器组合效应、最大炮检距的选择、深反射层的共反射点离散效应等项技术和问题。另外讨论了比较理想的深层资料采集方法。     

水-岩化学作用对岩体变形破坏力学效应研究进展

水—岩化学作用对岩体变形破坏力学效应的研究涉及力学和化学两方面,也即为地球化学与岩体力学两个研究领域的交叉。针对水化学作用对岩体力学性质的影响机理,较系统地总结了该研究领域中的现状和研究新进展,分析了其研究方法,指出了今后的研究方向和主要研究内容,并认为此方面的研究将在工程地质学中占重要地位。     

大型复杂采空区注浆效果检测方法研究

大型复杂采空区由于具有分布范围广、多层、厚度及埋深不等和周围岩性复杂等特点,导致其注浆质量检测难度较大,目前尚无可靠的系统检测方法。结合某采空区注浆工程实践,对浆液结石体的电阻率进行了现场试验,得到了浆液结石体的视电阻率范围为93～130m,与采空区及围岩均有较大差异。运用电测深法和电磁波CT对采空区注浆前后进行检测,发现注浆后浅部0～30m范围内,视电阻率普遍得到降低且变得相对均匀稳定; 深部低阻异常在注浆后电阻率也得以减弱,且均匀范围明显扩大; 电磁波吸收系数在40～70m范围内得到提高约25%。钻探取心发现,多数孔内可见注浆结石体; 检测孔的后期注浆中, 10个孔的注浆量均不大于周围相邻4个孔的注浆量平均值的15%。对以上检测结果分析可知:采空区在物性特征上表现为较低的电磁波吸收系数,注浆以后升高; 地下水位之上的采空区表现为较高的电阻率,注浆之后降低,地下水位以下的采空区则反之。注浆前后采空区物探差异明显,本段落采空层的浆液充填效果较好,几种检测方法的结果具有良好的对应关系。同时表明,采用全域检测的电测深和局部详查的电磁波CT相结合的物探方法,与钻探取心结果及检测孔后期注浆数据进行分析对比,可以对大型复杂采空区注浆效果进行有效检测和评价,可为类似采空区提供借鉴。     

考虑Hansbo渗流的二维Biot固结有限元分析

为进一步深入研究弹性饱和黏性土地基的二维固结机制,引入Hansbo渗流方程描述固结过程中的非达西渗流,修正Biot二维固结方程。基于加权残数法,给出相应的有限元数值求解格式。通过和饱和黏性土一维非达西渗流固结理论有限体积法数值结果的对比,证明数值计算方法的有效性。在此基础上,探讨Hansbo渗流参数对二维地基固结进程的影响。计算结果表明,在固结初期,Hansbo渗流将增强Mandel-Cryer效应,增大孔压的峰值,并延长孔隙水压力达到峰值的时间;在固结中后期,整个土层存在孔隙水压力滞后现象。同时,Hansbo渗流将阻碍地基沉降的发展。而且,上述影响会随着Hansbo渗流参数的增大而更加明显。     

粉质黏土填料在K30试验加载进程中的变形时间效应状态分析

变形稳定标准和分级加载制度是影响K30试验效率和准确性的关键因素,与加载进程中填土的变形时间效应状态密切相关。开展了3组最优含水率下压实系数K分别为0.90、0.95和1.00填土模型的小型平板载荷试验,获得了不同荷载作用下填土变形时程曲线和弹塑性变形数据,讨论了在K30试验加载进程中填土变形状态的变化及其对加载稳定时间的影响。试验表明：良好压实的粉质黏土填料,在K30试验进程中的变形以弹性为主,处于缓慢收敛状态,随着加载级数增加,塑性变形比例逐渐增大,变形时间效应呈现出由微弱进入明显状态的演化趋势,变形1.25 mm对应于缓慢收敛中的微弱时间效应亚状态;“变形速率不超过0.01 mm/min”变形稳定标准分级加载时间随时间效应指数呈加速增长规律,能在保证试验精度的基础上提高试验效率;以最大荷载下填土变形时间效应不应超过显著状态、变形量不小于1.25 mm为约束条件,针对5级加载、0.04 MPa荷载增量的加载制度,可得K30试验的适宜范围为60～160 MPa/m。     

信息化施工技术在保护某厂濒危烟囱中的应用

通过地处上海某厂锅炉房濒危烟囱北侧仅5米处的实验楼基础施工，详尽介绍了施工过程中保护濒危烟囱的防护工程对策，以及采用信息化施工技术而取得的良好经济效益。     

上海夏灌水现状及其开发利用

本文对上海市区地下含水层中滞留的夏灌余水的现状进行了调查分析与评价,对其开发利用的可行性作了论证,以助于今后更好地开展“夏灌冬用”工作。