Toward an improved global network for determination of tropospheric ozone climatology and trends

An examination of typical tropospheric ozone variability on daily, monthly, annual and interannual timescales and instrumental precision indicates that the current ozonesonde network is insufficient to detect a trend in tropospheric ozone of 1% per year at the 2 level even at stations with records a decade in length. From a trend prediction analysis we conclude that in order to detect a 1% per year trend in a decade or less it will be necessary to decrease the time between observations from its present value of 3–7 days to 1 day or less. The spatial distribution of the current ozonesonde stations is also inadequate for determining the global climatology of ozone. We present a quantitative theory taking into account photochemistry, surface deposition, and wind climatology to define the effectively sampled region for an observing station which, used in conjunction with the instrumental precision and the above prediction analysis, forms the basis for defining a suitable global network for determining regional and global ozone climatology and trends. At least a doubling of the present number of stations is necessary, and the oceans, most of Asia, Africa, and South America are areas where more stations are most needed. Differential absorption lidar ozone instruments have the potential for far more frequent measurements of ozone vertical profiles and hence potentially more accurate climatology and trend determinations than feasible with ozonesondes but may produce a (fair weather) biased data set above the cloud base. A strategy for cloudy regions in which either each station utilizes both lidars and sondes or each station is in fact a doublet comprised of a near-sea-level lidar and a proximal-mountain-top lidar could serve to minimize this bias.     

Numerical Modelling of the Effects of Ozone on the Summer Atmospheric Circulation

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Modelling the January and July Climate of 9000 Years before Present

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Formic and acetic acids in atmospheric condensate in Wilmington,North Carolina

Formic and acetic acids occurred in atmospheric condensate with concentrations similar to rainwater collected in Wilmington, North Carolina, during the sampling period from June to October of 1990. Atmospheric concentrations of these acids (calculated from the condensate concentrations) were higher in continental versus maritime air masses. Concentrations of formic and acetic acids were correlated with each other in both condensate and air. Traffic was a source of acetic acid and of bisulfite to atmospheric condensate in this study.     

Nonlinear chemical couplings in the tropospheric NO x -HO x gas phase chemistry

A bifurcation phenomenon with relevance to atmospheric chemistry is discussed. The gasphase reactions in the troposphere exhibit two types of temporal evolution which are controlled by the strength of the source,Q, of nitric oxide, NO, via the nonlinear chemical coupling between the hydrogen oxides and nitrogen oxides chemistry. IfQ remains below a threshold value, all short-lived species, including NO, approach steady-state concentrations, while above the threshold bifurcation to another state with increasing (nonstationary) NO concentrations accompanied by a depletion of the OH and HO₂ abundances takes place.     

用非色散红外气体分析仪进行大气CO2本底浓度的测量

按WMO关于开展全球CO2监测的要求，在对引进设备进行改进的情况下，建立了我国开展大气CO2本底浓度连续测量的红外气体分析测量系统及有关方法。系统的测量精度优于0.1ppm，完全满足全球本底测量的要求，并具有较好的国际可比性。在此基础上，首次取得了我国大陆上空大气CO2的本底浓度资料。     

臭氧和平流层动力学的相互作用

讨论了给定的南极春季臭氧洞(取自1979—1985年臭氧减少的观测结果)对二维平流层—对流层模式中温度和环流的影响。11月份,南极上空约17km处,温度最多可降低6℃。这种温度变化引起的平均经向环流对臭氧洞起填塞作用,不过,这种影响很小,每年仅产生14DU的变化。观测事实表明,近年来10月份,南半球波活动减弱。为此,我们作了南半球波作用全年都减少一半,并考虑了臭氧洞的数值试验。结果表明,臭氧柱在11月份76°S减少了44DU,在赤道却增加了12DU。     

北京地区臭氧垂直分布的演变趋势与特征的研究——卫星SBUV资料与地面遥感对比分析

利用地面遥感O₃垂直分布的逆转方法〈C〉测量出的北京上空O₃剖面资料,对雨云7号卫星的SBUV系统测量的同地区的O₃垂直分布数据进行了订正.对订正后的长达8年（1979-1986年）的完整的SBUV资料进行了较为仔细的分析,得出了这一时期内的O₃垂直分布长期演变呈下降趋势.并在上层O₃含量的季节变化特征和周期振荡等方面,有新的发现,得出一些有意义的结果.