Reactive transport impacts on recovered freshwater quality during multiple partially penetrating wells (MPPW-)ASR in a brackish heterogeneous aquifer

The use of multiple partially penetrating wells (MPPW) during aquifer storage and recovery (ASR) in brackish aquifers can significantly improve the recovery efficiency (RE) of unmixed injected water. The water quality changes by reactive transport processes in a field MPPW-ASR system and their impact on RE were analyzed. The oxic freshwater injected in the deepest of four wells was continuously enriched with sodium (Na⁺) and other dominant cations from the brackish groundwater due to cation exchange by repeating cycles of ‘freshening’. During recovery periods, the breakthrough of Na⁺ was retarded in the deeper and central parts of the aquifer by ‘salinization’. Cation exchange can therefore either increase or decrease the RE of MPPW-ASR compared to the RE based on conservative Cl⁻, depending on the maximum limits set for Na⁺, the aquifer’s cation exchange capacity, and the native groundwater and injected water composition. Dissolution of Fe and Mn-containing carbonates was stimulated by acidifying oxidation reactions, involving adsorbed Fe²⁺ and Mn²⁺ and pyrite in the pyrite-rich deeper aquifer sections. Fe²⁺ and Mn²⁺ remained mobile in anoxic water upon approaching the recovery proximal zone, where Fe²⁺ precipitated via MnO₂ reduction, resulting in a dominating Mn²⁺ contamination. Recovery of Mn²⁺ and Fe²⁺ was counteracted by frequent injections of oxygen-rich water via the recovering well to form Fe and Mn-precipitates and increase sorption. The MPPW-ASR strategy exposes a much larger part of the injected water to the deeper geochemical units first, which may therefore control the mobilization of undesired elements during MPPW-ASR, rather than the average geochemical composition of the target aquifer.     

Magma associations in Ediacaran granitoids of the Cachoeirinha‒Salgueiro and Alto Pajeú terranes,northeastern Brazil: Forty years of studies

Granitic magmatism in the Cachoeirinha‒Salgueiro and Alto Pajeú terranes in the Transversal Zone Domain of the Borborema Province, northeastern Brazil, occurred in three main time intervals: 650–620 Ma, 590–560 Ma and 545–520 Ma. The oldest one is characterized by intrusions of magmatic-epidote (mEp) bearing calc-alkalic (some with trondhjemitic affinities) and high-K calc-alkalic plutons, synkinematic to the main regional foliation, under contractional tectonic regime, and exhibits T_DM < 2.0 Ga and ƐNd (0.6 Ga) from −1 to −4, and δ¹⁸O (zircon) values from 7.1 to 10‰_VSMOW. O- and Nd-isotope data for the 650‒620 Ma group of plutons is compatible with partial fusion of subducted oceanic basaltic crust (mEp-bearing calc-alkalic tonalites/granodiorites, equivalent to adakites). Voluminous intrusions in the 590–560 Ma interval are represented by abundant mEp-free high-K calc-alkalic, peralkalic, ultrapotassic, mEp-bearing high-K calc-alkalic, and less abundant shoshonitic magmas. Nd-model ages for this group of plutons vary from 1.5 to 2.5 Ga and ƐNd (0.6 Ga) ranges from −8 to −20; δ¹⁸O (zircon) varies from 6.4 to 7.9‰_VSMOW. Values of δ¹⁸O (zircon) for the 590‒560 Ma old group of plutons coupled with Nd isotope data are compatible with remelting of crustal (negative ƐNd, 1.6 to 2.0 Ga old) source rocks. O- and Nd-isotope data for this group of plutons are compatible with underplating of basaltic magma in the base of the lower crust for the high-K calc-alkalic granitoids, coeval to transcurrent movements along sigmoidal shear zones. Intrusion of one shoshonitic (Serrote do Arapuá), one calc-alkalic (Riacho do Icó) plutons besides the peralkalic Manaíra-Princeza Isabel dike set have witnessed this transition from contractional to transcurrent movements along shear zones, around 610‒600 Ma.     

Coupled Model of Two-phase Debris Flow, Sediment Transport and Morphological Evolution

The volume fraction of the solid and liquid phase of debris flows,which evolves simultaneously across terrains,largely determines the dynamic property of debris flows. The entrainment process significantly influences the amplitude of the volume fraction. In this paper,we present a depth-averaged two-phase debris-flow model describing the simultaneous evolution of the phase velocity and depth,the solid and fluid volume fractions and the bed morphological evolution. The model employs the Mohr–Coulomb plasticity for the solid stress,and the fluid stress is modeled as a Newtonian viscous stress. The interfacial momentum transfer includes viscous drag and buoyancy. A new extended entrainment rate formula that satisfies the boundary momentum jump condition(Iverson and Ouyang,2015) is presented. In this formula,the basal traction stress is a function of the solid volume fraction and can take advantage of both the Coulomb and velocity-dependent friction models. A finite volume method using Roe's Riemann approximation is suggested to solve the equations. Three computational cases are conducted and compared with experiments or previous results. The results show that the current computational model and framework are robust and suitable for capturing the characteristics of debris flows.     

南海上层经向翻转环流的低频变化

The low-frequency variability of the shallow meridional overturning circulation(MOC) in the South China Sea(SCS) is investigated using a Simple Ocean Data Assimilation(SODA) product for the period of 1900–2010. A dynamical decomposition method is used in which the MOC is decomposed into the Ekman, external mode, and vertical shear components. Results show that all the three dynamical components contribute to the formation of the seasonal and annual mean shallow MOC in the SCS. The shallow MOC in the SCS consists of two cells: a clockwise cell in the south and an anticlockwise cell in the north; the former is controlled by the Ekman flow and the latter is dominated by the external barotropic flow, with the contribution of the vertical shear being to reduce the magnitude of both cells. In addition, the strength of the MOC in the south is found to have a falling trend over the past century, due mainly to a weakening of the Luzon Strait transport(LST) that reduces the transport of the external component. Further analysis suggests that the weakening of the LST is closely related to a weakening of the westerly wind anomalies over the equatorial Pacific, which leads to a southward shift of the North Equatorial Current(NEC) bifurcation and thus a stronger transport of the Kuroshio east of Luzon.     

Three dimensional seismic studies of deep-water hazard-related features on the northern slope of South China Sea

Mass transport deposits and geological features related to fluid flow such as gas chimneys, mud diapirs and volcanos, pockmarks and gas hydrates are pervasive on the canyon dominated northern slope of the Pearl River Mouth basin of the South China Sea. These deposits and structures are linked to serious geohazards and are considered risk factors for seabed installations. Based on high resolution three dimensional seismic surveys, seismic characteristics, distributions and origins of these features are analyzed. A distribution map is presented and geometrical parameters and spatial distribution patterns are summarized. Results show that various groups of the mapped features are closely tied to local or regional tectonism and sedimentary processes. Mass transport complexes are classified as slides near the shelf break, initially deformed slumps on the flanks of canyons and highly deformed slumps on the lower slope downslope of the mouth of canyons. We propose them to be preconditioned by pore pressure changes related to sea level fluctuations, steep topography, and fluid and fault activities. Gas chimneys are mainly located in the vicinity of gas reservoirs, while bottom-simulating reflectors are observed within the gas chimney regions, suggesting gas chimneys serve as conduits for thermogenic gas. Mud diapirs/volcanos and pockmarks are observed in small numbers and the formation of pockmarks is related to underlying gas chimneys and faults. This study aims at reducing risks for deep-water engineering on the northern slope of South China Sea.     

近年来厄尔尼诺期间北赤道流输运的年际变化

为了研究近年来厄尔尼诺期间北赤道流输运的年际变化,本文利用海洋客观分析数据MOAA GPV(Grid Point Value of the Monthly Objective Analysis)以及P-vector方法计算了北太平洋绝对地转流,探讨了2001~2013年期间厄尔尼诺与北赤道流输运之间的关系。在此期间发生的4次厄尔尼诺事件中,北赤道流输运在2002~2003、2006~2007、2009~2010年的厄尔尼诺成熟期都出现了明显的增强,但是在2004~2005年的厄尔尼诺成熟期并没有明显的增强。进一步分析发现,在2002~2003年、2006~2007年、2009~2010年的厄尔尼诺成熟期,10°N以南的热带西北太平洋区域出现了负的海面高度异常和气旋式环流异常,这主要是由热带环流区域出现的西风异常和正的Ekman抽吸通过Rossby波西传到热带西太平洋区域所致;但是在2004~2005年厄尔尼诺成熟期,海面温度异常的分布明显不同,西风异常和正的Ekman抽吸异常明显北移,导致负的海面高度异常和气旋式环流异常出现在了10°N以北的西北太平洋区域,使得北赤道流输运在2004~2005年的厄尔尼诺成熟期没有明显的增强。     

Development and Extension of An Aggregated Scale Model: Part 1 – Background to ASMITA

Whilst much attention has been given to models that describe wave, tide and sediment transport processes in sufficient detail to determine the local changes in bed level over a relatively detailed representation of the bathymetry, far less attention has been given to models that consider the problem at a much larger scale (e.g. that of geomorphological elements such as a tidal flat and tidal channel). Such aggregated or lumped models tend not to represent the processes in detail but rather capture the behaviour at the scale of interest. One such model developed using the concept of an equilibrium concentration is the Aggregated Scale Morphological Interaction between Tidal basin and Adjacent coast (ASMITA). In this paper we provide some new insights into the concepts of equilibrium, and horizontal and vertical exchange that are key components of this modelling approach. In a companion paper, we summarise a range of developments that have been undertaken to extend the original model concept, to illustrate the flexibility and power of the conceptual framework. However, adding detail progressively moves the model in the direction of the more detailed process-based models and we give some consideration to the boundary between the two.     

The Sediment Source and Transport Trends around the Abandoned Yellow River Delta,China

Sediment source and transport trends are influenced by various hydrodynamic factors, and thus play important roles in sedimentary evolution and coastal stability. To examine sediment transport trends around the abandoned Yellow River delta promontory and its erosion mechanism, we employ empirical orthogonal function (EOF) analysis to study sedimentary characteristics and transport trends of the abandoned Yellow River delta in northern Jiangsu Province, China. The results showed that: (1) the main sediment source in the abandoned Yellow River delta is the submarine coastal slope and both sides of the abandoned Yellow River Delta; (2) the main hydrodynamics controlling sediment transport is the current that runs along the shore, coupled with waves, especially southward currents; (3) the sediment of the study area was redistributed under hydrodynamics; coarse sediments were eroded and broadly transported to the south. Therefore, it is concluded that the sediment sources and transport have important influence on coastal evolution: the sediment source area shows mass loss of deposits and erosion; deposits in the submarine coastal slope provide the source and were continuously eroded to provide materials to other places as a sediment source.     

对坡面径流挟沙力研究的几点认识

坡面径流挟沙力是土壤侵蚀过程模型的核心输入参数。在系统界定坡面径流挟沙力概念的基础上,深入分析了坡面径流水动力学特性和泥沙特性对坡面径流挟沙力的影响及其机制,受降雨、地形、土壤、植被、土地利用、结皮形成、细沟发育和砾石出露等多种因素时空变异的综合影响,坡面径流挟沙力具有强烈的时空变化特征,导致坡面径流挟沙力的测定较为困难。将确定挟沙力常用的方法划分为河流挟沙力方程修正法、推理法、模型模拟法和测量法,比较分析了不同方法的优缺点。未来的研究应该重点关注挟沙力测定方法与技术、坡面径流输沙过程的动力机制、典型土壤的挟沙力、挟沙力方程构建与验证及变化条件下坡面径流挟沙力等方面。     

Advances and Trends in Atmospheric Measurement by Smartphones*

With the development and popularization of smartphones and embedded sensors, a non-professional atmospheric measurement method by using smartphones carried by the public has been proposed recently. Without extra dedicated instrument, this method has many advantages, such as low hardware cost, high spatio-temporal resolution, and wide coverage, and it can supplement the professional atmospheric measurement methods, which has broad applications in the meteorological operation, scientific research, public service, and other fields. At present, the research on the non-professional atmospheric measurement in China is limited. In order to make full use of this method, this paper briefly outlined the states of existing smartphones and embedded sensors, highlighted the measurement of precipitation, air temperature, pressure, aerosols, and radiation by smartphones. To promote the development of smartphones for atmospheric measurement, future research should focus on mechanism study, available sources exploration, data quality control, big data processing, joining and matching with operation, research and service, etc.