Global distribution of gaseous mercury in the troposphere

Atmospheric mercury concentrations were measured during a nautical expedition on the Atlantic Ocean between Hamburg (54°N, 10°E) and Santo Domingo (20°N, 67°W). In addition, samples were taken during flights on a commerical aircraft in the upper and middle troposphere between 60°N and 55°S, mostly over the Pacific Ocean. The data obtained in the lower troposphere over the Northern Atlantic show considerable variation in the Hg concentrations, with values ranging between 1 and 11 ng/m³; the average concentration was found to be 2.8 ng/m³. The upper tropospheric data show an interhemispheric difference with average values of 1.45 ng/m³ and 1.08 ng/m³ in the Northern and Southern Hemisphere, respectively. This suggests that mercury production occurs predominantly over the continents both by natural and anthropogenic processes. The mercury content in aerosols was found to be 0.3 ng/m³, or one-tenth of the atmospheric concentration. The data indicate a mean residence time of mercury in the atmosphere of a few months to one year.     

Mean bulk densities of samples of dry atmospheric aerosol particles: A summary of measured data

Mean bulk densities of various samples of dry atmospheric aerosol particles sampled at different sites and during different seasons and weather situations range between 1.8 and more than 3 gm cm³.     

A spectrum of the acoustic-gravity waves associated with Auroral electro-jet

This model concerns the analysis of Aurora initiated travelling pressure waves in an isothermal atmosphere. Electro-dynamic Lorentz Force associated with auroral electric current density during the periods of geomagnetic activity is invoked as a possible exciting source.The dispersion phenomena in auroral induced acoustic gravity modes in the earth's atmosphere are examined and various cut-off frequencies analysed.Finally, an attempt is made to obtain a far field representation of the forced oscillations by means of Green's Function technique. Therefrom, the spectral amplitudes of the ground-level oscillations are computed. Incorporating various scaling factors, it is deduced that these amplitude components are in reasonable agreement with the results of recent measurements.     

大气热源年代际异常与20世纪70年代末期东亚夏季风年代际减弱

利用1958-2001年ERA-40再分析资料计算大气热源,统计分析了亚洲季风区及其邻近海域大气热源年代际变异的典型模态;利用线性斜压干模式,模拟了夏季大气对大气热源年代际异常的响应,揭示了大气热源年代际异常与1970s末期东亚夏季风年代际减弱的关系。结果表明:近50 a来亚洲及其邻近海域夏季整层大气热源变异主要表现为年代际变化特征,其年代际位相转换发生在1970s中后期,这与东亚夏季风年代际减弱的时间一致;菲律宾附近海域和中国西南地区是与东亚夏季风年代际减弱有直接联系的两个热源异常关键区;东亚夏季风年代际减弱最直接地表现为这两个关键区热源异常的共同作用,而赤道中东太平洋、赤道印度洋大气热源增强则通过大气遥响应机制影响菲律宾附近海域低层大气环流异常对东亚夏季风变异起相反的贡献。     

Abundances of Jupiter's trace hydrocarbons from Voyager and Cassini

The flybys of Jupiter by the Voyager spacecraft in 1979, and over two decades later by Cassini in 2000, have provided us with unique datasets from two different epochs, allowing the investigation of seasonal change in the atmosphere. In this paper we model zonal averages of thermal infrared spectra from the two instruments, Voyager 1 IRIS and Cassini CIRS, to retrieve the vertical and meridional profiles of temperature, and the abundances of the two minor hydrocarbons, acetylene (C₂H₂) and ethane (C₂H₆). The spatial variation of these gases is controlled by both chemistry and dynamics, and therefore their observed distribution gives us an insight into both processes. We find that the two gases paint quite different pictures of seasonal change. Whilst the 2-D cross-section of C₂H₆ abundance is slightly increased and more symmetric in 2000 (northern summer solstice) compared to 1979 (northern fall equinox), the major trend of equator to pole increase remains. For C₂H₂ on the other hand, the Voyager epoch exhibits almost no latitudinal variation, whilst the Cassini era shows a marked decrease polewards in both hemispheres. At the present time, these experimental findings are in advance of interpretation, as there are no published models of 2-D Jovian seasonal chemical variation available for comparison.     

Simulation of the Askervein flow. Part 2: Large-eddy simulations

Large-eddy simulations of the neutrally stratified flow over the Askervein Hill were performed, to improve the knowledge of the flow obtained from field measurements and numerical simulations with Reynolds averaged Navier-Stokes (RANS) methods. A Lagrangian dynamic subgrid model was used but, to avoid the underdissipative character near the ground, it was merged with a damped Smagorinsky model. Simulations of a flat boundary-layer flow with this subgrid model showed that the turbulent vertical motions and shear stress were better resolved using grids with a stream to spanwise aspect ratio Δx / Δy = 2 than with an aspect ratio Δx / Δy = 1. Regarding the flow over the Askervein Hill, it was found that large-eddy simulations provide an acceptable solution for the mean-velocity field and better predictions of the turbulent kinetic energy in the upstream side of the hill than the model. However, as with the model, grid convergence was not achieved in the lee side and the size of the zone with reversed flow increased with the grid refinement. Nevertheless, the existence of the intermittent separation predicted with unsteady RANS in part one of this work seems unquestionable, due to the deceleration of the flow. In our opinion, a better modelling of the decelerating boundary layer in the lee side is required to improve the results obtained using equilibrium assumptions and achieve grid convergence.     

Shear stress partitioning in large patches of roughness in the atmospheric inertial sublayer

Drag partition measurements were made in the atmospheric inertial sublayer for six roughness configurations made up of solid elements in staggered arrays of different roughness densities. The roughness was in the form of a patch within a large open area and in the shape of an equilateral triangle with 60 m long sides. Measurements were obtained of the total shear stress (τ) acting on the surfaces, the surface shear stress on the ground between the elements (τ_S) and the drag force on the elements for each roughness array. The measurements indicated that τ_S quickly reduced near the leading edge of the roughness compared with τ, and a τ_S minimum occurs at a normalized distance (x/h, where h is element height) of (downwind of the roughness leading edge is negative), then recovers to a relatively stable value. The location of the minimum appears to scale with element height and not roughness density. The force on the elements decreases exponentially with normalized downwind distance and this rate of change scales with the roughness density, with the rate of change increasing as roughness density increases. Average τ_S : τ values for the six roughness surfaces scale predictably as a function of roughness density and in accordance with a shear stress partitioning model. The shear stress partitioning model performed very well in predicting the amount of surface shear stress, given knowledge of the stated input parameters for these patches of roughness. As the shear stress partitioning relationship within the roughness appears to come into equilibrium faster for smaller roughness element sizes it would also appear the shear stress partitioning model can be applied with confidence for smaller patches of smaller roughness elements than those used in this experiment.     

A nutrient loading budget for Biscayne Bay, Florida

The water quality in Biscayne Bay has been significantly affected by past and continuing coastal and watershed development. The nutrient concentrations in the Bay have been dramatically changed by the conversion of natural creeks and sheet flow freshwater inputs to rapid and episodic canal inputs from the large and rapidly expanding Miami metropolitan area. This study is an evaluation of nutrient loadings to Biscayne Bay for 1994-2002 from canal, atmospheric, and groundwater sources. Dissolved inorganic nitrogen (DIN, as nitrate, nitrite, and ammonium) and total phosphorus (TP) loadings by the canals were influenced by their geographic locations relative to discharge amount, watershed land use, stormwater runoff, and proximity to landfills. Annual budgets showed that canals contributed the bulk of N loading to the bay as 1687.2 metric ton N yr(-1) (88% total load). Direct atmospheric DIN load for Biscayne Bay was only 231.7 ton N yr(-1), based on surface area. Of the canal DIN load, nitrate+nitrite (NO(x)(-)) loading (1294.5 ton N yr(-1)) made up a much greater proportion than that of ammonium (NH(4)(+), 392.6 ton N yr(-1)). In the urbanized north and central Bay, canal DIN load was evenly split between NO(x)(-) and NH(4)(+). However, in the south, 95% of the DIN load was in the form of NO(x)(-), reflecting the more agricultural land use. Contrary to N, canals contributed the only 66% of P load to the bay (27.5 ton P yr(-1)). Atmospheric TP load was 14 ton Pyr(-1). In the north, canal P load dominated the budget while in the south, atmospheric load was almost double canal load. Groundwater inputs, estimated only for the south Bay, represented an important source of N and P in this zone. Groundwater input of N (141 ton N yr(-1)) was about equal to atmospheric load, while P load (5.9 ton P yr(-1)) was about equal to canal load.     

Spatial and seasonal variation of major ions in Himalayan snow and ice: A source consideration

The spatial and temporal variation of major ions (Ca²⁺, Mg²⁺, Na⁺, K⁺, , , and Cl⁻) in Himalayan snow and ice is investigated by using two snow pits from the East Rongbuk glacier (28°01′N, 86°58′E, 6500 m a.s.l.), one snow pit from the Nangpai Gosum glacier (28°03′N, 86°39′E, 5700 m a.s.l.), one snow pit from the Gyabrag glacier (28°11′N, 86°38′E, 6303 m a.s.l.), and three ice cores from the Sentik (35°59′N, 75°58′E, 4908 m a.s.l.), Dasuopu (28°33′N, 85°44′E, 7000 m a.s.l.), and East Rongbuk (27°59′N, 86°55′E, 6450 m a.s.l.) glaciers, respectively. In general, the major ions show a significant seasonal variation, with high concentrations during the non-monsoon (pre-monsoon and post-monsoon) season and relatively low concentrations during the monsoon season. Monsoon precipitation with high local/regional dust loading related to summer circulation is possibly responsible for the high concentrations occurring sporadically during the monsoon season. The crest of the Himalayas is an effective barrier to the spatial distribution of Na⁺, Cl⁻ and concentrations, but not to the major ions associated with dust influx (e.g. Ca²⁺ and Mg²⁺). Atmospheric backward trajectories from the HYSPLIT_4 model used in identifying chemical species sourcing suggest that the major ions in the Himalayan snow and ice come mainly from the Thar Desert located in the North India, as well as West Asia, or even the distant Sahara Desert in the North Africa during the winter and spring seasons. This is different from the conventionally assumed arid and semi-arid regions of the central Asia. Factors, such as different vapor sources due to atmospheric circulation patterns and geographical features (e.g. altitude, topography), may contribute to the differences in major ionic concentrations between the western and eastern Himalayas.     

江南南部初夏雨季的降水和环流气候特征

基于1961～2010年气象台站逐日降水资料、同期美国NCEP/NCAR的逐日再分析格点资料,通过气候平均、REOF分析、聚类分析等方法,分析了江南地区初夏降水的地域性和时段性特征,及西太平洋副高和高、低空急流等大气环流的相应演变过程。结果发现:（1）江南南部27.5°～29.5°N存在一个独立于华南前汛期和江淮梅雨的初夏雨季,该雨季平均发生时间为6月11～30日,比江淮梅雨早约8天左右。（2）西太平洋副高的西伸东退是江南南部初夏雨季发生发展的重要环流背景,6月第2候副高发生突变性加速西伸之后雨季开始,雨季期间850 hPa副高西伸脊点基本稳定在最西位置即133°E附近,6月第6候副高东退北抬后雨季结束。（3）低层急流大风带的形成和位置是江南南部初夏雨季阶段的重要动力条件,印度洋和孟加拉湾向东北延伸的低层急流与西太平洋副高西北侧的气流连通形成低层急流大风带,并与北侧上空的高空急流耦合,降水集中区位于低层急流大风带左侧、高空急流入口区右侧。