Magnetic properties of soils from sites with different geological and environmental settings

Measurements of magnetic susceptibility of soils, reflecting magnetic enhancement of topsoils due to atmospherically deposited magnetic particles of industrial origin, are used recently in studies dealing with outlining polluted areas, as well as with approximate determination of soil contamination with heavy metals. One of the natural limitations of this method is magnetic enhancement of soils caused by weathering magnetically rich parent rock material. In this study we compare magnetic properties of soils from regions with different geological and environmental settings. Four areas in the Czech Republic and Austria were investigated, representing both magnetically rich and poor geology, as well as point-like and diffuse pollution sources. Topsoil and subsoil samples were investigated and the effect of geology and pollution was examined. Magnetic data including mass and volume magnetic susceptibility, frequency-dependent susceptibility, and main magnetic characteristics such as coercivity (Hc and Hcr) and magnetization (Ms and Mrs) parameters are compared with heavy metal contents. The aim of the paper is to assess the applicability of soil magnetometry under different geological-environmental conditions in terms of magnetic discrimination of dominant lithogenic/anthropogenic contributions to soil magnetic signature. Our results suggest that lithology represents the primary effect on soil magnetic properties. However, in case of significant atmospheric deposition of anthropogenic particles, this contribution can be clearly recognized, independent of the type of pollution source (point-like or diffuse), and discriminated from the lithogenic one. Different soil types apparently play no role. Possible effects of climate were not investigated in this study.     

Electrification of volcanic plumes

Volcanic lightning, perhaps the most spectacular consequence of the electrification of volcanic plumes, has been implicated in the origin of life on Earth, and may also exist in other planetary atmospheres. Recent years have seen volcanic lightning detection used as part of a portfolio of developing techniques to monitor volcanic eruptions. Remote sensing measurement techniques have been used to monitor volcanic lightning, but surface observations of the atmospheric electric Potential Gradient (PG) and the charge carried on volcanic ash also show that many volcanic plumes, whilst not sufficiently electrified to produce lightning, have detectable electrification exceeding that of their surrounding environment. Electrification has only been observed associated with ash-rich explosive plumes, but there is little evidence that the composition of the ash is critical to its occurrence. Different conceptual theories for charge generation and separation in volcanic plumes have been developed to explain the disparate observations obtained, but the ash fragmentation mechanism appears to be a key parameter. It is unclear which mechanisms or combinations of electrification mechanisms dominate in different circumstances. Electrostatic forces play an important role in modulating the dry fall-out of ash from a volcanic plume. Beyond the local electrification of plumes, the higher stratospheric particle concentrations following a large explosive eruption may affect the global atmospheric electrical circuit. It is possible that this might present another, if minor, way by which large volcanic eruptions affect global climate. The direct hazard of volcanic lightning to communities is generally low compared to other aspects of volcanic activity.     

东北夏季气温变异的区域差异及其与大气环流和海表温度的关系

利用1951～2000年中国东北地区23个台站资料，对东北夏季气温的时空分布进行了研究，发现其变化除具有整体的一致性外，东北南部和北部的夏季气温在年际和年代际时间尺度都表现出很大不同，其中北部区域的夏季气温在1987～1988年间发生了一次显著的气候突变. 另外，剔除夏季气温全区一致变化的年份后，南北两区夏季气温与大气环流和海表温度的关系表明：突变前，影响北部和南部冷/热夏季的大气环流形势存在显著的不同，关键海域亦有很大差异：影响南部的为中纬度西太平洋和印度洋部分海域，影响北部的主要为ENSO事件；突变后，两区的夏季气温及相应大气环流和关键海区都趋于一致. 在整个分析时段内，北部夏季气温与东亚夏季风存在显著负相关，而南部的关系则不明显.     

PM10 and heavy metal measurements in an industrial area of southern Italy

Atmospheric particulate concentrations and heavy metal content are measured from March to July 2001 at an industrial site located in a rural zone of the southern Italy. PM₁₀ samples are collected by a low-volume sampler and each sample is analysed by AAS techniques for its content of Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn. We measure also temperature, atmospheric pressure and relative humidity, and we collect anemometric data. The study purpose is the investigation of pollutant levels in an industrial area located in a rather unpolluted region and the characterization of the correlation structure among particulate concentrations, heavy metal content and local meteorological parameters. Data analysis is carried out by means of univariate and multivariate statistical methods. In the investigated period, the average value of PM₁₀ daily concentrations (24 μg Nm^− 3) does not exceed the national standard of 40 μg Nm^− 3 and only nine values are higher than the European daily limit value of 50 μg Nm^− 3. Particularly, the occurrence of two anomalous values (183 μg Nm^− 3 in 3 March and 94 μg Nm^− 3 in 22 June) seems to be related to no-local events as confirmed both by in situ data measured in the AQM network of Potenza city (about 10 km far from the study area) and by remote measurements performed in the same days. Regarding the heavy metal levels, we observe high levels of Cr (34 ng Nm^− 3), Ni (85 ng Nm^− 3) and Zn (214 ng Nm^− 3) in agreement with the local industrial source pattern. The multivariate analysis, carried out using meteorological parameters as exogenous variables, allow to evaluate the role of the different variables as driving factors of the correlation structure among the metals.     

Statistics of Scalar Fields in the Atmospheric Boundary Layer Based on Large-Eddy Simulations. Part II: Forced Convection

Forced convection in a quasi-steady atmospheric boundary layer is investigated based on a large-eddy simulation (LES) model. The performed simulations show that in the upper portion of the mixed layer the dimensionless (in terms of mixed layer scales) vertical gradients of temperature, humidity, and wind velocity depend on the dimensionless height z/z _i and the Reech number Rn. The peak values of variances and covariances at the top of the mixed layer, scaled in terms of the interfacial scales, are functions of the interfacial Richardson number Ri. As a result expressions for the entrainment rates, in the case when the interfacial layer has a finite depth, and a condition for the presence of moistening or drying regimes in the mixed layer, are derived. Profiles of dimensionless scalar moments in the mixed layer are proposed to be expressed in terms of two empirical similarity functions F _m and F _i , dependent on dimensionless height z/z _i , and the interfacial Richardson number Ri. The obtained similarity expressions adequately approximate the LES profiles of scalar statistics, and properly represent the impact of stability, shear, and entrainment. They are also consistent with the parameterization proposed for free convection in the first part of this paper.     

Product study of the reaction of OH radicals with isoprene in the atmosphere simulation chamber SAPHIR

Atmospheric oxidation of isoprene and its oxidation products methacrolein (MACR) and methyl vinyl ketone (MVK) have an important impact on the photochemical activity in the boundary layer, in particular in forested areas. The oxidation of isoprene by OH radicals was investigated in chamber experiments conducted under tropospheric conditions in the atmosphere simulation chamber SAPHIR at the Research Center Jülich. The aim was to determine the product yield of MVK and MACR in the OH-induced isoprene oxidation and the rate constant of their reaction with OH under real atmospheric conditions. The recently published updated degradation scheme for isoprene from Geiger et al. (2003) was used to determine rate constants and product yields. The fractional yields in the isoprene peroxy radical reaction with NO were found to be 0.41±0.03 for MVK and 0.27±0.03 for MACR. The rate coefficient for MACR with OH was found to be in very good agreement with the recommended value of IUPAC Atkinson (Atkinson et al., 2005). while the rate coefficient for MVK with OH was 27% lower.     

Simulation of a Stably Stratified Atmospheric Boundary Layer Using One-Dimensional Turbulence

One-dimensional turbulence (ODT) is a single-column simulation in which vertical motions are represented by an unsteady advective process, rather than their customary representation by a diffusive process. No space or time averaging of mesh-resolved motions is invoked. Molecular-transport scales can be resolved in ODT simulations of laboratory-scale flows, but this resolution of these scales is prohibitively expensive in ODT simulations of the atmospheric boundary layer (ABL), except possibly in small subregions of a non-uniform mesh.Here, two methods for ODT simulation of the ABL on uniform meshes are described and applied to the GABLS (GEWEX Atmospheric Boundary Layer Study; GEWEX is the Global Energy and Water Cycle Experiment) stable boundary-layer intercomparison case. One method involves resolution of the roughness scale using a fixed eddy viscosity to represent subgrid motions. The other method, which is implemented at lower spatial resolution, involves a variable eddy viscosity determined by the local mesh-resolved flow, as in multi-dimensional large-eddy simulation (LES). When run at typical LES resolution, it reproduces some of the key high-resolution results, but its fidelity is lower in some important respects. It is concluded that a more elaborate empirically based representation of the subgrid physics, closely analogous to closures currently employed in LES of the ABL, might improve its performance substantially, yielding a cost-effective ABL simulation tool. Prospects for further application of ODT to the ABL, including possible use of ODT as a near-surface subgrid closure framework for general circulation modeling, are assessed.     

多暗像元大气校正方法

 针对Landsat TM影像，设计了一种适用于非均质大气的大气校正方法。该方法以暗目标减法（DOS）为基础，结合大气辐射传输模型，通过选取TM影像上多个暗像元，并计算其所对应的大气校正系数对整幅图像进行大气校正。该方法不依赖任何外部信息，并且考虑了大气的非均质性，校正精度较高。     

婺源县空气负离子分布规律初步分析

在婺源大鄣山卧龙谷景区、鸳鸯湖景区、月亮湾景区、城区和部分村庄选取7个能够代表当地生态环境特征的监测点,进行为期2 d的负离子浓度、温度、风向、风速、空气相对湿度和气压流动监测,并与南昌城区负离子浓度观测资料进行对比,初步分析了负离子分布规律,以及负离子与首要污染物(PM10)的关系.分析结果认为,负离子浓度与植被覆盖率、海拔高度呈正相关,与首要污染物浓度呈负相关;风景区的负离子浓度高于城区:植被状况与瀑布对负离子的空间分布影响最大.     

东经120°E中间层和低热层大气潮汐及其季节变化特征

利用为期一年的卫星遥感温度（SABER/TIMED）资料重建了120°E子午圈内中间层和低热层大气潮汐各主要频率分量（周日、半日和8小时潮汐）.这些主要频率分量随高度振幅增大，在97 km高度达到显著的振幅；其中迁移性周日潮汐在97 km高度出现极大振幅，然后随高度衰减.本文从考察迁移性成分和非迁移性成分各自在总潮汐中贡献角度出发，着重讨论了那些对形成该子午圈中97 km高度上整体潮汐扰动起控制作用的潮汐成分.结果显示，对周日和半日频率这两种潮汐而言，迁移性成分控制了它们的总体时空分布.在春分季节，迁移性周日潮的控制作用最显著，决定了赤道和两半球热带的活动中心；其中北半球副热带地区的季节变化形势与以往利用武汉（30°N，114°E）流星雷达风测量资料开展分析得到的结果是一致的；其他季节受非迁移性成分明显影响，例如，在本文关注的2005年中，夏至季节受（1，0）模、（1，-3）模和（1，-2）模的共同影响形成了从赤道向南延伸的活动中心，极值中心位于赤道附近，振幅达到了20 K以上，是全年的最大值.受迁移性成分控制，半日潮活动主要出现在两半球热带地区，北半球活动中心位于秋分季节（振幅达到13 K），南半球活动中心位于春分和夏至之间.其他季节受非迁移成分的影响，形成若干分布在两半球的活动中心.在本文关注的40°S～40°N范围内，与周日潮和半日潮相比，8小时潮汐具有显著较低的振幅；另外，虽然迁移性成分在一年中的大部分时间系统地分布在两半球热带地区，但是非迁移成分具有与迁移性成分相当或更大的振幅，在整体上控制了这种潮汐的时空分布.