天然有机质存在条件下的纳米颗粒与重金属协同行为研究

纳米颗粒与重金属元素相结合发生反应,可能产生一系列相互作用关系。这些作用过程是取决于多个环境条件共同作用的复杂过程,尤其是在土壤这种复杂的典型非均质环境介质中。这些作用关系可分为协同促进和拮抗抑制两大类关系。对于土壤中的重金属元素离子而言,纳米态粒子对其环境有效性究竟是协同促进还是拮抗抑制作用,关键取决于纳米粒子的表面修饰特性、二者间的界面反应以及反应后重金属元素的最终赋存状态这三个方面。协同促进或拮抗抑制作用与否则最终决定了这些污染重金属离子的生物可利用性和生态毒性响应。本文对近年来纳米颗粒-重金属共环境行为国内外研究现状进行综述讨论。纳米-重金属界面吸附解吸和土壤中迁移持留过程研究涉及多个热力学、动力学解析方法,科学家结合静态批实验和动态迁移实验等实验室模拟手段,对纳米颗粒、重金属离子、有机质三因子在土壤介质中的相互作用影响和共行为方式展开深入探讨。在重金属离子-纳米颗粒表面吸附机制、赋存形态以及重金属纳米吸附态土壤迁移固定机制研究中,多种定性表征方法的综合应用,如透射电镜(TEM)、X射线衍射(XRD)、X射线光电子能谱(XPS)、傅里叶变换红外光谱(FTIR)、X射线吸收近边结构光谱/扩展X射线吸收精细结构光谱(XANES/EXAFS)等方法相结合,被公认是揭示这一系列过程机制的重要技术手段。针对不同土壤环境中有机质存在条件,正确评价纳米态物质对重金属的迁移性及生物可利用性的影响作用,将为纳米环境效应评估和纳米修复技术等相关应用提供重要的数据支持和机理依据。     

FT-IR measurements of cold C3H8 cross sections at 7–15 μm for Titan atmosphere

We present absorption cross sections of propane (C₃H₈) at temperatures from 145 K to 297 K in the 690–1550 cm⁻¹ region. Pure and N₂-broadened spectra were measured at pressures from 3 Torr to 742 Torr using a Bruker IFS125 FT-IR spectrometer at JPL. The gas absorption cell, developed at Connecticut College, was cooled by a closed-cycle helium refrigerator. The cross sections were measured and compiled for individual spectra recorded at various experimental conditions covering the planetary atmosphere and Titan. In addition to the cross sections, a propane pseudoline list with a frequency grid of 0.005 cm⁻¹, was fitted to the 34 laboratory spectra. Line intensities and lower state energies were retrieved for each line, assuming a constant width. Validation tests showed that the pseudoline list reproduces discrete absorption features and continuum, the latter contributed by numerous weak and hot band features, in most of the observed spectra within 3%. Based on the pseudoline list, the total intensity in the 690–1550 cm⁻¹ region was determined to be 52.93 (±3%) × 10⁻¹⁹ cm⁻¹/(molecule cm⁻²) at 296 K; this value is within 3% of the average from four earlier studies. Finally, the merit of the pseudoline approach is addressed for heavy polyatomic molecules in support of spectroscopic observation of atmospheres of Titan and other planets. The cold cross sections will be submitted to the HITRAN database (hitran.harvard.edu), and the list of C₃H₈ pseudolines will be available from a MK-IV website of JPL (http://mark4sun.jpl.nasa.gov/data/spec/Pseudo).     

Storm‐dominated sedimentation in a protected basin fringed by coral reefs,Nara Inlet,Whitsunday Islands,Great Barrier Reef,Australia

Hydrodynamic data and samples of bed sediment were collected from Nara Inlet, a small incised embayment in the Whitsunday Islands, central Great Barrier Reef. Measured tidal currents in the inlet do not exceed 0.2 ms^–1 even at spring tides. Swell waves dominate much of the inner shelf of the Great Barrier Reef but are absent from in the inlet due to the presence of a fringing reef at the inlet mouth. On the silty sand floor of the inlet, particle size decreases towards the inlet head. Most of the bed is too coarse to be remobilised by fair‐weather wave and tides, and we predict that bedload sediment transport thresholds are only exceeded in the inlet during cyclones. The observed distribution of bed sediments is consistent with landward dispersal of sediment under storm conditions. Over 20 m of (presumably Holocene) sediments occurs in the inlet and the seismic character of the infill is consistent with the observed textural variation of the modern sediments. We infer that sediment accumulation on the floor of the inlet has been storm dominated throughout much of the Holocene.     

沙尘天气下输沙率的野外观测与分析

2014年7月—2014年8月借助风速仪、微梯度集沙仪,通过野外监测系统获取的试验数据,对塔中地区2014年7月—2014年8月沙尘天气过程中贴地层输沙率进行分析,得出:0～85 mm高度内,随着风速的增大,35～85 mm无论是绝对的输沙量还是相对的输沙量都减少。0～85 mm高度内,各层输沙率最大值均出现在风速为8 m·s-1左右,波动较为显著;最小值出现在6.5 m·s-1左右,波动不明显;沙尘天气中,输沙率最大值出现在5～15 mm高度,最小值出现在35～85 mm高度。扬沙天气中,风速9.2 m·s-1时,输沙率最大值在0～5 mm处。沙尘暴天气,拐点风速为7.5 m·s-1,7.5 m·s-1时,输沙率增加不显著,7.5 m·s-1时,输沙率增加显著。通过微梯度集沙仪获得的上述试验数据是风沙工程设计的一个极重要工程参数,具有重要的实践意义。     

希尔伯特-黄变换技术及在边界层湍流研究中的应用

大气边界层中的湍流运动可以视为由许多不同时空尺度的湍涡叠加形成的,谱分析方法可以将这些不同尺度的涡旋分离开来。在介绍希尔伯特-黄变换（HHT）的基础上,选取2011年4月16日00—01时（北京时）、05—06时、12—13时不同时段的大气湍流观测数据,采用希尔伯特-黄变换技术分析了内蒙古科尔沁沙地地区的谱分布特征,得到的各内在模函数对应的中心瞬时频率可以表现出不同尺度上的湍流波动,其中,包含周期为3—5和10—13 min的阵风和重力内波,并在希尔伯特边际谱中体现。三维希尔伯特谱分布表明湍流能量多集中在频率小于0.5 Hz的低频段;大气湍流脉动较强的时段,其内在模函数和希尔伯特谱也对应着较大的能量。对比传统的快速傅里叶变换（FFT）方法,希尔伯特-黄变换可以更清晰地表现出湍流的频谱分布。     

锡在高温气相里的迁移实验与南岭大厂 矿区100号矿体形成机制

我国著名大型锡矿大厂矿区的100号矿体是一个不规则的大脉状矿体,由质密锡铅锌矿石组成。该大脉矿体长度约1200多米。大厂矿区矿床形成过程有两个主要矿化阶段:早期锡石硫化物阶段和晚期的硫盐锡石多金属矿化阶段。矿物流体包体数据表明:早期形成于300~400℃(450℃)条件下,有高盐度流体包体与低盐度流体包体共存,流体处于从超临界流体进入近临界的气液两相不混溶区过渡阶段,有流体沸腾现象;晚期流体盐度变化小处于降温过程。而100号矿体形成于300~360℃,压力较低,仅为8.24MPa。本次研究设计一含锡溶液从超临界态进入亚临界态的气液不混溶区的实验,研究金属在气-液间再分配过程。实验模拟一个非平衡的气液分离反应动力学过程。重点研究含Sn-NaHCO3-HCl-H2O在近临界压(25~22MPa)和8~14MPa、380~300℃条件下,在亚临界态气-液两相不混溶区时相分离过程。气液分离实验是恒压降温过程。结果表明:近临界区NaHCO3-HCl-H2O的NaCl-H2O体系出现气-液(L-V)分离现象。降温远离临界点时,在V与L相里的Na、Cl浓度比:Na(V/L)、Cl(V/L)比值多数远小于1,Na、Cl主要分布在液相里。实验表明出现含Sn溶液的V-L两相分离过程,并且,Sn已在L-V间再分配,Sn(V/L)多数大于1。说明Sn多数情况下分布于气相里(贫NaCl富H2OCO2)。在380~250℃范围内NaCl-H2O-CO2体系包含的H2O-CO2体系也出现V-L两相不混溶区。实验发现H2O-CO2的L-V分离过程中,气相里HCO-3和CO2-3分布很少,CO2多。同时,锡在H2O-CO2的L-V间也存在再分配,锡分布在富CO2气体里。实验说明富CO2气体迁移锡。实验为地质解释提供依据,说明100号矿体形成于快速减压的大型裂隙条件下。在300~360℃下压力减低,使含金属流体迅速进入L-V两相不混溶区,气体快速迁移金属,快速沉积金属矿石。     

Experimental Study Optimizing Hole Cleaning-Cuttings Transport in Oil Drilling Engineering

With a clear understanding of the drilling fluid techniques and the cutting-taking mechanism, a new advanced model is set up for analyzing field data and quantitative forecast of cutting-taking mechanism. Therefore, a number of values affecting the drilling rate and the hole cleaning are studied over a wide range of parameters. Drilling data obtained under high-borehole-pressure conditions are analyzed to determine the causes of the reduction in rate of penetration (ROP) as the borehole pressure increases, which in some cases is caused by the buildup of rock debris under the bit. The theoretical achievement and testing conclusions can be very instructional for horizontal well drilling. Much higher annular velocities are required for effective hole cleaning in directional wells than in vertical wells. Highviscosity muds are observed to provide better transport than low-viscosity muds.     

基于拉格朗日方法评估青藏高原若尔盖地区水汽输送特征

干旱指数一直以来是评估一个地区地表干湿状态的有效标准.为了认识青藏高原若尔盖地区在极端干旱和湿润条件下的水汽空间分布格局,本文基于地面观测资料计算月尺度的标准化降水蒸散指数,提取2000-2017年青藏高原若尔盖地区的极端干旱和湿润状况,利用拉格朗日后向轨迹模型模拟该地区极端干湿条件下的水汽输送路径,并评估潜在水汽源地...     

辽宁区域性春旱的大气环流及影响因子分析

利用美国NCEP/NCAR的再分析资料、Hadley中心逐月海温资料(HadiSST)和辽宁地区逐日降水资料,对辽宁区域性春旱大气环流特征及影响因子进行分析。结果表明：乌山脊和东亚大槽减弱,位相比历年平均位相偏东,中高纬大气环流经向度减小,是导致中国辽宁区域性春季降水减少的大气环流背景;区域性春旱同期,大陆气压升高,海上气压降低;辽宁上空湿度明显小于历年均值,贝湖到中国辽宁一带盛行西北气流。区域性春旱前冬,辽宁上空200hPa高度场出现正距平;地面气温较历史同期偏高;Nino3海温异常偏低。