MECHANISM OF THE HYDROLYSIS OF ADENOSINE 5＇-TRIPHOSPHATE: A REGRESSION ANALYSIS OF KINETIC DATA

Data of the hydrolysis of adenosine 5'-triphosphate have been re-evaluated using a computer program thatnumerically integrates the differential rate equations within a routine that optimizes rate coefficients givena suitable model and concentration versus time data. The model is tested by calculation of Hamilton R-values, the Fisher F-statistic, a sensitivity analysis,the standard errors on the rate coefficients and by constructing contour maps of the objective functionversus two rate coefficients. An optimization using only phosphate concentration data cannot distinguish between a model in whichadenosine 5'-monophosphate is formed predominantly directly with a molecule of pyrophosphate, andone in which it is formed via adenosine 5'-diphosphate. A more accurate set of rate coefficients iscalculated from existing data and the relative importance of the two paths determined.     

大气模式设计中的两个问题

本文就大气模式设计中的两个问题:分辨率的确定和非绝热加热、耗散之间的虚假的不平衡的处理进行了讨论。还推导了决定水平和垂直分辨率的公式以及调整非绝热和耗散使其达到准平衡的办法。     

建设项目大气环境影响评价的Fuzzy综合评判方法

本文将Fuzzy综合评判方法应用于建设项目的大气环境影响评价,并通过与其它评价方法的比较,说明Fuzzy综合评判方法在建设项目大气环境影响评价中的可行性和客观性。     

攀枝花市大气污染物降水清除机制的研究

本文采用了主成份分析及因子分析的方法,研究了影响降水pH值的主要源及其贡献和这些源被降水清除的机制。分析结果表明:大气中一次污染物是影响降水pH及各种成分浓度的主要因素。人为污染源包括高排放源、低排放源和汽车源,它们的排放物以碱性物质为主;自然污染源包括输送物、腐烂物、自然NOx等,它们的排放物主要是酸性物质;在一般情况下,降水的pH值取决于高、低排放源排放的碱性物质的多寡;降水量越大,清除的污染物越多,在雨季各测点降水平均pH值为6.31～7.10。在高排放源影响小的地方,对持续时间长的大雨,降水后期的pH能反映自然源的影响,其值小于5.60。可见,攀枝花市酸雨几率极低甚至降水呈碱性,     

SHORT COMMUNICATION MODEL SELECTION BY THE PROGRAM MINIGLASS IN COMPLEX FORMATION STUDIES

The model selection from EMF data of pH titration curves has been studied for binary and ternarysystems(Ni~(2+)-glycine and Ni~(2+)-methionine-taurine respectively)by using the MINIGLASSprogram.Comparison between experimental and calculated titration curves with this interactive programindicates the presence(and the pH range)of the different species in equilibrium.     

Methodological Development of the Conditional Sampling Method. Part II: Quality Control Criteria of Relaxed Eddy Accumulation Flux Measurements

Determination of biosphere–atmosphere exchanges requires accurate quantification of the turbulent fluxes of energy and of a wide variety of trace gases. Relaxed Eddy Accumulation (REA) is a method that has received increasing attention in recent years, because it does not require any rapid sensor for the scalar measurements as the Eddy Correlation method (EC) does. As in all micrometeorological studies, REA measurements in the atmospheric surface layer are valid under some restrictive conditions so as to be representative of a specific ecosystem. These conditions are the homogeneity of the underlying surface, stationary and horizontally homogeneous turbulence. For most experiments these conditions are not fully satisfied. Data uncertainties can also be related to not fulfilling the method principles or to the technical characteristics of the REA system itself. In order to assess REA measurement quality, a methodological approach of data analysis is developed in this study. This methodological analysis is based on the establishment of criteria for data quality control. A set of them, deduced from the mean and turbulent flow, are called ‘Dynamic criteria’ and are designated to control the stationarity and homogeneity of the w function and the validation of Taylor’s hypothesis. A second set (‘REA operational criteria’) is designed to check the sampling process and, more precisely, the homogeneity of the negative and positive selection process throughout the sampling period. A third set of criteria (‘Chemical scalar criteria’) concerns the scalar measurements. Results of the criteria application to data measured at two different experimental sites are also presented. Cut-off limits of criteria are defined based on their statistical distribution and shown to be specific for each site. Strictness of each criterion, defined by the percentage of flagged samples, is analysed in conjunction with the meteorological conditions and atmospheric stability. It is found that flagged samples mainly correspond to neutral and stable nocturnal conditions. During daytime, nearly free convection conditions can also yield poor quality data.     

云南省怒江傈僳族自治州经济发展战略研究

怒江傈僳族自治州是云南省最贫困的民族自治州。本文在认真分析、正确认识州情和改革开放形势的前提下,提出经济发展的指导思想和资源开发脱贫型的战略模式,制定了战略目标、战略步骤和战略重点。在产业结构方面,确定以铅锌为主的有色金属工业,以大理石为主的建材工业,以林副产品为主的生物资源综合开发作为三大主导产业。为保证战略目标的实现,提出重视科学技术和教育事业;改善交通、解决能源、搞活流通:绝不放松粮食生产,慎重解决人口问题;高度重视水土保持,维持生态平衡;采取特殊政策和灵活措施等。     

A Re-Evaluation of Long-Term Flux Measurement Techniques Part II: Coordinate Systems

To convert measurements of windspeed, eddy flux and scalar concentration into estimates of surface scalar exchange, we implicitly or explicitly assimilate the measurements into mathematical statements of the mass balance in a control volume on a representative patch of the surface. The form of this statement depends on the coordinate system in which it is written and the coordinate system should be chosen so that measurements can be used optimally. This requirement imposes a set of conditions on the coordinates. Here we perform a comparative analysis of some candidate coordinate systems, concentrating on the Cartesian and physical streamline systems. We show that over gentle topography there are definite advantages in working in streamline coordinates. Transforming measurements of vector and tensor quantities measured in the reference frame, s _i, of the anemometer into the reference frame, e _i, of the chosen coordinate system involves using the measured statistics of the wind field to define three Euler rotation angles. We compare the method in most common use, which employs the components of the mean wind vector and the Reynolds stress tensor to define these angles, with the more recent planar-fit method that uses instead an ensemble of mean wind vectors to define the rotations. We find that, in real flows, the standard method has a previously unrecognized closure problem that ensures that the third rotation angle defined using the stress tensor or scalar flux vector will always be in error and often give unphysical results. An alternative procedure is recommended. Finally, the relationships between measurements and model outputs are discussed.     

One-Equation Turbulence Modelling for Atmospheric and Engineering Applications

A new algebraic turbulent length scale model is developed, based on previous one-equation turbulence modelling experience in atmospheric flow and dispersion calculations. The model is applied to the neutral Ekman layer, as well as to fully-developed pipe and channel flows. For the pipe and channel flows examined the present model results can be considered as nearly equivalent to the results obtained using the standard k– model. For the neutral Ekman layer, the model predicts satisfactorily the near-neutral Cabauw friction velocities and a dependence of the drag coefficient versus Rossby number very close to that derived from published (G. N. Coleman) direct numerical simulations. The model underestimates the Cabauw cross-isobaric angles, but to a less degree than the cross-isobar angle versus Rossby dependence derived from the Coleman simulation. Finally, for the Cabauw data, with a geostrophic wind magnitude of 10 ms^–1, the model predicts an eddy diffusivity distribution in good agreement with semi-empirical distributions used in current operational practice.