北极河流径流量变化及影响因子分析

利用最新的北极径流资料(R-arcticNET V3.0和Arctic RIMS),对进入北冰洋的4条主要河流的季节及年代际变化进行诊断分析。结果表明:入海径流在4-6月的大幅增加主要是由气温达到融点后积雪融化造成的,降水的作用次之。总的来说,欧亚区域在过去的70年里入海径流量是增加的,而北美区域在近30年里入海径流量是减小的,但注入北冰洋的径流总量是增大的。值得注意的是入海径流的年代际变化在不同季节增减趋势显著不同,夏季和秋季径流量减小,而其他两个季节径流量增大。进一步分析了影响入海径流变化的一些气候因子,结果表明:北大西洋涛动(北太平洋指数)与欧亚(北美)区域的冬、春季径流量存在正相关。春季气温与春季径流量呈正相关,而与夏季径流量呈负相关。降水与径流量基本上为同步正相关。春季积雪覆盖面积与春季径流量为负相关,而与夏季径流量为正相关,夏季积雪覆盖面积与夏季的径流量为正相关。     

Homogenization of the Daily Land Surface Temperature over the Mainland of China from 1960 through 2017

Land surface temperature(LST) is one of the most important factors in the land-atmosphere interaction process. Raw measured LSTs may contain biases due to instrument replacement, changes in recording procedures, and other non-climatic factors. This study attempts to reduce the above biases in raw daily measurements and achieves a homogenized daily LST dataset over China using 2360 stations from 1960 through 2017. The high-quality land surface air temperature(LSAT)dataset is used to correct the LST warming biases especially evident during cold months in regions north of 40°N due to the replacement of observation instruments around 2004. Subsequently, the Multiple Analysis of Series for Homogenization(MASH) method is adopted to detect and then adjust the daily observed LST records. In total, 3.68 × 103 effective breakpoints in 1.65 × 106 monthly records(about 20%) are detected. A large number of these effective breakpoints are located over large parts of the Sichuan Basin and southern China. After the MASH procedure, LSTs at more than 80% of the breakpoints are adjusted within +/– 0.5°C, and of the remaining breakpoints, only 10% are adjusted over 1.5°C.Compared to the raw LST dataset over the whole domain, the homogenization significantly reduces the mean LST magnitude and its interannual variability as well as its linear trend at most stations. Finally, we perform preliminary analysis upon the homogenized LST and find that the annual mean LST averaged across China shows a significant warming trend [0.22°C(10 yr)–1]. The homogenized LST dataset can be further adapted for a variety of applications(e.g.,model evaluation and extreme event characterization).     

水流紊动对泥沙絮凝的影响

主要研究水流紊动对泥沙絮凝的影响。认为水处理方面的絮凝动力学理论可用于研究泥沙絮凝问题。根据试验实测资料及国外有关试验结果研究表明,在紊动状态下,泥沙絮凝存在两个阶段,每个阶段中紊动对泥沙絮凝的影响也有所不同。     

风沙流中沙粒浓度分布的实验研究

利用粒子图像测速技术（PIV）,在风洞内对与天然沙接近的石英沙风沙流沙颗粒浓度沿高度分布进行了研究。对 3种不同轴线风速研究结果表明,风沙流中沙粒浓度沿水平方向基本不变,而随高度呈指数衰减,而且其衰减速率与风速密切相关。风速越大,衰减速率越慢;风速越小,衰减速率越快。风沙运动一旦发生时,靠近沙床表面的沙粒浓度随风速变化很小,可以认为趋于稳定,达到最大值。     

南黄海中部隆起印支面剥蚀量恢复与演化过程——来自CSDP-2井的证据

南黄海中部隆起是下扬子地块向海域的延伸,是当前海相盆地海域资源调查的潜力区。中部隆起自印支期以来经历多期构造隆升、挤压及剥蚀作用,显著影响了盆地油气资源的形成和分布。2016年底完钻的大陆架科学钻探CSDP-2井首次在中部隆起钻穿印支不整合面,该不整合面在中部隆起既是新近系-第四系底界,又是下三叠统灰岩的顶界,横向延伸平缓,上、下地层产状差异巨大,下伏地层具有强烈的挤压变形及逆冲推覆,呈现显著的角度不整合接触关系。本次研究基于泥岩声波时差法计算的印支面地层剥蚀量约为1200 m,镜质体反射率法计算的剥蚀量约为1400 m,与地层趋势面估算的剥蚀量基本一致。结合南黄海盆地演化过程分析,认为中部隆起大致于晚三叠世开始隆升,至晚白垩世期间经历快速剥蚀,并可能延续到渐新世末期。在当前南黄海盆地资源调查逐步转向中、古生界海相残留盆地之际,依托实际钻探资料进行印支不整合面研究及剥蚀量恢复对于恢复盆地构造-热演化史及评价油气资源等均具有重要的现实意义。     

利用探地雷达观测分析早春融雪前后沙丘表层土壤含水量的时空分布

积雪融水是古尔班通古特沙漠春季植物发育的重要水源, 快速获取早春沙丘的土壤水分变化具有十分重要的生态学意义. 2010年3、 4月分别使用探地雷达进行了多次测量实验, 结果显示: 1)融雪初期, 沙丘顶部土壤的自由水含量最大, 阳坡次之, 且融雪水在重力作用下沿坡面侧向缓慢流动, 在坡底汇集, 主导了融雪初期乃至整个春季沙丘表层土壤水分的分布格局; 2)融雪后期, 由于阴坡积雪和冻土消融相对滞后, 表层土壤含水量略高于阳坡, 而沙丘顶部由于融雪最早且融雪期间水分转移最多而表面最为干燥; 3)通过与时域反射仪的同步测量结果对比, 探地雷达的测量精度被有效控制在0.03范围内, 且探地雷达提供的连续数据更有利于从细节上把握土壤含水量的变化趋势, 为中小尺度土壤水分的动态研究提供了一种科学、 有效的技术手段.     

Improved Platinum-Group Element Extraction by NiS Fire Assay from Chromitite Ore Samples Using a Flux Containing Sodium Metaphosphate

Many chromite-rich rocks contain relatively high concentrations of the platinum-group elements (PGE). In many cases, the phases carrying PGE occur as either platinum-group minerals (PGM) or as base metal sulfides in solid solution in sulfides. In some cases, such as the UG-2 unit of the Bushveld Complex, the PGM are occluded inside chromite grains. Chromites are notably difficult to dissolve in most fluxes and if the chromite contains some PGM the possibility exists that not all the PGE will be recovered during fusion. In this work, shortcomings in published methods of analysis based on the nickel sulfide fire assay procedure were investigated and a new procedure developed based on the addition of sodium metaphosphate to the fusion mixture. Optimum composition of the fusion mixture was found to be 10 g sodium metaphosphate and 9 g silica to 10 g sample, 15 g sodium carbonate, 30 g lithium tetraborate, 7.5 g nickel and 4.5 g sulfur to achieve complete dissolution of chromite grains. The new flux mixture was evaluated by the analysis of reference material CHR-Pt+ (which is known to contain PGM inside chromite grains) and no undissolved chromite grains were found in the glassy slag. Analysis of the nickel sulfide beads from this fire assay using neutron activation analysis showed similar results for Rh and Ru when compared with published conventional true (or accepted) values, while Au, Ir, Os, Pd and Pt values determined here were 10 to 30% higher than the corresponding published conventional true values. It was concluded that the addition of sodium metaphosphate improved chromite dissolution in the flux and appears to improve PGE recovery.     

Fe3+纳米胶体颗粒的光吸收边蓝移与溶液中Al/Fe比的关系

合成了n（Al）／n（Fe）和碱化度不同的45个聚合氯化铝铁（PAFC）样品,进行了光谱分析,结果显示光吸收边蓝移或红移以及Fe（Ⅲ）羟基氧化物和Al-Fe共聚体纳米胶体颗粒大小分布与溶液的Al／Fe比和碱化度（B=[OH]／[Al＋Fe]）密切相关。电镜观察和电子衍射分析表明：Al（Ⅲ）的加入使Fe（Ⅲ）羟基氧化物和Al-Fe共聚体纳米胶体颗粒变小、有序度降低是造成PAFE光吸收边蓝移和保持胶体颗粒在亚稳定状态下存在的重要原因。当n（Al）／n（Fe）〉8：2后,PAFC溶液中Fe（Ⅲ）羟基氧化物和Al-Fe共聚体胶体主要以〈10m的纳米颗粒形态存在,对应的光谱能级提高到26000cm^-1以上,且各种曰值下Fe^3＋的光谱能级趋于一致。这表明,在大量Al（Ⅲ）存在条件下,PAFE中Fe3^＋的所处的化学环境相似。点能谱分析显示,n（Al）／n（Fe）=4：6的样品中颗粒物的化学计量比最接近AlOOH,FeOOH,溶液的稳定性最差。     

An Overview of Dissolved and Suspended Matter Fluxes in the Loire River Basin: Natural and Anthropogenic Inputs

The spatial and temporal distributions of major elements were investigated in the surface waters and in associated suspended matter at two sites of the upper Loire basin (Orleans and Brehemont) between 1995 and 1998.According to geochemical and isotopic patterns, the dissolved load appears to result from a process of mixing rainwater inputs, weathering processes of carbonate and silicate bedrock, and agricultural and urban inputs. Natural inputs influence 60% of water chemical composition at both sites. Annual dissolved fluxes were estimated to be 1300 10³ t/y at Orleans and 1620 10³ t/y at Brehemont. Major elements are transported mainly in the dissolved fraction. After correcting for atmospheric and anthropogenic inputs, the silicate specific export rate was calculated to be 11 t/y/km² throughout the basin and the carbonate specific export rate to be from 47 t/y/km² at Orleans to 23 t/y/km² at Brehemont.The suspended load appears to result from at least two particle reservoirs: a silicate reservoir and a carbonate reservoir. The silicate reservoir has a detrital origin, mainly during periods of high flow, while the carbonate reservoir has a detrital origin during periods of high flow and an authigenic origin during periods of low flow. Of the total annual flow of suspended matter, this authigenic material represents 16% at Orleans, 25% at Brehemont and 37% in the fluvial part of the estuary. After correcting authigenic inputs, the specific export rate due to mechanical weathering was estimated to be 8 t/y/km² throughout the Loire basin.     

瑞雷波勘探在地下洞穴探测中的应用

利用瑞雷波勘探方法进行地下洞穴探测，在实际处理过程中，对场地所测得的面波频散曲线进行分类、归纳，并利用动力触探曲线对各种特征曲线所反映的地下洞穴情况进行标定，从而确定整个测区洞穴的空间分布规律。